When tank mixed with certain boadleaf-selective herbicides, fluazifop {(+)-2-[4-[[5-(trifluoromethyl)-2-pyridinyl] oxy] phenoxy] propanoic acid}, sethoxydim {2-[1-(ethoxyimino)butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one}, haloxyfop {2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl] oxy] phenoxy] propanoic acid}, and fluazifop-P {(R)-2-[4-[[5-trifluoromethyl)-2-pyridinyl] oxy] phenoxy] propanoic acid} were less effective in controlling two annual grasses, Texas panicum (Panicum texanum Buckl. #3 PANTE) and large crabgrass [Digitaria sanguinalis (L.) Scop. # DIGSA]. These herbicides were applied alone or were combined with the broadleaf-selective herbicides bentazon {3-(1-methylethyl)-(1H)-2,l,3-benzothiadiazin-4(3H)-one-2,2-dioxide} and/or 2,4-DB [4-(2,4-dichlorophenoxy)butanoic acid]. The herbicide combinations controlled smooth pigweed (Amaranthus hybridus L. # AMACH) and yellow nutsedge (Cyperus esculentus L. #CYPES). Increasing the rates of the grass-selective herbicides in the mixture reduced the adverse effects of 2,4-DB or bentazon.

Effects of temperature, sunlight, soil incorporation and surface irrigation on the phytotoxicity of oryzalin (3,5-dinitro-N4,N4 -dipropylsulfanilamide) were studied. The activity of oryzalin applied 4 to 6 weeks prior to planting was enhanced by covering the soil with plastic as measured by the inhibition of grain sorghum [Sorghum bicolor (L.) Moench. 'Sexauer G-701′] root growth. Growth chamber studies demonstrated that oryzalin phytotoxicity to grain sorghum was greater at 20 and 25 C than at 30C. The control of foxtail millet [Setaria italica (L.) Beauv. #5 SETIT] bristly foxtail [Setaria verticillata (L.) Beauv. # SETVE], redroot pigweed (Amaranthus retroflexus L. # AMARE), and smooth pigweed (Amarantbus hybridus L.), and injury to grain sorghum increased as the thoroughness of mechanical incorporation of oryzalin into soil increased. The phytotoxicity of surface-applied oryzalin increased with increasing amounts of irrigation water until it equaled the level of a preplant-incorporated treatment.

Greenhouse studies were conducted to determine host status of weed species for Rhizoctonia solani AG-1, which causes Rhizoctonia foliar blight of soybean. Weed species were barnyardgrass, broadleaf signalgrass, common cocklebur, entireleaf morningglory, hemp sesbania, itchgrass, johnsongrass, large crabgrass, northern jointvetch, prickly sida, purple nutsedge, redweed, sicklepod, and smooth pigweed. Seedling weeds were inoculated with suspensions containing intraspecific group IA and IB isolates of the fungus. In the first study, sclerotia of IA were recovered from tissue of all weeds except smooth pigweed, and mycelia of IA were recovered from all except smooth pigweed and redweed. In that study, neither microsclerotia nor mycelia of IB were recovered from sicklepod, barnyardgrass, or large crabgrass, and only microsclerotia were recovered from itchgrass and purple nutsedge. In the second study, sclerotia of IA, microsclerotia of IB, and mycelia of each isolate were recovered from all weed species. In other studies, R. solani spread from at least six of seven weed species to a noninfected soybean plant growing in close proximity. These studies emphasize the importance of weed control, not only for reducing plant competition and increasing yield, but also for the potential impact on development of RFB.

