A new protocol was developed to examine an assemblage of kaolinite-smectite in a buried horizon of a paleosol developed on gabbro parent material. The new extraction procedure appears suitable for removing kaolinite and for ascertaining the nature of the smectite interstratified with kaolinite. Smectite was identified by X-ray diffraction (XRD) and infrared (IR) patterns, cation exchange capacity (CEC) and chemical analyses.

The results obtained provide for increased understanding of the process of transformation of smectite into kaolinite.

Widely distributed Mid-Neoproterozoic mafic rocks of the Qilian – Qaidam – East Kunlun region record the tectonic evolution of the northeastern Tibetan Plateau. This study presents whole-rock geochemistry, zircon U–Pb geochronology and Hf isotopes for the Xialanuoer gabbros of the central South Qilian Belt (SQB). Zircon laser ablation – inductively coupled plasma – mass spectrometry (LA-ICP-MS) U–Pb dating indicates that the gabbros were emplaced at ca. 738 Ma, indicating they are contemporaneous with mafic magmatism elsewhere in the northeastern Tibetan Plateau. The gabbros have low SiO2, Cr and Ni contents and Mg# values, are relatively enriched in light rare-earth elements (LREEs) and depleted in high-field-strength elements (HFSEs; e.g. Nb and Ta), have no positive Zr or Hf anomalies and have relatively high Nb/Ta but low Nb/La ratios. These data indicate that the Xialanuoer gabbros formed from calc-alkaline basaltic magmas that were originally generated by the partial melting of an enriched mantle of type-I (EMI-type) enriched region of the lithospheric mantle, underwent little to no crustal contamination prior to their emplacement, and have within-plate basalt geochemical affinities. Combining these data with the presence of widespread contemporaneous continental rift-related magmatism and sedimentation in the North Qilian, Central Qilian, South Qilian, Quanji, North Qaidam and East Kunlun regions suggests that the northeastern Tibetan Plateau underwent Mid-Neoproterozoic continental rifting, which also affected other Rodinian blocks (e.g. Tarim, South China, Australia, North America and Southern Africa).

The Arabian Shield of Saudi Arabia represents part of the Arabian–Nubian Shield and forms an exposure of juvenile continental crust on the eastern side of the Red Sea rift. Gabbroic intrusions in Saudi Arabia constitute a significant part of the mafic magmatism in the Neoproterozoic Arabian Shield. This study records the first detailed geological, mineralogical and geochemical data for gabbroic intrusions located in the Gabal Samra and Gabal Abd areas of the Hail region in the Arabian Shield of Saudi Arabia. Geological field relations and investigations, supported by mineralogical and geochemical data, indicate that the gabbroic intrusions are generally unmetamorphosed and undeformed, and argue for their post-collisional emplacement. Their mineralogical and geochemical features reveal crystallization from hydrous, mainly tholeiitic, mafic magmas with arc-like signatures, which were probably inherited from the previous subduction event in the Arabian–Nubian Shield. The gabbroic rocks exhibit sub-chondritic Nb/U, Nb/Ta and Zr/Hf ratios, revealing depletion of their mantle source. Moreover, the high ratios of (Gd/Yb)N and (Dy/Yb)N indicate that their parental mafic melts were derived from a garnet-peridotite source with a garnet signature in the mantle residue. This implication suggests that the melting region was at a depth exceeding ∼70–80 km at the garnet stability field. They have geochemical characteristics similar to other post-collisional gabbros of the Arabian–Nubian Shield. Their origin could be explained by adiabatic decompression melting of depleted asthenosphere that interacted during ascent with metasomatized lithospheric mantle in an extensional regime, likely related to the activity of the Najd Fault System, at the end of the Pan-African Orogeny.

