The proposed correlation of Lower Old Red Sandstone dacitic ignimbrites between the Northern Midland Valley and Grampian terranes of central Scotland has been investigated in a combined palaeomagnetic and geochemical study. Statistically indistinguishable late Silurian palaeolatitudes (Grampian terrane 27.0° S±3.5°; Northern Midland Valley terrane 22.9° S± 1.8°), comparable remagnetization histories, a shared ‘normal’ polarity for the primary magnetization and equivalent gyroremanence acquisition, favour correlation across the Highland Boundary Fault. Similar chemistry for biotite phenocrysts further corroborates correlation which was initially made on the basis of a similar field appearance and petrography.

This correlation, together with evidence from provenance studies, suggests that the separation of the Northern Midland Valley and Grampian terranes inferred for the Ordovician period was largely removed by late Silurian times, with scope for relative displacements of the order of only tens of kilometres after Lower Old Red Sandstone deposition.

The Skiddaw Group in the Cross Fell inlier comprises the Catterpallot Formation of latest Tremadoc or earliest Arenig age, the Murton Formation of Arenig age, and the Kirkland Formation of early Llanvirn age. Each of these formations can be correlated with formations in the Skiddaw Group of the Lake District. The faulted contact of the Catterpallot and Kirkland formations is the probable extension of the Causey Pike Fault (CPF), which separates two distinct sequences in the Skiddaw inlier of the northern Lake District. Contrasts across the CPF in the Cross Fell inlier reflect those seen in the Skiddaw inlier. The CPF is a major basement structure, separating markedly different successions in the Ordovician strata of northern England.

Ultramafic xenoliths from Madeira island are divided into dunite/websterite/wehrlite/clinopyroxenite (DWWC) and harzburgite/lherzolite suites; the harzburgite/lherzolite xenoliths show abundant deformational features and are more refractory (Fo = 90–91) than the DWWC suite (Fo = 77–88).

DWWC xenoliths are spinel-bearing olivine ± orthophyroxene cumulates with intercumulus clinopyroxene and rare plagioclase, amphibole and phlogopite. Mineral chemistry and geothermobarometric data indicate that DWWC xenoliths crystallized at 1150–1300 °C from Madeiran alkalic basalts and accumulated in magma reservoir(s) located 36–45 km beneath the island.

The harzburgite/lherzolite xenoliths are composed of olivine + orthopyroxene + spinel ± clinopyroxene ± (rare) phlogopite and display alkali feldspar or clinopyroxenite veins and crystal aggregates. The complex thermal evolution recorded by these xenoliths and the close similarity of clinopyroxene REE contents and calculated fO2 values in both harzburgites and DWWC cumulates are attributed to recent infiltration of the harzburgites by melts trapped or crystallized within the mantle; these features, and the refractory bulk chemistry of the harzburgite/lherzolite suite, support the interpretation that these xenoliths represent depleted oceanic lithosphere variously modified by magmatism associated with the genesis of Madeira island. The association of these upper mantle xenoliths with cumulates crystallized from Madeiran magmas (DWWC) suggests that the harzburgite/lherzolite suite originated in the uppermost mantle above magma storage zone(s), probably near the boundary between the mantle and the overlying oceanic crust.

Lithostratigraphic terminology is revised for rocks of Ordovician age in the eastern Taurus. The Seydişehir Formation, of late middle Cambrian to early Ordovician age, is shown to be applicable in the eastern and western Taurus as well as in south-eastern Turkey. Near Degˇirmentaş, northeast of Adana, the Seydişehir Formation is overlain, with inferred unconformity, by clastic strata of Ashgill age referred to the Şort Tepe Formation, first defined south of Hakkâri, in the Border Folds of southeastern Turkey. Palaeontological evidence is cited for the early Silurian (Llandovery) age of the unconformably overlying Halityayla Formation farther south, on the coast near Ovacik, where the Şort Tepe Formation is as yet unrecorded. A general model is proposed showing relationships of Cambrian and Ordovician rocks and faunas in southern and southeastern Turkey.