Triazine-susceptible (S) and -resistant (R) biotypes of smooth pigweed (Amaranthus hybridus L.) were grown in the field under competitive conditions at varying initial proportions of S and R plants. R plants were less competitive than S plants as measured by accumulation of total above-ground dry weight and seed dry weight. S and R plants were also grown in the field under non-competitive conditions at 100, 40, and 10% light. Growth rate at 10% light did not differ between S and R plants. At the two higher light intensities, dry-matter accumulation 11 weeks after seeding was about 40% less in the R plants. At 100% light, relative growth rate and net assimilation rate were lower in the R plants by about 3.5 and 19%, respectively. The light- and CO2-saturated rates of CO2 fixation in intact leaves of glasshouse-grown R plants were 20% less than those in S plants. An apparent 10 and 20% greater number of chlorophyll molecules per photosystem II reaction center in R plants (as compared with S plants) grown in the field at 40 and 100% light, respectively, did not explain differences between the S and R biotypes in photo synthetic capacity. The S and R plants did not differ in specific leaf weight or chlorophyll content on a leaf-area basis. Lower growth rate of R plants may be responsible for inferior competitive ability of R biotypes and could be the result of an impaired photosynthetic capacity.

In order to find the most effective and economical method of incorporation, six preplant herbicides for cotton (Gossypium hirsutum L.) were incorporated with a tandem disk or field cultivator, or sprayed on unbedded soil prior to bedding with a disk bedder. These treatments were compared to incorporating sprayed beds with a rolling cultivator and no incorporation. A mixed population of pigweed (Amaranthus hybridus L. # AMACH and Amaranthus retroflexus L. # AMARE) was present each year. There was no significant difference in pigweed control among incorporation with a disk, field cultivator, or rolling cultivator. Puncturevine (Tribulus terrestris # TRBTE) and barnyardgrass [Echinochloa crus-galli (L.) Beauv. # ECHCG] were controlled best following rolling cultivator incorporation. Cotton lint yields were not affected by incorporation methods or herbicides. Economic analysis and weed control indicate that the field cultivator was the best way of incorporation.

Greenhouse studies were conducted to investigate the effects of adjuvant and rainfall on bentazon spray retention, efficacy, and foliar washoff in hemp sesbania, sicklepod, smooth pigweed, and velvetleaf. Bentazon was applied at 0.28 to 2.24 kg ai/ha with Agri-Dex, a crop oil concentrate (COC) or Kinetic, an organiosilicone-nonionic surfactant blend (OSB) when weeds were at the three- to five-leaf stage. Plants were subjected to 2.5 cm simulated rainfall for 20 min at 1 and 24 h after application of bentazon. Shoot fresh weight reduction assessed 2 wk after treatment was similar with either adjuvant on velvetleaf and smooth pigweed. OSB enhanced bentazon efficacy in hemp sesbania and sicklepod as compared to COC. Rainfall at 1 h after application generally reduced bentazon activity in all weeds. OSB maintained bentazon activity in hemp sesbania when subjected to rainfall at 1 h after application as compared to COC. Overall, bentazon spray retention on plants was 9 to 550% higher with OSB as compared to COC among the species at 1 h after application. Amount of bentazon residue washed off from the foliage by rainfall within a weed species was relatively similar for both adjuvants except in smooth pigweed and ranged from 39 to 98% among the four weed species at 1 h after application. OSB exhibited specificity for certain weed species and the potential to minimize bentazon spray reaching the soil by increasing deposition.

Tolerance of direct-seeded pepper under clear plastic mulch to herbicides applied pre- and post-emergence was investigated in 1991 and 1992. Weed control of herbicides applied preemergence was also studied. Paprika cultivar ‘Buketen’ and canning cultivars ‘Piquillo de Lodosa’ and ‘Pico de Mendavia’ were seeded in the field in Zaragoza, Spain, in a loamy soil. Percent emergence, plant mortality after the postemergence treatment, dry weight of plants, and fruit weight were recorded. Pepper was tolerant to diphenamid and napropamide applied preemergence but these herbicides did not control broadleaf weeds. Clomazone, when applied preemergence resulted in chlorotic seedlings and at 2 kg ai/ha reduced the final stand, but was selective when applied at the 6 to 8-leaf stage of the crop. Pepper was tolerant to diethatyl-ethyl when applied preemergence. However, diethatyl-ethyl applied postemergence caused severe phytotoxicity symptoms, and when mixed with diphenamid, fruit ripeness in 1992 was delayed. Weed control during the crop emergence period was better when diethatyl-ethyl was used mixed with diphenamid or napropamide.