The data of Joesten (1986) are re-interpreted. The petrography of the coronas is not consistent with magrnatic origin. Both microstructural types described by Joesten (1986), here re-named ‘columnar’ and ‘tabular’, formed by solid-state replacement of plagioclase and of adjacent olivine or ilmenite. Tabular microstructures are not annealed, but result from overgrowth or epitaxy of amphibole and pyroxene on pre-existing grains. Since the diffusion-controlled models of Joesten (1986) can account for major aspects of the coronas, it seems possible that a slightly modified, less simplified theory might explain them fully. Open-system behaviour must be admitted, with some constraints provided by symplectites. It may also be necessary to develop the theory in more than one dimension, and to allow for departures from local equilibrium at layer boundaries.

The first occurrence of orbicular rocks in Turkey is reported. They are gabbros in a dyke in the Baskil island-arc magmatic suite, of the southern branch of the Alpine-Himalayan chain. The orbicules have lithologically varied cores, regular shells of troctolitic composition, with a radial arrangement of olivine and plagioclase crystals, and a matrix of vari-textured gabbro. Rock and mineral analyses indicate that magmatic crystallization began near the inner margin of the troctolitic shells. Metamorphic hydration of minerals in cores, shells and matrix followed directly after the later stages of magmatic crystallization, as part of a continuous process, and thus a magmatic-metamorphic origin for the orbicules is proposed. Alternative hypotheses for the development of the orbicules are discussed: one involving the development of a protocrystalline magma shell, the other rapid crystallization during upward migration of xenolith-bearing magma.

Reactions between olivine and plagioclase form kelyphytic corona textures in the Rymmen gabbro, southern Sweden. The coronas surround olivine and consist of enstatite ± amphibole and phlogopite, combined with an outer rim of symplectic intergrowth of green spinel and amphibole. Corona reactions took place in fractures within olivine prior to the formation of chlorite, serpentine, and magnetite in the fractures at cooler conditions. Disequilibrium between olivine and plagioclase has been put forward as an explanation for the corona formation. However, inclusions of plagioclase in olivine show that there is no reaction between these minerals, since no new minerals formed between them. The conclusion drawn is that the most important factor for development of kelyphytic structures in the Rymmen gabbro is contact with a late deuteric fluid in an environment where olivine and plagioclase are close to each other. Temperature estimates for the formation of the kelyphytic coronas in the Rymmen gabbro yield consistent temperatures of around 800 ± 30°C and pressures 6–8 kbar, which indicate emplacement at a depth of 20–30 km in the crust. Late deuteric fluids caused olivine replacement by intergrown orthopyroxene and magnetite, in Fe-Ti oxide-rich rocks only. In these, plagioclase is replaced by symplectite when in contact with ilmenite and magnetite. It is noted that the symplectite minerals have low Ti contents. This suggests that the Fe-Ti oxide was a catalyst for the reaction between plagioclase and late-stage aqueous fluids rather than being a reactant, alternatively that the magnetite/ilmenite was a reactant and Ti was retained in the oxide.

The Kûngnât Complex (1275±1.8 Ma) in the Gardar Alkaline Province, South Greenland, cuts Archaean gneisses and comprises two intersecting syenitic stocks and a gabbroic ring-dyke. The magmas, with increasingly more primitive compositions, were emplaced successively by ring-faulting and roof stoping. The syenites are orthocumulates (cumulus alkali feldspar, olivine, pyroxene, titanomagnetite and apatite; intercumulus phases include alkali amphibole, biotite, quartz and calcite). In the well dissected earlier stock, a 2.2 km-thick layered sequence displays graded modal layering, feldspar lamination and cryptic layering. Modal layering in both stocks is directed mainly inwards at 35° – 50°. Heterogeneous nucleation of the cumulus assemblage, close to steep thermal boundary layers, is inferred. The modal layering is ascribed primarily to gravitational sorting aided by the large density differential between a) feldspar and b) Fe-rich silicates and oxides. Episodic collapse of cumulus + melt slurries contributed to inward-dipping crystal pediments on the chamber floors. The Ring-Dyke (up to 100 m wide) is nearly continuous through 360°. Kûngnât exhibits a compositional nearcontinuum from olivine gabbro through syenite intermediaries to alkali granite, ascribed to protracted assimilation/fractional crystallization processes. The most radiogenic Nd isotope data from Kûngnât (εNdi values between –3.3 and –1.0) point to a lithospheric mantle source, whereas the most unradiogenic values imply enrichment in LREE by crustal contamination of the magmas.