The structure and microbiology of active travertines is described from Canary and Minerva springs, with emphasis on ‘shrubs’ growing in terracette pools. These dendritic growths of aragonite consist of intricately branched sprays containing thousands of radiating needles. Shrub microstructure could be explained by the principle of ‘Keimauslese” and the preferential elongation of sharp protuberances in a rapidly depositing environment.

The shrubs, and other active travertines, contain unicellular and filamentous bacteria. Estimates of total bacteria numbers ranged from 0.6−1.7 × 105 mm−3 but biomass was low, and always less than 1% of the travertine by weight. No evidence was found to indicate that bacteria played a role in shrub growth or morphology, but crystal trapping on bacterial strings may influence travertine fabrics on cascades. The shrubs are considered to have developed by inorganic processes, in hot spring waters supersaturated with aragonite.

A new early Cambrian sponge of sphinctozoan organization named Polythalamia americana nov. gen. et sp. is described from Nevada and Alaska, U.S.A. P. americana nov. gen. et sp. shows little resemblance to other Cambrian reported sphinctozoans, but is similar to late Palaeozoic to early Mesozoic forms from Europe and Asia, e.g. Stylothalamia and Amblysiphonella. The polyphyletic origin of sphinctozoans based upon spicule criteria from younger examples is therefore corroborated by the varied morphology and clearly widespread palaeogeographic distribution of Cambrian forms, which were hitherto recognized only from Australia. P. americana nov. gen. et sp. possesses a relatively small, globular multi-chambered calcareous skeleton, with thin but densely perforate walls and a central retrosiphonate, perforate spongocoel. The skeleton is composed of an irregular microstructure of unknown, but probable calcitic, original mineralogy. There are no spicules or primary internal structures, but secondary vesicular filling tissue is present. The pore organization, however, it directly comparable to archaeocyaths, e.g. coscinocyathines, and this character is taken to be the only synapomorphy available for taxonomic and phylogenetic purposes. Indeed, P. americana nov. gen. et sp. is closely associated with a diverse archaeocyath assemblage and draws attention to morphological similarities between some archaeocyaths and sphinctozoans, thus questioning the criteria at present used to distinguish between these groups. Accordingly, a list of nomenclatural synonymies is given to aid comparison. Coscinocyathine archaeocyaths possess chambered juvenile stages and P. americana nov. gen. et sp. is suggested to represent an aspiculate lineage of sphinctozoan grade which may be derived from forms such as Clathricoscinus by neoteny. It appears that at least three clades of sphinctozoan-grade calcified sponges were present by end of early Cambrian time and their occurrence in association with island arcs of the palaeopacific rim is confirmed.

The Chuping Limestone of northwest Peninsular Malaysia, until recently considered entirely of Permian age, has yielded late Triassic (early Norian) conodonts. TheLimestone thus spans the time interval late Early Permian–Late Triassic and is in part equivalent to the Kodiang Limestone (Late Permian–Late Triassic) in Kedah andsimilar limestone sequences in south Thailand and north Sumatra. Early Late Triassic (Carnian) conodonts are also reported from pelagic limestones associated with bedded chertsof the Chert Member of the Semanggol Formation in Kedah. The Chert Member, previously considered of Middle Triassic age, is re-interpreted to represent Early, Middle and early Late Triassic deposition. The Triassic sedimentary rocks of the Malay Peninsula represent three distinct sedimentary regions: a stable shallow marine carbonate complex (ChupingLimestone, Kodiang Limestone), which forms part of an elongate carbonate platform on theSibumasu block; a deep water pelagic/turbidite basinal sequence (Semanggol Formation) which accumulated in either a foredeep basin or an intracratonic pull-apart basin related to strike-slip faulting; and a volcanic-sourced volcaniclastic basinal sequence on the East Malaya block (Semantan Formation and equivalents) which accumulated in either a forearc/intra-arc setting, or in a post-orogenic rift basin.

An analysis of outcrop and borehole information relating to the strata between the Upper Band and Better Bed coals of the central and south Pennines shows that two lithological facies can be recognized within a cyclic sequence of mudstones, siltstones and sandstones. In one facies, sandstones and siltstones contain abundant mica, and argillaceous beds are neutral grey in colour. Petrographically the sandstones are feldspathic but contain little lithic material other than multigrain quartz. In the other facies, mica is much less common, argillaceous beds are greenish grey, and sandstones and siltstones contain a notable proportion of chloritic lithoclasts. The sediments of both facies were deposited in lower delta plain/shallow-water delta environments, and palaeocurrent measurements show that the micaceous facies was supplied from the north or east while the green facies came in from the west.

