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8 - Self- and tracer diffusion

Published online by Cambridge University Press:  05 August 2012

George D. J. Phillies
Affiliation:
Worcester Polytechnic Institute, Massachusetts
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Publisher: Cambridge University Press
Print publication year: 2011

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References

[1] W., Brown, P., Stilbs, and R. M., Johnsen. Self-diffusion and sedimentation of dextran in concentrated solutions. J. Polym. Sci. Polym. Phys., 20 (1982), 1771–1780.Google Scholar
[2] W., Brown, P., Stilbs, and R. M., Johnsen. Friction coefficients in self-diffusion, velocity sedimentation, and mutual diffusion for polyethylene oxide in aqueous solution. J. Polym. Sci. Polym. Phys., 21 (1983), 1029–1039.Google Scholar
[3] B., Tinland, G., Maret, and M., Rinaudo. Reptation in semidilute solutions of wormlike polymers. Macromolecules, 23 (1990), 596–602.Google Scholar
[4] P. T., Callaghan and D. N., Pinder. Dynamics of entangled polystyrene solutions studied by pulsed field gradient nuclear magnetic resonance. Macromolecules, 13 (1980), 1085–1092.Google Scholar
[5] P. T., Callaghan and D. N., Pinder. Self-diffusion of random-coil polystyrene determined by pulsed field gradient nuclear magnetic resonance: Dependence on concentration and molar mass. Macromolecules, 14 (1981), 1334–1340.Google Scholar
[6] P. T., Callaghan and D. N., Pinder. Influence of multiple length scales on the behavior of polymer self-diffusion in the semidilute regime. Macromolecules, 17 (1984), 431–437.Google Scholar
[7] J., Hadgraft, A. J., Hyde, and R. W., Richards. Diffusion of polystyrene in polymethyl methacrylate + benzene solutions measured by photon correlation spectroscopy. Far. Trans. II, 75, 1495–1505.
[8] H., Hervet, L., Leger, and F., Rondelez. Self-diffusion in polymer solutions. A test for scaling and reptation. Phys. Rev. Lett., 42 (1979), 1681–1684.Google Scholar
[9] L., Leger, H., Hervet, and R., Rondelez. Reptation in entangled polymer solutions by forced Rayleigh scattering. Macromolecules, 14 (1981), 1732–1738.Google Scholar
[10] H., Deschamps and L., Leger. Self-diffusion measurements in polymer solutions at the Θ temperature by forced Rayleigh light scattering. Macromolecules, 19 (1986), 2760–2765.Google Scholar
[11] N., Nemoto, M., Kishine, T., Inoue, and K., Osaki. Self-diffusion and viscoelasticity of linear polystyrene in entangled solutions. Macromolecules, 24 (1991), 1648–1654.Google Scholar
[12] N., Nemoto, T., Kojima, T., Inoue, and M., Kurata. Self-diffusion of polymers in the concentrated regime I. Temperature dependence of the self-diffusion coefficient and the steady viscosity of polystyrene in dibutyl phthalate. Polym. J., 20 (1988), 875–881.Google Scholar
[13] M., Nyden, O., Soederman, and G., Karlstroem. A PFG NMR self-diffusion investigation of probe diffusion in an ethylhydroxyethylcellulose matrix. Macromolecules, 32 (1999), 127–135.Google Scholar
[14] V. D., Skirda, N. F., Fatkullin, V. I., Sundukov, and A. I., Maklakov. Concentration dependence of the coefficient of self-diffusion of macromolecules in polymer solutions. Polym. Sci. U.S.S.R., 29 (1987), 2229–2236.Google Scholar
[15] H., Tao, T. P., Lodge, and E. D., von Meerwall. Diffusivity and viscosity of concentrated hydrogenated polybutadiene solutions. Macromolecules, 33 (2000), 1747–1758.Google Scholar
[16] G., Fleischer. Self-diffusion in concentrated solutions of polystyrene in toluene: No evidence for large-scale heterogeneities. Macromolecules, 32 (1999), 2382–2383.Google Scholar
