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SEX PHEROMONE OF THE MAPLE LEAF ROLLER CENOPIS ACERIVORANA (LEPIDOPTERA: TORTRICIDAE)

Published online by Cambridge University Press:  31 May 2012

G. G. Grant
Affiliation:
Forest Pest Management Institute, Canadian Forestry Service, Sault Ste. Marie, Ontario P6A 5M7
K. N. Slessor
Affiliation:
Department of Chemistry, Simon Fraser University, Burnaby, British Columbia V5A 1S6

Abstract

Pheromone gland rinses of female maple leaf roller moths were analyzed by capillary gas chromatography and found to contain (Z)-11-tetradecenal, (E)-11-tetradecenal, tetradecanal, (Z)-11-tetradecenyl acetate, (E)-11-tetradecenyl acetate, and tetradecyl acetate in the average ratio of 33:20:8:21:17:2 for single female analysis and 31:16:6:16:27:3 for a pooled extract of 55 females. Identity of the tetradecenals, the tetradecenyl and tetradecyl acetates was confirmed by gas chromatography/mass spectrometry. Electroantennogram analysis indicated that (Z)-11-tetradecenal followed by (E)-11-tetradecenal were the most stimulating compounds tested. In field tests, only three components (Z)-11-tetradecenal, (E)-11-tetradecenal and (Z)-11-tetradecenyl acetate, in the microgram ratio of 65:35:10, were necessary for optimum attraction. Another tortricid moth, Archips griseus, was attracted to some of the aldehyde mixtures.

Résumé

La chromatographie en phase gazeuse à colonnes capillaires a révélé, dans les extraits de la glande qui, chez la femelle adulte de l'enrouleuse de l'érable, secrète les phéromones, la présence de (Z)-tétradécène-11-al, de (E)-tétradécène-11-al, de tétradécénal et d'acétate de (Z)-tétradécène-11-ol-1, de (E)-tétradécène-11-ol-1 et de tétradécénol. En moyenne, le rapport des concentrations de ces substances dans les extraits était respectivement de 33/20/8/21/17/2 pour une femelle et de 31/16/6/16/27/3 pour 55 femelles. On a confirmé l'identité des tétradécénals ainsi que des acétates par chromatographie en phase gazeuse couplée à la spectrométrie de masse. Des électroantennogrammes ont démontré que les substances qui provoquaient les plus fortes réactions étaient d'abord le (Z)-tétradécène-11-al puis le (E)-tétradécène-11-al. Sur le terrain, un mélange de trois des composés seulement, soit 65 μg de (Z)-tétradécène-11-al, 35 μg de (E)-tétradécène-11-al et 10 μg d'acétate de (Z)-tétradécène-11-ol-1, s'est révélé le meilleur attractif. Une autre tortricide, Archips griseus, a été attirée par certains mélanges d'aldéhydes.

Type
Articles
Copyright
Copyright © Entomological Society of Canada 1983

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