A comparison of the structure of the α-methylbenzyl analogue (MBAT) of atrazine with the Photosystem II herbicides atrazine [6-chloro-N-ethyl-N′-(1-methylethyl)-1,3,5-triazine-2,4-diamine] and diuron [N′-(3,4-dichlorophenyl)-N,N-dimethylurea] suggested that N-alkylbenzyltriazines may be a structural bridge between the triazines and the phenylureas. In the phenylureas, the addition of chlorines at the meta and/or para positions produces a marked increase in activity. Chloro-substituted derivatives of MBAT were synthesized to determine whether this structure-activity relationship also applies to the alkylaryltriazines. Addition of a chlorine to MBAT at the 4-position (CMBAT) caused a substantial increase in intrinsic activity, and a second chlorine at the 3-position (DCMBAT) caused a further increase. In direct comparisons, DCMBAT was more active in vitro than terbuthylazine [6-chloro-N-ethyl-N′-(1,1-dimethylethyl)-1,3,5-triazine-2,4-diamine], the most active chlorotriazine, and was also more active than diruon. The effects of DCMBAT were also measured on triazine-resistant pigweed (Amaranthus hybridus L. # AMACH) both in vivo and in vitro. The activity of this compound in triazine-resistant chloroplasts was intermediate between that of atrazine and diruon both in inhibition of photosynthetic electron transport and in competition for diuron binding sites, with half-maximal values falling in the micromolar range. Whole plant phytotoxicity of DCMBAT on triazine-resistant pigweed was also intermediate between that of diuron and atrazine. Since DCMBAT is a triazine with biological properties similar to that of a urea, we conclude that in a functional as well as structural sense, DCMBAT is a herbicide that is a hybrid between a triazine and a urea.

Field experiments were conducted from 1993 to 1995 to compare weed control by the isopropylamine salt of glyphosate at 0.21, 0.42, 0.63, and 0.84 kg ae/ha applied at three stages of weed growth. Weed control by glyphosate applied at these rates alone or with ammonium sulfate at 2.8 kg/ha was also evaluated. In other experiments, potential interactions between glyphosate and acifluorfen, chlorimuron, and 2,4-DB were evaluated. Velvetleaf, prickly sida, sicklepod, pitted morningglory, entireleaf morningglory, palmleaf morningglory, and hemp sesbania were controlled more easily when weeds had one to three leaves compared with control when weeds had four or more leaves. Glyphosate controlled redroot pigweed, velvetleaf, prickly sida, sicklepod, and barnyardgrass more effectively than pitted morningglory, entireleaf morningglory, palmleaf morningglory, or hemp sesbania. Increasing the rate of glyphosate increased control, especially when glyphosate was applied to larger weeds. Greater variation in control was noted for pitted morningglory, palmleaf morningglory, prickly sida, and velvetleaf than for redroot pigweed, sicklepod, entireleaf morningglory, or hemp sesbania. Ammonium sulfate increased prickly sida and entireleaf morningglory control but did not influence sicklepod, hemp sesbania, or barnyardgrass control. Acifluorfen applied 3 d before glyphosate or in a mixture with glyphosate reduced barnyardgrass control compared with glyphosate applied alone. Chlorimuron did not reduce efficacy. Mixtures of glyphosate and 2,4-DB controlled sicklepod, entireleaf morningglory, and barnyardgrass similar to glyphosate alone.