Gabbros and dolerites in the Western Gneiss Region of Norway have been subjected to a high P-T regime and preserve evidence of the existence of several stages in the consequent reaction sequence. Incomplete reaction stages are characterized by corona structures between relict igneous phases and by frequent pseudo-morphs after igneous olivine, plagioclase and augite. The increasing degree of reaction is recorded by successive increases of modal garnet, omphacite and phlogopite (±orthopyroxene) to produce eclogite, often with excellent pseudomorphic preservation of the igneous fabric.

Pseudomorphic replacement of olivine by orthopyroxene (in coronas and aggregates) and of plagioclase by local assemblages of garnet, spinel, and sodic plagioclase, is interpreted as a transient reaction stage with restricted and selective diffusion between the original mafic and felsic domains. Complete eclogitization is compatible with more extensive diffusion, especially of Na and Al (on a mm scale) leading to omphacite production by replacement of olivine, augite, and orthopyroxene. Concomitant reactions in the felsic domains lead to total replacement of the transient phases by garnet, with or without inclusions of minute omphacite grains.

Strong Ca zoning of garnet in the coronites is inter-preted as a relict growth zoning, attributed to local controls by diffusion and subreactions in the plagioclase host and to local garnet + plagioclase + spinel equilibria. In contrast, complete eclogitization is associated with diffusional homogenization of garnet by (Mg, Fe)Ca−1 and MgFe−1 exchange with omphacite ± phlogopite.

Intruded into the Palaeogene lava field and underlying Moine (Neoproterozoic) crystalline basement rocks around Loch Scridain, Isle of Mull, Scotland, is a suite of high-level, inclined, xenolithic sheets, ranging in composition from basalt, through andesite and dacite, to rhyolite. These sheets, associated with the Mull central volcano, were emplaced post 55 Ma. As well as numerous crustal xenoliths, the more basic members of the complex contain a diverse suite of ultrabasic and basic xenoliths. Xenolith types include feldspathic peridotite with cumulus olivine, pyroxenite, gabbro with cumulus plagioclase and cumulus clinopyroxene, and pure anorthosite. Mineralogical data, coupled with whole-rock major- and trace-element data from a small number of the xenoliths suggest that the xenoliths represent early-formed cumulates cognate with their host basalts. Sr and Nd isotope data from the xenoliths confirms the cognate origin, and also shows that the basic magmas suffered crustal contamination at an early stage.

Coronas of symplectic pargasite [XMg = 68, XCa = 69, XSi = 68] + spinel [SP45] and orthopyroxene [EN70] separate cumulus plagioclase [AN64] and olivine [FO64] in troctolitic gabbro from Risör, Norway. Coronas with a primary microstructure characterized by low-angle grain boundaries have the mineral assemblage layer sequence,

PLAGIOCLASE : PARGASITE + SPINEL : ORTHOPYROXENE + SPINEL : ORTHOPYROXENE : OLIVINE, whereas those with an annealed microstructure have the layer sequence,

PLAGIOCLASE : PARGASITE + SPINEL : PARGASITE : ORTHOPYROXENE : OLIVINE.

Primary symplectite consists of fan-shaped grains of pargasite that open toward plagioclase and are ribbed by rods of spinel. On annealing to a single grain, low-angle grain boundaries disappear and spinel rods rotate into parallel positions. Primary orthopyroxene, initially radial to layer contacts, anneals to a single grain, rimming olivine. Irregular discontinuous layers and plumes of symplectic orthopyroxene+spinel disappear on annealing and a monomineralic layer of pargasite forms between orthopyroxene and the amphibole symplectite.

