Hostname: page-component-78c5997874-t5tsf Total loading time: 0 Render date: 2024-11-09T22:37:17.146Z Has data issue: false hasContentIssue false
  • English
  • Français

X-Ray Spectroscopic Studies of Bonding in Iron Germanides

Published online by Cambridge University Press:  06 March 2019

E. Adelson  and
A. E. Austin
E. Adelson
Affiliation:
Battelle Memorial Institute, Columbus Laboratories, Columbus, Ohio
A. E. Austin
Affiliation:
Battelle Memorial Institute, Columbus Laboratories, Columbus, Ohio
Get access

Abstract

X-ray emission spectra have been obtained with a single crystal spectrometer having a resolution λ/dλ of 6,640 for iron Kβ5 spectra. The spectrometer consisted of a Jarrel-Ash Microfocus unit in conjunction with a Picker diffractometer which was operated as a rocking crystal spectrometer with a stepping angle of 1/400th of a degree. Kβ5 and Kβ1,3 spectra have been obtained from iron, Fe0.9Mn0.9Ge, Fe1.60Ge, FeGe, FeGe2 and germanium. Because the K05 spectra are due to 4p - Is transitions from the 3d bands, the Kβ5 intensities are a direct measure of the overlap or hybridization of the 3d - 4s - 4p bands. The experimental results can be correlated either with orbitals derived on the basis of coordination, or more roughly with possible band distributions.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 12: Seventeenth Annual Conference on Applications of X-ray Analysis, August 21-23, 1968 , 1968 , pp. 506 - 517
Copyright
Copyright © International Centre for Diffraction Data 1968

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Kanematsu, K. and Ohoyama, T., “Magnetic and X-Ray Studies of Iron-Germanium System”, J. Phys. Soc. Jap. 20: 236–242, 1965, (most earlier references are listed).Google Scholar
2. Shtol'ts, A. K., Gel'd, P. V., and Zagrayazhskly, V. L., “Some Electrical and Magnetic Properties of the β-Phase of the System Fe-Ge”, Fiz. Metal. Metalloved. 16: 198–204, 1963.Google Scholar
3. Geist, D., Kunz, R., and Roemelt, G., “Das magnetische Verhalten von FeFe2 - Einkristallen, auch für Abweichungen von des stöchiomefcrischen Zusammensetzung” Z. für Phys., 193: 174–180, 1966.Google Scholar
4. Adelson, E. and Austin, A. E., “Magnetic Structures of Iron Germanides” J. Phys. Chem. Solids, 26: 1795–1804, 1965, (earlier references are listed).Google Scholar
5. Bertaut, E. F. and Chenevas, J., “Comments on the Magnetic Structure of δ-FeGe2” Sol. State Coram., 3: 117, 1965, (earlier references are listed).Google Scholar
6. Watanabe, H. and Kunitomi, N., “On the Neutron Diffraction Study of FeGe” J. Phys. Soc. Jap., 21: 1932–1935, 1966.Google Scholar
7. Suzuoka, T., Adelson, E., and Austin, A. E., “Magnetic Structure of Fe0.9Mn0.9Ge”, Acta Cryst., to be published.Google Scholar
8. Tomiyoshi, S., Yamamoto, H., and Watanabe, H., “The Mossbauer Study of FeGe” J. Phys. Soc. Jap., 21: 709–712, 1966, (earlier references are given).Google Scholar
9. Bhide, V. G. and Date, S. K., “MBssbauer Study of Intermetallic Fe5Ge3 System”, Sol. State Comm., 5: 435–437, 1967.Google Scholar
10. Beeman, W. W. and Friedman, H., “The X-Ray K- Absorption Edges of the Elements Fe(26) to Ge(32)”, Phys. Rev., 56: 392–405, 1939.Google Scholar
11. Blokhin, M. A. and Sachenko, V. P., “Width of the Inner Levels and Density Distribution of Electron States in Elements of the Iron Transition Group”, Bull. Acad. Sci. USSR, 21: 1333–1340, 1957, (Eng. tr.).Google Scholar
12. Nemnonov, S. A. and Kolobova, K. M., “Connection Between Certain X-Ray and Magnetic Characteristics of Iron-Base Alloys”, Fiz. Metal. Metalloved. 6: 466–474, 1958.Google Scholar
13. Men'shikov, A. Z., “Problem of Interpreting the X-Ray Emission and Absorption Spectra of Transition Metals”, Fiz. Metal. Metalloved. 15 : 833–838, 1963.Google Scholar
14. Nikiforov, I. Ya. and Blokhin, M. A., “Concerning the Shape of the Kg5 Emission Band of Iron”, Bull. Acad. Sci. USSR, 27: 323–327, 1963. (Eng. tr.).Google Scholar
15. Nikiforov, I. Ya. and Blokhin, M. A., “Shape of the K Emission Bands of Iron-Group Transition Metals”, Bull. Acad. Sci. USSR, 28 : 695–698, 1963. (Eng. tr.).Google Scholar
16. Nemoshkalenko, V. V. and Nagornyi, V. Ya., “Fine Structure of the X-Ray Emission Bands of Elements of the Iron Transition Group”, Sov. Phys. Dokl., 12 : 735–738, 1968.Google Scholar
17. Bearden, J. A. and Shaw, C. H., “Shapes and Wavelengths of K Series Lines of Elements Ti 22 to Ge 32”, Phys. Rev., 48.: 18–30, 1935.Google Scholar
18. Kolobova, K. M., Men'shikov, A. Z., and Nemnonov, S. A., Fiz. Metal. Metalloved. 21: 618–619, 1966.Google Scholar
19. Men'shikov, A. Z., “Nature of the X-Ray Short Wave Satellites”, Fiz. Metal. Metalloved., 14: 396–399, 1962.Google Scholar
20. Gorak, Z., “On the Origin of Some Satellites in X-Ray Spectra”, Bull. Acad. Sci. USSR, 24: 432–433, 1960. (Eng. tr.).Google Scholar
21. Tsutsumi, K., “The X-Ray Non-diagram Lines Kg’ of Some Compounds of the Iron Group”, J. Phys. Soc. Jap. 14: 1696–1706, 1959.Google Scholar
22. Malkovsk'a, M., “Studium der Linien Kβ1 und Kβ' im Roentgenspektrum von Fe und seinen Verbindungen”, Experim. Techn. d. Physik, VI: 129–131, 1958.Google Scholar
23. Goodenough, J. B., Magnetism and the Chemical Bond, (Interscience), 1963, p. 306.Google Scholar