[17] K., Osaki, Y., Nishimura, and M., Kurata. Viscoelastic properties of semidilute polystyrene solutions. Macromolecules, 18 (1985), 1153–1157.Google Scholar
[18] K., Zero and B. R., Ware. Mobilities of poly-L-lysine molecules in low-salt solutions. J. Chem. Phys., 80 (1984), 1610–1616.Google Scholar
[19] G., Johnson, A. I., Mel'cuk, H., Gould, W., Klein, and R. D., Mountain. Molecular-dynamics study of long-lived structures in a fragile glass-forming liquid. Phys. Rev. E, 57 (1998), 5707–5718.Google Scholar
[20] W., Klein, H., Gould, J., Tobochnik, et al.Clusters and fluctuations at mean-field critical points and spinodals. Phys. Rev. Lett., 85 (2000), 1270–1273.Google Scholar
[21] E. von, Meerwall, D. H., Tomich, N., Hadjichristis, and L. J., Fetters. Phenomenology of self-diffusion in star-branched polyisoprenes in solution. Macromolecules, 15 (1982), 1157–1163.Google Scholar
[22] E. D., von Meerwall, D. H., Tomich, J., Grigsby, et al. Self-diffusion of three-armed star and linear polybutadienes and polystyrenes in tetrachloromethane solution. Macromolecules, 16 (1983), 1715–1722.Google Scholar
[23] C., Xuexin, X., Zhongde, E., von Meerwall, et al. Self-diffusion of linear and 4- and 18-armed star polyisoprenes in tetrachloromethane solution. Macromolecules, 17 (1984), 1343–1348.Google Scholar
[24] L., Giebel, M., Benmouna, R., Borsali, and E. W., Fischer. Quasielastic light scattering from polydimethylsiloxane/polymethyl methacrylate/chloroform under the optical theta condition. Macromolecules, 26 (1993), 2433–2438.Google Scholar
[25] V. D., Skirda, V. I., Sundukov, A. I., Maklakov, et al.On the generalized concentration and molecular mass dependencies of macromolecular self-diffusion in polymer solutions. Polymer, 29 (1988), 1294–1300.Google Scholar
[26] E. D., von Meerwall, E. J., Amis, and J. D., Ferry. Self-diffusion in solutions of polystyrene in tetrahydrofuran. Comparison of concentration dependences of the diffusion coefficients of polymer, solvent, and a ternary probe component. Macromolecules, 18 (1985), 260–266.Google Scholar
[27] J. A., Wesson, I., Noh, T., Kitano, and H., Yu. Self-diffusion of polystyrenes by forced Rayleigh scattering. Macromolecules, 17 (1984), 782–792.Google Scholar
[28] D. B., Cotts. Properties of semidilute polymer solutions: Investigation of an optically-labeled three-component solution. J. Polym. Sci. Polym. Phys., 21 (1983), 1381–1388.Google Scholar
[29] T. P., Lodge. Self-diffusion of polymers in concentrated ternary solutions by dynamic light scattering. Macromolecules, 16 (1983), 1393–1395.Google Scholar
[30] B., Hanley, M., Tirrel, and T. P., Lodge. The behavior of the tracer diffusion coefficient of polystyrene in isorefractive “solvents” composed of polyvinyl methyl ether and o-fluorotoluene. Polym. Bull. Berlin, 14 (1985), 137–142.Google Scholar
[31] T. P., Lodge and L. M., Wheeler. Translational diffusion of linear and 3-arm-star polystyrenes in semidilute solutions of linear polyvinyl methyl ether. Macromolecules, 19 (1986), 2983–2986.Google Scholar
[32] T. P., Lodge and P., Markland. Translational diffusion of 12-arm star polystyrenes in dilute and concentrated polyvinyl methyl ether solutions. Polymer, 28 (1987), 1377–1384.Google Scholar
[33] L. M., Wheeler, T. P., Lodge, B., Hanley, and M., Tirrell. Translational diffusion of linear polystyrenes in dilute and semidilute solutions of polyvinyl methyl ether. Macromolecules, 20 (1987), 1120–1129.Google Scholar