An experiment was conducted at four locations in North Carolina during 1994 and 1995 to evaluate weed control, cotton yield, fiber quality, and net returns in no-tillage bromoxynil-tolerant cotton. The experiment focused on using bromoxynil or pyrithiobac sodium applied early POST over-the-top as alternatives to fluometuron plus MSMA applied early POST directed. Fluometuron plus MSMA was more effective than bromoxynil or pyrithiobac sodium on tall morningglory, large crabgrass, goosegrass, and broadleaf signalgrass. Bromoxynil and fluometuron plus MSMA were similarly effective on common lambsquarters, common ragweed, and eclipta and more effective than pyrithiobac sodium. Pyrithiobac sodium and fluometuron plus MSMA were similarly effective on smooth pigweed and Palmer amaranth and more effective than bromoxynil. Prickly sida control by bromoxynil and pyrithiobac sodium was equal to or greater than control by fluometuron plus MSMA. All early POST herbicides controlled pitted morningglory similarly. Regardless of the early POST herbicides used, fluometuron applied PRE and cyanazine plus MSMA applied late POST directed increased control of most weeds and increased cotton yield and net returns. Bromoxynil and pyrithiobac sodium effectively substituted for fluometuron plus MSMA only in systems that included fluometuron applied PRE and cyanazine plus MSMA applied late POST directed. Effects of herbicide systems on cotton fiber quality were minor.

In field studies in 1991, 1992, and 1993, rimsulfuron at 26 and 35 g ai/ha, sequentially at 26 g/ha, at 26 g/ha plus metribuzin at 280 g ai/ha, and metribuzin at 280 g/ha were evaluated POST for weed control in transplanted ‘Agriset’ tomato. Common lambsquarters was controlled by rimsulfuron at 35 g/ha. Rimsulfuron plus metribuzin gave consistent control of common ragweed, but jimsonweed control was inconsistent and goosegrass control was generally low. Rimsulfuron treatments caused slight (< 12%) temporary injury to new terminal growth of tomato. Yield of tomato fruit was consistently high in the metribuzin, metribuzin plus rimsulfuron, and rimsulfuron sequential treatments. In greenhouse studies, giant foxtail and large crabgrass control by rimsulfuron was above 95 and 85%, respectively, but goosegrass was not controlled. Height of four tomato cultivars was not reduced, but dry weight of ‘Floradade’ and ‘Sunbeam’ was reduced by rimsulfuron.

Cotton (Gossypium hirsutum L. ‘Stoneville 213’) was grown on Lucedale fine sandy loam with sicklepod (Cassia obtusifolia L. ♯ CASOB) and a complex of redroot pigweed (Amaranthus retroflexus L. ♯ AMARE) and smooth pigweed (A. hybridus L. ♯ AMACH) in all possible combinations of 0, 1, 2, 4, 8, and 16 weeds of each species per 7.5 m of row. Seed cotton yields decreased as a quadratic function of increasing weed density. One pigweed and one sicklepod plant per 7.5 m of row reduced yields by 9 and 9.7% in 1979 and 1980, respectively. At low levels of infestation (≤4 weeds/7.5 m of row), the competitive effect of pigweed and sicklepod was additive; however, at the high densities, the competitive effect was not additive. Mechanical harvesting efficiency and cotton maturity were not decreased by any weed density. Sicklepod was more competitive than pigweed in both years.

Sensitivity of 49 tomato cultivars and four weeds to DPX-E9636 was determined in greenhouse experiments. Cultivar tolerance varied from completely tolerant to intolerant. The most efficacious application method in greenhouse experiments was early POST for the weeds tested (yellow nutsedge, prostrate eclipta, and paraquat-resistant and -sensitive American black nightshade). Paraquat-resistant American black nightshade was 123 times more sensitive to DPX-E9636 than the paraquat-sensitive biotype. Under field conditions and at 0, 36, or 72 g ai/ha applied one week after transplanting, tomato cultivars showed no response to DPX-E9636 in visual vigor ratings 3 wk treatment, or in shoot fresh or dry weight 4 wk after treatment.

Eight field studies were conducted in soybeans at seven locations in Kansas over a 3-yr period to examine the efficacy of using reduced rates of the herbicides acifluorfen, bentazon, chlorimuron, and tank mixes of acifluorfen and bentazon. POST applications of these herbicides at 1/2X rates at 2 wk after planting (WAP) resulted in broadleaf weed control similar to that obtained from standard treatments of 1X rates applied at 4 WAP at six of seven studies with acifluorfen, bentazon, and acifluorfen plus bentazon and at five of seven studies with chlorimuron. One-quarter rates applied 2 WAP were equivalent to standard treatments for broadleaf weed control in four of seven studies with acifluorfen and chlorimuron, five of seven studies with bentazon, and six of seven studies with acifluorfen plus bentazon. One cultivation at 4 WAP, increased the broadleaf weed control with all herbicide treatments.