The identity of composition of intercumulus pargasite and orthopyroxene with the same phases in primary coronas, the occurrence of primary and annealed coronas rimming cumulus ilmenite and the occurrence of radial orthopyroxene separating grains of cumulus olivine and separating cumulus olivine and plagioclase argue for the origin of primary coronas by fractional crystallization of spinel-saturated troctolitic magma at a pressure greater than 5 kbar.

Irreversible thermodynamic calculations show that the mineral assemblage layer sequence of the primary coronas is diffusionally unstable and that this instability provides the driving force for their spontaneous transformation to the stable mineral assemblage layer sequence of the annealed coronas.

The publication of the British Geological Survey memoir on Rum and the Small Isles in 1997 was followed by a period of intense petrological and mineralogical research, leading to some 40 papers, books and other publications. The research progress since then is reviewed here and integrated with the information previously available to provide an overview of the current status of understanding of the centre. New data on the acidic and mixed acid/basic magmas of the early Rum caldera demonstrate that frequent mafic replenishments were the main driver for magmatic activity at Rum right from its initial stages. The caldera is bound by the Main Ring Fault, a structure which probably also exercised an influence on the emplacement of the subsequent basic and ultrabasic intrusions. The later emplacement of gabbros and ultrabasic rocks caused only limited thermal metamorphism of the surrounding Torridonian sandstones, contrasting markedly with the crustal isotope signatures of the early intracaldera ignimbrite magmas and the intense alteration of uplifted masses of Lewisian gneiss within the ring fault. Rare picritic dykes provide an indication of the possible parent magma for the mafic and ultrabasic rocks, but these, as with most other magmatic rocks on Rum, have undergone varying degrees of crustal contamination, involving both Lewisian granulite and amphibolite-type crust but, notably, no Moine metasedimentary compositions as is the case at the nearby Ardnamurchan centre. Detailed textural studies on the gabbroic and ultrabasic rocks allow a distinction between intrusive peridotites and peridotite that forms part of the classic layered cumulate units of Rum and, furthermore, this work and that on the chromite seams and veins in these rocks shows that movement of trapped magma and magma derived from later intrusions, may produce textures regarded previously as of primary cumulate origin. Sulfides in the chromitite seams and ultrabasic rocks, in turn, show possible influences from assimilated Mesozoic sediments. Igneous activity on Rum was short-lived, possibly only between 0.5 and 1 m.y. in duration and commenced at ∼60.5 Ma. The Rum Central Complex was extinct by the time the main activity at the nearby Skye Central Complex commenced (∼59 Ma). From recent apatite fission-track studies it seems probable that Rum, in common with other Palaeogene centres, underwent a brief, but significantly later heating event (∼45 Ma).

The South Dehshir Ophiolite, exposed along the southwestern margin of the Central Iranian microcontinent, comprises a mantle and a crustal sequence. This massif contains serpentinized peridotites, gabbros and diabase sheeted dykes cutting across wherlite, pegmatitic gabbro and plagiogranite, and is tectonically covered by radiolarites, pelagic limestones with Late Cretaceous microfauna and lavas. Under a microscope, the gabbros exhibit mesocumulate, adcumulate and hetradcumulate textures presumably formed in open magma chambers. Hypabyssal and lava samples show tholeiitic to calc-alkaline affinities, and their compositions cluster in the fields of arc or supra-subduction zone magmatism. Binary diagrams display compositional trends of magmatic differentiation, plotting away from the mid-ocean-ridge basalt (MORB) (tholeiitic) trend and following the arc (calc-alkaline) trend. Rare Earth element (REE) and spider diagrams display various enrichments at different levels. Moderate enrichment of the large-ion lithophile elements (LILE; Rb, Ba, Th, U, La, Sr) relative to the high-field-strength elements (HFSE; Nb, Ta) and slight depletion of Ti and Zr in some patterns may be attributed to variable influences of subduction components over the depleted mantle wedge. Elemental ratios display evidence for the contribution of both fluids and melt released from the subducted slab. Few patterns display ocean-island basalt (OIB) characteristics, possibly attributed to the involvement of local mantle plumes on the partial melting of the mantle wedge. This evidence indicates that the crustal rocks of the South Dehshir Ophiolite formed in a supra-subduction zone.