[34] T. P., Lodge, P., Markland, and L. M., Wheeler. Tracer diffusion of 3-arm and 12-arm star polystyrenes in dilute, semidilute, and concentrated polyvinyl methyl ether solutions. Macromolecules, 22 (1989), 3409–3418.Google Scholar
[35] L. M., Wheeler and T. P., Lodge. Tracer diffusion of linear polystyrenes in dilute, semidilute, and concentrated polyvinyl methyl ether solutions. Macromolecules, 22 (1989), 3399–3408.Google Scholar
[36] J. E., Martin. Polymer self-diffusion: dynamic light scattering studies of isorefractive ternary solutions. Macromolecules, 17 (1984), 1279–1283.Google Scholar
[37] J. E., Martin. Polymer self-diffusion in bimodal semidilute solutions. Macromolecules, 19 (1986), 922–925.Google Scholar
[38] P., Daivis, I., Snook, W., Megen, B. N., Preston, and W. D., Comper. Dynamic light scattering measurements of diffusion in polymer–polymer–solvent systems. Macromolecules, 17 (1984), 2376–2380.Google Scholar
[39] P. J., Daivis, D. N., Pinder, and P. T., Callaghan. Dynamic light scattering and pulsed gradient spin-echo NMR measurements of diffusion in polystyrene-polyvinyl methyl ether-toluene solutions. Macromolecules, 25 (1992), 170–178.Google Scholar
[40] W., Brown and R., Rymden. Comparison of the translational diffusion of large spheres and high molecular weight coils in polymer solutions. Macromolecules, 21 (1988), 840–846.Google Scholar
[41] M. S., Kent, M., Tirrell, and T. P., Lodge. Solution properties of polymer mixtures. Macromolecules, 25 (1992), 5383–5397.Google Scholar
[42] W., Brown and P., Stilbs. Self-diffusion of polyethylene oxide in aqueous dextran solutions measured using FT-pulsed field gradient NMR. Polymer, 24 (1983), 188–192.Google Scholar
[43] S. C., Smedt, A., Lauwers, J., DeMeester, et al. Structural information on hyaluronic acid solutions as studied by probe diffusion experiments. Macromolecules, 27 (1994), 141–146.Google Scholar
[44] B., Tinland and R., Borsali. Single-chain diffusion coefficient of f-dextran in polyvinyl pyrrolidone/water: fluorescence recovery after photobleaching experiments. Macromolecules, 27 (1994), 2141–2144.Google Scholar
[45] B. A., Smith, S. J., Mumby, E. T., Samulski, and L. P., Yu. Concentration dependence of the diffusion of polypropylene oxide in the melt. Macromolecules, 19 (1986), 470–472.Google Scholar
[46] S. F., Tead and E. J., Kramer. Polymer diffusion in melt blends of low and high molecular weight. Macromolecules, 21 (1988), 1513–1517.Google Scholar
[47] N., Nemoto, T., Inoue, Y., Makita, Y., Tsunashima, and M., Kurata. Dynamics of polymer–polymer–solvent ternary systems 2. Diffusion and sedimentation of polymethyl-methacrylate in semidilute solutions of polystyrene in thiophenol. Macromolecules, 18 (1985), 2516–2522.Google Scholar
[48] N., Nemoto, T., Kojima, T., Inoue, et al. Self-diffusion and tracer-diffusion coefficient and viscosity of concentrated solutions of linear polystyrenes in dibutyl phthalate. Macromolecules, 22 (1989), 3793–3798.Google Scholar
[49] N., Nemoto, M., Kishine, T., Inoue, and K., Osaki. Tracer diffusion of linear polystyrene in entanglement networks. Macromolecules, 23 (1990), 659–664.Google Scholar
[50] N., Numasawa, K., Kuwamoto, and T., Nose. Translational diffusion of polystyrene single chains in semidilute solutions of polymethyl methacrylate/benzene as measured by quasi-elastic light scattering. Macromolecules, 19 (1986), 2593–2601.Google Scholar
[51] D. N., Pinder. Polymer self-diffusion in ternary solutions and the monomer and segmental self-diffusion coefficients. Macromolecules, 23 (1990), 1724–1729.Google Scholar
