Control of seedling and rhizome johnsongrass [Sorghum halepense (L.) Pers. # SORHA] with five herbicides was evaluated after postemergence application in various diluents and spray volumes using one to three types of applicators from 1983 to 1985. The rate of each herbicide required to control seedling johnsongrass using paraffinic oil as the diluent in applications with an external- or internal-mixing air-assist sprayer at a spray volume of 9.4 L/ha was one-half the rate required when water plus 1.25% (v/v) paraffinic oil concentrate (POC) or water plus 1.25% (v/v) soybean oil concentrate (SOC) were the diluents in applications with a conventional sprayer equipped with fan jet spray nozzles at a spray volume of 187 L/ha. Rates were also reduced when once-refined soybean oil was the diluent at a spray volume of 9.4 L/ha, except for the ethyl ester of quizalofop {(±)-2-[4-[(6-chloro-2-quinoxalinyl)oxy] phenoxy] propanoic acid}. Sethoxydim {2-[1-(ethoxyimino)butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one} was equally effective on seedling johnsongrass growing in soybeans [Glycine max (L.) Merr. ‘DPL 105’] when applied at 224 g ai/ha with an internal-mixing air-assist sprayer or a controlled-droplet applicator (CDA) at a spray volume of 9.4 L/ha and a conventional sprayer at a spray volume of 187 L/ha, regardless of diluent. Conventional application required the use of 1.25% (v/v) SOC or POC as part of the diluent to be effective. For three of the five herbicides evaluated on rhizome johnsongrass, paraffinic oil at a spray volume of 9.4 L/ha was the only diluent that resulted in season-long control. Rhizome johnsongrass control with this diluent also resulted in significantly higher soybean yields than all other diluent-spray volume treatments.

Water and paraffinic oils were used to determine variables that affect positive displacement pumps used to meter liquid flow in an air-assist spray system. Components needed to construct an air-assist spray system were described for use in spray chambers and on a tractor for field application of herbicides in ultralow volume (ULV). The flow rate of the pump varied less than 2% for the water and oil as the pump setting was varied from 0 to 100% of the pump's capacity. Linear relationships were shown for both liquids as the voltage input varied from 4 to 13 volts. Air pressures to 100 kPa and liquid temperatures to 35 C did not affect flow rate of the pump. Volume median diameter of the spray droplets decreased from 295 μm to 77 μm and 159 μm to 85 μm for water and paraffinic oil, respectively, as the air pressure was adjusted from 14 to 110 kPa.

Comparative spread of droplets of several different oils and water with different adjuvants on leaf surfaces was investigated. Spread was better on the lower surface of johnsongrass leaves than on upper leaf surfaces with nine of 14 oils studied; two spread best on upper leaf surfaces, and three were equal in spread on both surfaces. Differences in spread coefficients did not appear to be directly related to surface tension, viscosity, or mid-boiling point of the oils. Soybean or cottonseed oils did not spread as well as petroleum oils but methylated soybean and sunflower oils had high spread coefficients on both upper and lower leaf surfaces. All but one petroleum-base oil spread three to four times better on leaf surfaces than on oil-sensitive paper. Water mixtures of an organosilicone surfactant spread much better on water-sensitive paper and on johnsongrass leaves than water with conventional adjuvants, but spread of paraffinic oils exceeded that of any water-adjuvant mixture. Spread coefficients of most petroleum-base oils were better on lower than upper leaf surfaces. Spread usually increased as the age of leaves increased from 14 to 56 d. Water droplets with adjuvant had at least an 86% weight loss after 6 min, but low volatile paraffinic oil droplets had little weight loss 2 d after application.

An air-assist spray nozzle was constructed to apply herbicides in oil or water at volumes as low as 2.3 L/ha. The spray was metered through a disc orifice inside the nozzle and forced into an airstream which atomized the liquid. The nozzle produced 16 to 54 spray droplets/cm2 with air pressures from 3.4 to 62 kPa from a 2-mm outlet using a lightweight paraffinic oil. The number of spray droplet deposits produced with a paraffinic oil at 34 kPa increased from 7 droplets/cm2 with a 0.8-mm outlet to 48 droplets/cm2 with a 2.4-mm outlet. The nozzle was designed primarily to apply herbicides in oil at 2.3 to 4.7 L/ha, but it has the capability of applying 150 L/ha of oil or water.