The plutonic crustal sequence exposed northeast of Sabzevar is part of the ophiolitic belt of Sabzevar that occurs along the northern margin of the Central Iran micro-continent. The sequence includes olivine and pyroxene gabbro with cumulate characteristics, isotropic gabbro, foliated gabbro and a diabase sheeted dyke complex cut by wehrlite and olivine websterite intrusions, and pegmatite gabbro and plagiogranite as small intrusions and dykes. The sequence is comparable to gabbros in known ophiolite complexes. Microscopic studies show an abundance of the mesocumulate and heteradcumulate textures that represent open system magma chambers, which are common in supra-subduction zones. The olivine → plagioclase → clinopyroxene → ± orthopyroxene → amphibole trend of mineralization in the gabbros, similar to mid-ocean ridge basalt (MORB), and olivine → clinopyroxene → ± orthopyroxene → plagioclase → amphibole, similar to arc rocks, indicate the diversity in the formation of these rocks, and represent petrographic evidence of their formation in a supra-subduction zone. The rocks have calc-alkaline to tholeiitic affinities, and niobium depletion in the spider diagrams of diabase that matches the patterns of island arc magma. These patterns, and the light rare earth element enrichment of the diabase and plagiogranite, suggest the effect and introduction of the fluids, originating from the subducting slab, beneath the mantle wedge. The low titanium compositions, matching those of arc diabase and plagiogranite, plot in the island arc to MORB tectonomagmatic fields, and suggest formation of the Sabzevar ophiolitic plutonic crustal sequence in a supra-subduction zone during Late Cretaceous time.

The Kızıldağ (Hatay) ophiolite in Turkey represents remnants of the southern Neotethyan ocean and is characterized by a complete ocean lithospheric section. It formed in a fore-arc setting above a N-dipping intraoceanic subduction zone, and represents the undeformed, more northerly part of the same thrust sheet that also forms the Baer–Bassit ophiolite to the south. The ophiolite was emplaced southwards from the southerly Neotethyan ocean in Maastrichtian time. U–Pb and Sm–Nd dates are used to constrain the crystallization age and duration of magmatic activity of the Kızıldağ ophiolite. U–Pb dating yielded ages of 91.7 ± 1.9 Ma for a plagiogranite and 91.6 ± 3.8 Ma for a cumulate gabbro. The cumulate gabbro also yielded a Sm–Nd isochron age of 95.3 ± 6.9 Ma. The measured ages suggest that the oceanic crust of the Kızıldağ ophiolite formed in a maximum time period of 6 Ma, and that the plagiogranite may have formed later than the gabbroic section. The U–Pb zircon ages from the Kızıldağ ophiolite and the cooling age of a metamorphic sole beneath the Baer–Bassit ophiolite are indistinguishable within the analytical uncertainties. This indicates the presence of young and hot oceanic lithosphere at the time of intraoceanic subduction/thrusting in the southern Neotethys. The U–Pb zircon ages from the Kızıldağ, the Troodos and the Semail ophiolites overlap within analytical uncertainties, suggesting that these ophiolites are contemporaneous and genetically and tectonically related within the same Late Cretaceous southern Neotethyan ocean.

Zoned olivine grains are abundant in the late Mesozoic Shatuo gabbro (southern Taihang Mountains, central North China Craton). Olivine cores are rich in MgO and NiO, rims are rich in FeO and MnO, and both cores and rims have very low CaO contents. The cores invariably have a high Mg no. (92–94), similar to olivine xenocrysts from Palaeozoic kimberlites in eastern China. The compositional features of these olivines imply that they are xenocrysts rather than phenocrysts, namely, disaggregates of mantle peridotites at the time of intrusion. The compositional similarity of olivine cores to xenocrysts from Palaeozoic kimberlites suggests that the lithospheric mantle beneath the central North China Craton is ancient and refractory in nature, and quite different from eastern China, where the mantle is mainly composed of newly accreted materials resulting from large-scale lithospheric removal and replacement. The contrasting features of the lithospheric mantle beneath the eastern and central North China Craton imply that the large-scale lithospheric removal in Phanerozoic times was mainly confined to the eastern North China Craton.

