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3 - Mid-infrared (Thermal) Emission and Reflectance Spectroscopy

Laboratory Spectra of Geologic Materials

from Part I - Theory of Remote Compositional Analysis Techniques and Laboratory Measurements

Published online by Cambridge University Press:  15 November 2019

By
Melissa D. Lane  and
Janice L. Bishop
Edited by
Janice L. Bishop ,
James F. Bell III  and
Jeffrey E. Moersch
Janice L. Bishop
Affiliation:
SETI Institute, California
James F. Bell III
Affiliation:
Arizona State University
Jeffrey E. Moersch
Affiliation:
University of Tennessee, Knoxville
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Summary

Middle infrared (~2000 to 200 cm–1 or 5 to 50 μm) data are extremely useful for compositional determination of geologic materials because this wavelength region hosts the fundamental (“Reststrahlen”) vibrational bands of most minerals. Analysis of remotely sensed data requires comparison to well-developed spectral libraries populated with a wide variety of mid-IR mineral spectra (and additional rock or meteorite spectra). Here we present the theory behind molecular vibrations of mineral structures and the simple harmonic oscillators that define them mathematically. We present dispersion theory that describes how energy travels through a crystal and how propagating energy is affected by the crystal lattice structure, specifically along the various crystal axes. The equipment required for these types of laboratory measurements (both emissivity and reflectivity) is presented as well as a discussion about how mid-IR data are affected by particle size and how related volume scattering affects spectral data. Finally, mid-IR emissivity spectra acquired in a dry, 1-atm environment are provided for 93 different minerals and meteorites. These spectra are available as ancillary data files.

Keywords

mid-infraredinfraredemissionemissivityreflectancemineralsvibrationalmeteoritesdispersionspectroscopy
Type
Chapter
Information
Remote Compositional Analysis
Techniques for Understanding Spectroscopy, Mineralogy, and Geochemistry of Planetary Surfaces
 , pp. 42 - 67
Publisher: Cambridge University Press
Print publication year: 2019

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