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7 - Atoms, molecules, and molecular motion

Vinay Ambegaokar
Affiliation:
Cornell University, New York
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Summary

If, in some cataclysm, all of scientific knowledge were to be destroyed, and only one sentence passed on to the next generation of creatures, what statement would contain the most information in the fewest words? I believe it is the atomic hypothesis (or the atomic fact, or whatever you wish to call it)…

Richard P. Feynman

That a gas, air for example, is made up of a myriad tiny bodies, now called molecules, moving about randomly and occasionally colliding with each other and with the walls of a containing vessel, is today a commonplace fact that can be verified in many ways. Interestingly, this molecular view was widely though not universally accepted long before there were experimental methods for directly confirming it. The credit for the insight has to go to Chemistry, because a careful study of chemical reactions revealed regularities that could most easily be understood on the basis of the molecular hypothesis. These regularities were known to chemists by the end of the eighteenth century. By this time, the notion of distinct chemical species, or ‘elements,’ was well established, these being substances, like oxygen and sulfur, that resisted further chemical breakdown. It was discovered that when elements combine to make chemical compounds they do so in definite weight ratios. It was also found that when two elements combine to make more than one compound the weights of one of the elements, when referred to a definite weight of the second, stand one to another in the ratio of small integers – which sentence is perhaps too Byzantine to be made sense of without a definite example.

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Chapter
Information
Reasoning about Luck
Probability and its Uses in Physics
, pp. 102 - 119
Publisher: Cambridge University Press
Print publication year: 1996

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