Three named divisions of the sequence are based on recognition of the two facies types. They correspond roughly with three upward-coarsening transgressive–regressive sedimentary cycles of presumed eustatic origin. In the lowest part of the succession (Shibden division) the main clastic input was of the micaceous type. Sandstones are found only in the north of the basin, where they form a series of superimposed delta-front bodies. Mudstones were deposited elsewhere, in a large body of open water which, although linked to the sea, was generally of lowered salinity. The restriction of the delta-front sandstones to the same geographical area over a long period of time is attributed to differential subsidence of the basin across deep-seated structures.

The sediments of the overlying Brighouse division belong to the green facies, and the source of the elastics lay to the west. After an initial period of mudstone deposition in an extensive, apparently non-marine, body of open water, fluviodeltaic sand and silt spread across the entire area. There is no obvious control of sandstone distribution by basement structures.

The succeeding Bradley Wood division includes sediments of both micaceous and green facies. A lobe of medium-grained micaceous sandstone around Sheffield (Thurlstone Channel) represents a fluvial incursion from the east and a linear body of fine-grained green-facies sandstone south of Chesterfield (Bole Hill Channel) represents a similar incursion from the west. Elsewhere, small units of finer-grained elastics are probably deltaic deposits linked to the same sources. The location of the channel sand-bodies suggests control by deep-seated fractures.

Metabentonites occur extensively in the Moffat Shale Group of the Southern Uplands of Scotland. At Dob's Linn 135 metabentonite beds, 1–50 cm thick, occur in Ashgill to Llandovery strata, representing an aggregate thickness of 6 m of compacted ash accumulated over approximately 25 Ma. The metabentonites are characterized by relatively high concentrations of trace elements, including Ba, Cs, Hf, Nb, Rb, Ta, Th, U, Y, Zr and REEs, which were inherited from evolved vitric ash. Immobile trace element data indicate that a spectrum of silicic ash compositions accumulated, ranging from subalkaline to mildly peralkaline. In the late Ordovician N. gracilis to G. persculptus biozones, subalkaline ash falls predominated, whereas peralkaline ash falls predominated in the Llandovery (Silurian) P. acuminatus to M. convolutes biozones, giving way to predominantly subalkaline ash falls during accumulation of the M. sedgwickii to R. maximus biozones. Changeovers in the dominant ash types are marked by increased proportions of ash. The magmas from which the ash types evolved were generated in an ensialic arc transitional to a back-arc setting, and involved attenuated sialic crust and mantle characterized by variable depletion in HFS elements. Lithological, petrological and REE characteristics suggest that the Moffat Shale Group is not exclusively pelagic in origin and probably accumulated in a back-arc basin bordering an ensialic arc terrane.

An inverse elastic flexural model with compressive thrusting is applied to the northern Green River Basin, Wyoming. A combination of six parameters in the model determines the deformational processes of basement due to sediment load and compressive thrusting: flexural rigidity, lateral stress, bending moment, initial load, dip angle of the basement, and length. The results suggest that the northern Green River Basin develops dominantly as an elastic flexural response to the deformation of basement due to compressive thrusting of the Wind River Mountains. From the unloaded basement configuration we estimate that by latest Cretaceous time the thrust fault activity of the Wind River Mountains led the basement to uplift about 7 km above the hinge point at the margin of the basin and to form a complex faulted mountain system. The maximum uplift rate is about 100 m/Ma at the Wind River Mountains. Also we predict the sedimentary pattern, and provenance of sediments of Tertiary units, from the unloaded basement geometry. Thus the inverse elastic flexural model can be used to assess the evolutionary processes involved in a basin under compressive thrusting.