[52] H., Kim, T., Chang, J. M., Yohanan, L., Wang, and H., Yu. Polymer diffusion in linear matrices. Polystyrene in toluene. Macromolecules, 19 (1986), 2737–2744.Google Scholar
[53] T., Chang, C. C., Han, L. M., Wheeler, and T. P., Lodge. Comparison of diffusion coefficients in ternary polymer solutions measured by dynamic light scattering and forced Rayleigh scattering. Macromolecules, 21 (1988), 1870–1872.Google Scholar
[54] D. E., Smith, T. T., Perkins, and S., Chu. Self-diffusion of an entangled molecule by reptation. Phys. Rev. Lett., 75 (1995), 4146–4149.Google Scholar
[55] J., Skolnick and A., Kolinski. Dynamics of dense polymer systems: Computer simulations and analytic theories. Adv. Chemical Phys., 77 (1990), 223–278.Google Scholar
[56] T. P., Lodge. Reconciliation of the molecular weight dependence of diffusion and viscosity in entangled polymers. Phys. Rev. Lett., 83 (1999), 3218–3221.Google Scholar
[57] B., Chu, D. Q., Wu, and G. M., Liang. Polymer probe dynamics. Macromolecules, 19 (1986), 2665–2666.Google Scholar
[58] B., Chu and D. Q., Wu. Polymer probe dynamics. Macromolecules, 20 (1987), 1606–1619.Google Scholar
[59] T., Cosgrove and P. C., Griffiths. Diffusion in bimodal and polydisperse polymer systems. 1. Bimodal solutions of protonated and deuterated polymers. Polymer, 36 (1993), 3335–3342.Google Scholar
[60] N., Numasawa, T., Hamada, and T., Nose. Dynamic light scattering of polystyrene single chains in a semidilute solution of polymethyl methacrylate and benzene. J. Polym. Sci. Polym. Phys., 24 (1986), 19–26.Google Scholar
[61] P. S., Russo, M., Baylis, Z., Bu, et al.Self-diffusion of a semiflexible polymer measured across the lyotropic liquid-crystalline-phase boundary. J. Chem. Phys., 111 (1999), 1746–1752.Google Scholar
[62] G. D. J., Phillies. Fluorescence correlation spectroscopy and nonideal solutions. Biopolymers, 14 (1975), 499–508.Google Scholar
[63] B. A., Scalettar, J. E., Hearst, and M. P., Klein. FRAP and FCS studies of self-diffusion and mutual diffusion in entangled DNA solutions. Macromolecules, 22 (1989), 4550–4559.Google Scholar
[64] U., Zettl, S. T., Hoffmann, F., Koberling, et al. Self-diffusion and cooperative diffusion in semidilute polymer solutions as measured by fluorescence correlation spectroscopy. Macromolecules, 42 (2009), 9537–9547.Google Scholar
[65] J. M., Carter and G. D. J., Phillies. Second-order concentration correction to the mutual diffusion coefficient of a suspension of hard Brownian spheres. J. Phys. Chem., 89 (1985), 5118–5124.Google Scholar

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  • Self- and tracer diffusion
  • George D. J. Phillies, Worcester Polytechnic Institute, Massachusetts
  • Book: Phenomenology of Polymer Solution Dynamics
  • Online publication: 05 August 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511843181.009
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  • Self- and tracer diffusion
  • George D. J. Phillies, Worcester Polytechnic Institute, Massachusetts
  • Book: Phenomenology of Polymer Solution Dynamics
  • Online publication: 05 August 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511843181.009
Available formats
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  • Self- and tracer diffusion
  • George D. J. Phillies, Worcester Polytechnic Institute, Massachusetts
  • Book: Phenomenology of Polymer Solution Dynamics
  • Online publication: 05 August 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511843181.009
Available formats
×