Trace element inversion modelling of Grenvillean anorthosite massifs and associated rocks yield NMORB-normalised trace element profiles enriched in highly incompatible elements; commonly with negative Nb and Th anomalies. Model melts can be divided into subtypes that cannot be linked through fractional crystallisation processes. Most model melts are depleted in the heavy rare-earth elements and can be explained by partial melting of arc basaltic sources (5–60 melting ) with garnet-bearing residues. Some of the model melts have flat NMORB-normalised profiles (for rare-earth elements), have high compatible element contents, and might have been derived from mantle fertilised by arc magmatism, followed by low-pressure fractional crystallisation. Intermediate Ce/Yb types may represent mixtures of these end-members, or less probably, variations in the crustal source composition and residual assemblage. The active tectonic context now favoured for the Grenville Province appears to be inconsistent with plume or thermal insulation models. The heat source for crustal and mantle melting could record either post-orogenic thermal relaxation of a tectonically-thickened arc crust, or basaltic underplating caused by delamination of a mantle root or subduction slab beneath this arc crust. In this context, pre-Proterozoic anorthosites may be lacking, because prior to ca. 2·5 Ga, the crust may have been too weak to be thickened tectonically. The absence of post-Proterozoic anorthosites may be due to the secular decrease in radiogenic heating and cooling of the mantle and crust.

The Xiaofangshen mafic stock is a hornblende gabbroic body emplaced in the Faku dome of northern Liaoning within the continental interior of the North China–Mongolian plate. Zircon U–Pb SHRIMP dating yields an emplacement age of 241 ± 6 Ma. These gabbroic rocks exhibit strong enrichment in large ion lithophile elements (e.g. Th, U) and light REE, slightly negative Eu anomalies, and pronounced depletion in high field strength elements (e.g. Nb, Ta, Zr, Ti). They show a relatively narrow range of isotopic compositions with initial 87Sr/86Sr ratios of 0.7053 to 0.7055, ϵNd(t) values of +0.40 to +0.68 and zircon ϵHf(T) values from +5.0 to +7.4. These geochemical features suggest that they might have been derived from partial melting of a subduction-related metasomatized lithospheric mantle source, which is tectonically affiliated to the Xing-Meng orogenic belt. Combined with our previous geochronological dating on the predominantly granitic intrusions from the Faku dome, it is inferred that the northern Liaoning block has a tectonic affinity with the Phanerozoic accretionary orogenic belt. This revelation further leads to the proposition that the Chifeng–Kaiyuan fault likely represents the Mesozoic lithospheric boundary between the North China craton and the Xing-Meng orogenic belt in northern Liaoning. The Xiaofangshen gabbros, together with the Triassic mafic–ultramafic cumulates and granulite xenoliths and the Triassic alkaline intrusions within the continental interior of the newly amalgamated North China–Mongolian Plate, constitute an important post-orogenic to within-plate anorogenic magmatic province, in response to the continued magmatic underplating caused by lithospheric delamination and hot asthenosphere upwelling.

