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X-Ray Photoelectron and Fluorescence Spectra of Several Zirconium Oxide Compounds

Published online by Cambridge University Press:  06 March 2019

Tatsuya Haruyama ,
Goh Sasaki ,
Sei Fukushima ,
Kozo Kuchitsu  and
Naoto Koshizaki
Tatsuya Haruyama
Affiliation:
Analysis Research Center, Fuji Xerox Co., Ltd. Kanagawa, JAPAN
Goh Sasaki
Affiliation:
Department Chemistry, Nagaoka University of Technology Niigata, JAPAN
Sei Fukushima
Affiliation:
Analysis Research Center, Fuji Xerox Co., Ltd. Kanagawa, JAPAN
Kozo Kuchitsu
Affiliation:
Department Chemistry, Nagaoka University of Technology Niigata, JAPAN
Naoto Koshizaki
Affiliation:
Composite Engineering Division, Structure Technology Department, Industrial Products Research Institute Ibaraki, JAPAN
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Abstract

Ila group metal - Zr pcrovskitc type compounds (MZrO3, M=Ba. Sr and Ca) and other oxides were studied by XPS to know the effects of M atoms to Zr atoms. And the feasibility of using XPS and high-resolution XRF for the coordination analysis of Zr atoms was examined for some kinds of stabilized zirconia. An almost linear relationship between the energy of Zr 3d peaks and the radii of Ila group metal ions was found, and, a simple model to interpret this relationship has been proposed. However, no relationship between the energy shifts of Zr 3d spectra or Zr Lα1, 2 spectra and the coordination numbers of Zr atoms in the several Zr oxide compounds was found. Thus, the coordination analysis using XPS or high-resolution XRF is not feasible.

Type
XI. Thin-Film and Surface Characterization by XRS and XPS
Information
Advances in X-Ray Analysis , Volume 35 , Issue B: First Pacific-International Congress on X-ray Analytical Methods (PICXAM). Fortieth Annual Conference on Applications of X-ray Analysis, August 7-16, 1991 , 1991 , pp. 851 - 856
Copyright
Copyright © International Centre for Diffraction Data 1991

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