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4 - Quantum Mechanical Operators

Published online by Cambridge University Press:  02 December 2022

Ram Yatan Prasad Pranita
Affiliation:
Pro-vice-chancellor, Sido Kanhu Murmu University, Dumka, Jharkhand, India
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Summary

Before taking into consideration the quantum mechanical operators, it is perhaps the best to clear the meaning of the term operator in the mathematical sense. The term operator may be defined in the following manner:

An operator is a symbol, which represents a mathematical operation to be carried out on a specific operand.

or

An operator is a symbol that tells to do something to whatever follows the symbol.

or

An operator may be defined as a short-hand notation for a set of well-defined mathematical operations to be carried out on a function (called the operand).

or

An operator conveys the instruction to carry out operation on a function.

or

An operator is defined as a symbol of mathematical procedure, which alters one function into another.

or

A mathematical entity that acts to transform various functions of the independent variables to different functions of these variable.

It means, operator. function = new function

Here symbol d/dx is an operator that alters the function sin x into first derivative with respect to x, i.e., cos x.

Similarly, the symbol () is an operator, the instruction being to take the square root of the quantity, which follows it. For example, if a number, say 25, is kept under operator (), it alters 25 into its square root, i.e., 25 = 5. Addition, subtraction, multiplication, division, log, differentiation, integration, etc., are also operators. It is to be noted that the operators always operate on the function written to the right of them and the operator has no physical significance if written alone.

An operator is normally written with a cap sign (ˆ) overhead, e.g., Â. Thus,  represents an operator. To make it clearer, if we write  f (x) = g(x), it means  is an operator operating on the function f (x). g(x) is an another function, which is a new one obtained after the operation of operator  on the function f (x).

If  = d/dx and f (x) = ax2, then  f (x) = d/dx(ax2) = 2ax = g(x). Similarly, we can cite other examples similar to the above.

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Publisher: Foundation Books
Print publication year: 2014

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  • Quantum Mechanical Operators
  • Ram Yatan Prasad Pranita, Pro-vice-chancellor, Sido Kanhu Murmu University, Dumka, Jharkhand, India
  • Book: Principles of Quantum Chemistry
  • Online publication: 02 December 2022
  • Chapter DOI: https://doi.org/10.1017/9789385386060.006
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  • Quantum Mechanical Operators
  • Ram Yatan Prasad Pranita, Pro-vice-chancellor, Sido Kanhu Murmu University, Dumka, Jharkhand, India
  • Book: Principles of Quantum Chemistry
  • Online publication: 02 December 2022
  • Chapter DOI: https://doi.org/10.1017/9789385386060.006
Available formats
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Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • Quantum Mechanical Operators
  • Ram Yatan Prasad Pranita, Pro-vice-chancellor, Sido Kanhu Murmu University, Dumka, Jharkhand, India
  • Book: Principles of Quantum Chemistry
  • Online publication: 02 December 2022
  • Chapter DOI: https://doi.org/10.1017/9789385386060.006
Available formats
×