A volcano-plutonic complex in the Susa area, southwest Japan, consists of the Yamashima andesites, the Koyama gabbros and syn-plutonic porphyrite dykes derived from a common basaltic andesite magma. The complex is closely associated with middle Miocene turbidite deposits. The Yamashima andesites are composed mainly of basaltic andesite feeder dykes, massive submarine lavas with hyaloclastites, and their reworked deposits. The lavas and deposits immediately overlie turbidite deposits, indicating submarine volcanic activity. The Koyama gabbros formed hornfels by contact metamorphism of the surrounding turbidites and andesites. Highly purified clinopyroxene and plagioclase mineral separates from the Yamashima andesites were dated by a K–Ar method using an ultra-low blank K analysis procedure. Ages obtained from duplicate analyses are 16.5±1.5, 15.2±1.4, 15.8±1.7, and 16.5±2.0 Ma for clinopyroxene, and 14.2±0.8, 15.2±0.9, and 15.6±0.9 Ma for plagioclase. The clinopyroxene and plagioclase data define a mineral isochron age of 14.7±0.9 (1σ) Ma with an initial 40Ar/36Ar ratio of 297.3±2.4 (1σ), suggesting that clinopyroxene has no excess argon and can be reliably dated by K–Ar. Most of the groundmass ages are considerably younger (12.1–14.6) than the isochron age, perhaps due to argon loss during alteration. The gabbros give ages of 14.2±0.3 and 14.1±0.3 Ma for biotite, and 13.7±0.3 and 13.7±0.7 Ma for green hornblende. The porphyrite dyke yields an age of 12.5±0.3 Ma for the groundmass, and the pelitic hornfels gives a biotite age of 14.8±0.3 Ma. Our new K–Ar ages, together with previous studies, show that a series of geological events took place in the Susa area between 16 and 13 Ma. Conglomerates and sandstones were deposited in the beginning of marine transgression. Subsequent abrupt deepening led to deposition of a thick black shale unit, turbidite deposits and large-scale submarine channel-fill deposits. Coeval igneous activity formed the volcano-plutonic complex. The magmato-tectonic event was synchronous with the opening of the Japan Sea and the associated clockwise rotation of the southwest Japan arc sliver, recording a unique tectonic setting.

Plutonic complexes with interlayered mafic and silicic rocks commonly contain layers (1–50 m thick) with a chilled gabbroic base that grades upwards to dioritic or silicic cumulates. Each chilled base records the infusion of new basaltic magma into the chamber. Some layers preserve a record of double-diffusive convection with hotter, denser mafic magma beneath silicic magma. Processes of hybridisation include mechanical mixing of crystals and selective exchange of H2O, alkalis and isotopes. These effects are convected away from the boundary into the interiors of both magmas. Fractional crystallisation aad replenishment of the mafic magma can also generate intermediate magma layers highly enriched in incompatible elements.

Basaltic infusions into silicic magma chambers can significantly affect the thermal and chemical character of resident granitic magmas in shallow level chambers. In one Maine pluton, they converted resident I-type granitic magma into A-type granite and, in another, they produced a low-K (trondhjemitic) magma layer beneath normal granitic magma. If comparable interactions occur at deeper crustal levels, selective thermal, chemical and isotopic exchange should probably be even more effective. Because the mafic magmas crystallise first and relatively rapidly, silicic magmas that rise away from deep composite chambers may show little direct evidence (e.g. enclaves) of their prior involvement with mafic magma.

The Precambrian basement on the islands of Islay, Colonsay and Inishtrahull comprises a deformed igneous association of mainly syenite and gabbro, with minor mafic and felsic intrusions. This association is collectively referred to as the Rhinns Complex. Isotopic data indicate that the complex represents new addition of material to the crust at c. 1·8 Ga. The igneous protolith was juvenile mantle-derived material, not reworked Archaean crust. Overall, the complex has an alkalic composition, with major and trace element patterns similar to igneous rocks generated in a subduction-related setting: high LILE/HFSE and LREE/HREE ratios, together with negative Nb, P and Ti anomalies.

The formation of the Rhinns Complex was contemporaneous with the Laxfordian tectonothermal cycle in the Lewisian Complex. These Proterozoic events are most likely associated with an extensive 1·9–1·7 Ga mobile belt around the southern margin of Laurentia-Baltica. As part of this belt, the Rhinns Complex forms a link between the Ketilidian province of South Greenland and the Svecofennian of Scandinavia.

Inherited isotopic signatures in the Caledonian granites on the north side of the Highland Boundary Fault may reflect the presence of a large area of Proterozoic basement (?Rhinns Complex) beneath Scotland and NW Ireland. Alternatively, the Proterozoic signature could be derived from the incorporation of Moine or Dalradian sediment into the granitic magmas.