Three levels of weed control (0, 70, and 100%) were maintained in 1989 during corn production at two sites. Weed control in 1990 with a premix formulation of metolachlor and atrazine was directly related to 1989 control levels. Herbicides generally were more effective in conventional tillage than in no-tillage. In no-tillage, giant foxtail control in 1990 averaged 59% following 100% control in 1989 compared to 15% following 0% weed control. At one location, tillage minimized the impact of the prior year's weed control with herbicides providing greater than 85% control in conventional tillage regardless of prior history. In no-tillage, weed control of 85% or better was obtained only following 100% control the previous year.

Effects of temperature and interference were examined in a replacement series experiment with soybean [Glycine max (L.) Merr. ‘Ransom’], common cocklebur (Xanthium pensylvanicum Wallr.), and smooth pigweed (Amaranthus hybridus L.). Plants were grown in controlled-environment greenhouses at day/night temperatures of 32/23, 29/20, or 26/17C and harvested 14 and 34 days after planting. In all species, height, dry weight, and leaf area at both harvests, and dry matter and leaf area duration for the harvest interval, increased significantly with temperature. Net assimilation rate in all species peaked at 29/20C. Dry weight and leaf area at day 34, and dry matter production and leaf area duration for the harvest interval, were reduced in plants subjected to interference. Temperature modified the effects of interference upon growth in smooth pigweed, but not in the other species. Common cocklebur and soybean were roughly equivalent as competitors at all temperatures and were superior to smooth pigweed.

Field studies were conducted from 1984 to 1986 to assess cabbage injury and yield response to several acetanilide herbicides. When incorporated, metolachlor significantly injured cabbage and reduced yields while post-transplant applications caused foliar flecking but did not reduce yields. Crop injury from pretransplant applications of 4.4 kg ai/ha was significant for all herbicides in both 1985 and 1986. Although total yields in 1985 and 1986 were comparable, maturity was delayed in 1986. With few exceptions, the acetanilides did not differ in either injury or yield-reducing potential. However, compared to trifluralin, metolachlor reduced yields in both years and at both rates.

The cross-resistance of triazine-resistant biotypes of smooth pigweed (Amaranthus hybridus L. # AMACH), common lambsquarters (Chenopodium album L. # CHEAL), common groundsel (Senecio vulgaris L. # SENVU), and the crop canola (Brassica napus L. var. Atratower) to a selection of herbicides was evaluated at both the whole plant and chloroplast level. The triazine-resistant biotypes of all four species showed a similar pattern of cross-resistance, suggesting that a similar mutation had occurred in each species. The four triazine-resistant biotypes were resistant to injury from atrazine [6-chloro-N-ethyl-N′-(1-methylethyl)-1,3,5-triazine-2,4-diamine], bromacil [5-bromo-6-methyl-3-(1-methylpropyl)-2,4-(1H,3H)pyrimidinedione], and pyrazon [5-amino-4-chloro-2-phenyl-3(2H)-pyridazinone] and were slightly resistant to buthidazole {3-[5-(1,1-dimethylethyl)-1,3,4-thiadiazol-2-yl]-4-hydroxy-1-methyl-2-imidazolidinone}. The triazine-resistant biotypes were more sensitive to dinoseb [2-(1-methylpropyl)-4,6-dinitrophenol]. Triazine-resistant smooth pigweed showed resistance to cyanazine {2-[[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl] amino]-2-methylpropanenitrile} and metribuzin [4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one] with slight resistance to linuron [N′-(3,4-dichlorophenyl)-N-methoxy-N-methylurea] and desmedipham {ethyl [3-[[(phenylamino)carbony] oxy] phenyl] carbamate}. There was little or no resistance to diuron [N′-(3,4-dichlorophenyl)-N,N-dimethylurea], bromoxynil (3,5-dibromo-4-hydroxybenzonitrile), bentazon [3-(1-methylethyl)-(1H)-2,1,3-benzothiadiazin-4(3H)-one 2,2-dioxide], or dicamba (3,6-dichloro-2-methoxybenzoic acid). Parallel studies at the chloroplast level indicated that the degree of resistance to inhibition of photosynthetic electron transport was highly correlated with the degree of resistance to herbicidal injury. This correlation indicates that atrazine, cyanazine, metribuzin, pyrazon, bromacil, linuron, desmedipham, and buthidazole cause plant injury by inhibition of photosynthesis. This correlation also indicates that triazine resistance and cross-resistance at the whole plant level is due to decreased sensitivity at the level of photosynthetic electron transport. Cross-resistance to numerous additional herbicides was evaluated on isolated chloroplast thylakoid membranes and these results are discussed. 14C-atrazine was displaced from thylakoid membranes by several herbicides, indicating that these herbicides compete for a common binding site.

