Sapphirine granulites from the Vestfold Hills, East Antarctica: geochemical and metamorphic evolution

Abstract

A varied suite of sapphirine-bearing and quartz-undersaturated granulites, the Taynaya Paragneiss, occur as boudins and enclaves within the c. 2500 Ma old felsic orthogneisses of northern Vestfold Hills. Highly magnesian varieties with X_Mg (=100x(Mg/(Mg+Fe)) near 95 preserve the assemblage sapphirine + enstatite + spinel, whereas sapphirine + cordierite + sillimanite + corundum occurs in aluminous and feldspathic types with X_Mg near 90. Phase equilibria and relative thermometry based on Al₂O₃ solubility in enstatite indicate equilibration of these assemblages at c. 830–880°C and 0.35–0.85 GPa. There is no evidence for the extreme temperatures (1000–1100°C) previously proposed for early metamorphism in the Vestfold Hills, and no indication in the metamorphic assemblages of isobaric cooling prior to 2500 Ma. Two types of metasomatism have altered the bulk rock compositions near boudin and enclave margins. Cordierite rinds locally formed on corundum-sillimanite granulites reflect interaction with magmatic precursors to the enclosing felsic gneisses, as supported by the isotopic and chemical compositions of cordierite channel volatiles. More extensive metasomatism producing schistose phlogopite + sapphirine rinds on all boudins involved infiltration of a LILE-enriched fluid which introduced K₂O, H₂O, Fe, Rb, Ba and minor Sr along the boudin margins. Whole rock geochemistry of Taynaya Paragneiss unaffected by this metasomatism is consistent with their derivation from evaporitic mudstones, and implies the existence of a basement older than the dominant 2500 Ma orthogneisses.