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8 - Specialised PGSE and related techniques

Published online by Cambridge University Press:  06 August 2010

William S. Price
William S. Price
Affiliation:
University of Western Sydney
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Summary

Introduction

This chapter primarily deals with specialised NMR pulse sequences for measuring diffusion and flow. Sequences for MRI applications are given in Chapter 9. Steady gradient methods and especially those involving the stray field of superconducting magnets are outside the scope of the present work and so only a brief coverage is given in Section 8.2. Multiple-quantum and heteronuclear measurements are covered in Section 8.3. There has been considerable development of fast diffusion pulse sequences and these are covered in Section 8.4. Methods for handling samples that contain overlapping resonances with differences in relaxation time are considered in Section 8.5. Multi-dimensional methods for mixture separation and diffusion editing are presented in Section 8.6. Double PGSE and multi-dimensional motional correlation experiments are discussed in Section 8.7. Flow and Electrophoretic NMR are covered in Sections 8.8 and 8.9, respectively. Finally, the use of long-range dipolar interactions and miscellaneous sequences are presented in Section 8.10.

Steady gradient and stray field measurements

The earliest gradient-based diffusion measurements were based on the (technically simple) steady gradient experiments as discussed in Chapter 2. However, due to the limitations mentioned in Section 2.2.4, PGSE has generally overshadowed SGSE.

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NMR Studies of Translational Motion
Principles and Applications
 , pp. 256 - 295
Publisher: Cambridge University Press
Print publication year: 2009

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