In field tests, common cocklebur (Xanthium pensylvanicum Wallr.) was controlled at the one- and two-leaf stages with 0.3 kg/ha acifluorfen {5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoic acid}. Four-leaf common cocklebur required 1.1 kg/ha for comparable control. Acifluorfen at 0.6 and 0.8 kg/ha controlled 96 and 90% of entireleaf morningglory [Ipomoea hederacea (L.) Jacq. var. integriuscula] atone- and two-leaf stages, respectively, but control was reduced as plants aged. Dark applications (2100 h) were more effective than those at sun-up (0600 h) or midday (1200 h) in control of hemp sesbania [Sesbania exaltata (Raf.) Cory], pitted morningglory (Ipomoea lacunosa L.), and smooth pigweed (Amaranthus hybridus L.). Hour of application had no significant influence on control of common cocklebur or prickly sida (Sida spinosa L.). An increase in surfactant (80% alkyl aryl polyoxyethylene glycols) concentration enhanced acifluorfen control of entireleaf morningglory and Texas gourd [Cucurbita texana (A.) Gray] at the 0.3-kg/ha rate applied 2 weeks after emergence. Soybean [Glycine max (L.) Merr.] injury was increased with the 1.1-kg/ha rate when surfactant concentration was increased from 0.5 to 0.75%. Increasing the spray volume increased pitted morningglory control but decreased hemp sesbania control. In the growth chamber, better control of pitted morningglory and common cocklebur was obtained at high (35 C day, 26 C night) than at low temperatures (27 C day, 18 C night) when plants were treated 1 week after emergence.

The role of preplant glyphosate applications and residual herbicides in the efficacy of glyphosate for weed management in double-crop no-till glyphosate-resistant soybean (GRS) was investigated in the coastal plains of Mid-Atlantic United States. The experiment had a two- by two- by five-factorial treatment structure laid out in three or four randomized complete blocks at research centers in Delaware and New Jersey. The factors investigated were preplant weed management: preplant or no preplant glyphosate applications; postemergence (POST) herbicide treatments: 0.8 kg ae/ha glyphosate alone or 0.8 kg/ha glyphosate tank-mixed with 0.6 kg ai/ha clomazone plus 0.07 kg ai/ha imazethapyr; and GRS growth stage at herbicide application which ranged from cracking, 5 to 8 d after planting, (DAP) to the V6 stage (35 DAP). Preplant glyphosate applications did not influence the efficacy of POST glyphosate applications alone or with the residual herbicides. Glyphosate alone or with clomazone plus imazethapyr provided excellent control of horseweed and fall panicum irrespective of the time of herbicide application from GRS at cracking to the V6 stage. With other weed species, residual herbicide influence varied with year, weed species, and GRS growth stage at herbicide application. Generally, glyphosate alone was most effective when applied at the V2 to V6 stages (16 to 35 DAP). A tank-mix of glyphosate with clomazone plus imazethapyr extended this window to include applications at GRS cracking and the V1 stage. Herbicide treatments were safe on GRS at all stages of application up to the V6 stage (35 DAP).