Preface

Summary

Materials Science is an extremely broad field covering metals, semiconductors, ceramics, and polymers, just to mention a few. Its study is dominated by the fabrication of specimens and the characterization of their properties. A relatively small portion of the field is devoted to phase transformation, the dynamic process by which in the present context a liquid is frozen or a solid is melted.

This book is devoted to the study of liquid (melt)-solid transformations of atomically rough materials: metals or semiconductors, including model organics like plastic crystals. The emphasis is on the use of instability behavior as a means of understanding those processes that ultimately determine the micro-structure of a crystalline solid. The fundamental building block of this study is the Mullins–Sekerka instability of a front, which gives conditions for the growth of infinitesimal disturbances of a soild–liquid front. This is generalized in many ways: into the nonlinear regime, including thermodynamic disequilibrium, anisotropic material properties, and effects of convection in the liquid. Cellular, eutectic, and dendritic behaviors are discussed. The emphasis is on dynamic phenomena rather than equilibria. In a sense then, it concerns “physiology” rather than “anatomy.”

The aim of this book is to present in a systematic way the field of continuum solidification theory. This begins with the primitive field equations for diffusion and the derivation of appropriate jump conditions on the interface between the solid and liquid. It then uses such models to explore morphological instabilities in the linearized range and gives physical explanations for the phenomena uncovered.