Granitic rocks from all the exposed components of the Lake District batholith have been analysed for ammonium to look for evidence of an ammonium-rich sedimentaryprotolith. The results indicate that the ammonium content of Lake District granites is related to the type and degree of alteration experienced by the rocks. Fresh, little-altered granites from all parts of the batholith have low ammonium contents (< 30 ppm), whereas highly altered rocks contain up to 250 ppm ammonium. The most ammonium-rich rocks are highly altered specimens of Skiddaw Granite containing appreciable secondary muscovite, sericite and clay. The degree of ammonium enrichment is related to the style of alteration and host-rock lithology. Evidence for the source of ammonium is provided by strong depletion (< × 0.3) of ammonium in silty mudstones within the cordierite andgarnet hornfels zones of the Skiddaw Granite aureole. In view of the low ammonium content of some sediments and the losses known to accompany high-grade metamorphism and associated dehydration, the low primary ammonium contents of the granites are not considered to be evidence either for or against a sedimentary protolith.

The metaluminous to peraluminous granitoids of the Donegal batholith, northwest Ireland, were emplaced at c. 400 Ma into greenschist-amphibolite facies metasediments of the Dalradian Supergroup. Sm-Nd and Rb-Sr isotopic data are provided for eleven granitoid samples from six of the plutons and one specimen from the northeast granodiorite pluton of the Newry complex, Co. Down; the Donegal results reveal essentially similar initial Sr isotope ratios (0.7051–0.7068) but highly variable initial eNd values, −1.2 to −8.3 (and −0.5 for Newry). Certain granitoids have distinctive Nd isotopic compositions characteristic of the involvement of old, LREE-enriched continental crust in some cases or young crust and/or mantle-derived magmas in others. The Nd and Sr isotopic variations can be explained by a variety of mixing hypotheses.

The use of calcrete horizons as a means of assessing rates of sediment accretion in ancient alluvial sequences is reviewed. Any attempt to use such horizons in quantifying ancient alluvial deposition must appreciate that accurate data on rates of formation of Quaternary calcretes are limited. Such data show considerable variations in the rates and no reliable data exist at all for some calcrete types. The abundance of calcretes in the geological record warrants a new initiative to improve our understanding oftheir origins and rates of formation.

An exceptionally well-preserved synsedimentary deformation feature is described from uppermost Miocene fluvio-lacustrine coastal plain sediments, exposed in lignite mines of the Lower Rhine Basin, Germany. The feature is interpreted as a complex, multi-stage channel-bank collapse structure. Rotational slumping of bank material into the channel along two failure surfaces extending below the channel toe generated a series ofminor compressional ‘thrust/backthrust’ structures within the muddy channel-fill sediments. A reconstruction of the failure event is proposed which is linked toa lowering of river stage and subsequent channel abandonment. The accurate description of this unusually well-preserved channel-bank collapse structure may have general application in the interpretation of similar, but less-well-exposed-preserved phenomena elsewhere.

Berthierine, siderite and pyrite are the major ferriferous phases in the Northampton ironstone (NIS). Mineralogical and chemical data suggest a formation of these phases in a diagenetic marine environment changing from post-oxic to sulphidic conditions. Berthierine was formed first when the Fe2+ activity in the diagenetic system increased. Later, this phase was partially replaced by siderite and/or pyrite. A second stage of the diagenetic development in the NIS with increasing CO2 partial pressure (PCO2 ) is documented by siderite. The isotopic composition (δ18O mean value: –1.7‰PDB; δ13C mean value: –8.6‰PDB) points to siderite precipitation from a marine porewater environment with a microbial CO2 source. The shift from post-oxic to sulphidic conditions is indicated by the occurrence of pyrite and can be considered as a final stage. The diagenetic processes in the marine environment and the formation of the ferriferous phases were stopped by the influx of brackish or fresh water when the Midland Shelf turned estuarine.

Investigations of the March Gravels of Northam Pit, Eye, Cambridgeshire, have provided previously undescribed molluscan, ostracod and foraminiferal faunas together with pollen spectra, which enable a detailed palaeoenvironmental synthesis to be developed. The sediments were laid down in brackish-water conditions and a temperate environment, during a Late Pleistocene temperate stage.

A highly xenolithic dolerite dyke is described which contains a large number of spinel lherzolite xenoliths. The petrology of the dolerite and the xenolith suite is described and electron probe analyses presented for the mineral phases in one of the spinel lherzolite xenoliths. The dyke geochemistry is consistent with a Permo-Carboniferous age.