The relationship between three parameters, the Tmax given by Rock-Eval pyrolysis, the illite content in illite-smectite mixed layers (I-S) and the Ku¨bler Index (KI) has been investigated in the Cretaceous–Neogene, sedimentary syn-orogenic successions in the Northern Apennines (Italy). A strong relationship was found between maturity stages of kerogen, illite content in I-S and KI. The oil formation zone for continental organic matter (Type III), delimited by Tmax between 434 and 465ºC, corresponded to rocks with short-range ordering R1, I-S with illite content between 60 and 85% and KI values in the range 0.85–0.65 (ºΔ2θ). Over-mature rocks were characterized by Tmax >465ºC, a long-range ordered I-S with an illite content >85% and KI in the range 0.65–0.45 (ºΔ2θ). The relationship permits use of both mineralogical parameters and Tmax to estimate palaeotemperatures in sedimentary successions and it can be exploited in hydrocarbon research to evaluate the petroleum potential.

Mixed-layer illite-smectite samples from the Ordovician and Silurian K-bentonites of the Baltic Basin and the Baltic Shield (Norway, Sweden, Denmark, Poland and Estonia) were dated by K-Ar on several grain fractions and were studied by X-ray diffraction (XRD), both on oriented and random preparations, in order to reveal the conditions of smectite illitization in the area. Authigenic K-feldspar was also dated. The geographic pattern of the degree of illitization (% smectite in illite-smectite measured by XRD) is consistent with other indicators of palaeotemperatures (acritarchs, conodont alteration index, vitrinite reflectance, apatite fission track ages). It reveals the highest maximum palaeotemperatures (up to at least 200ºC) along the Norwegian and the German-Polish branches of the Caledonides and the lowest palaeotemperatures (120ºC) in the central part of the studied area. The distribution of K-Ar ages is not well correlated with this pattern, revealing a zone of older ages (Lower Devonian-Lower Carboniferous) between Denmark and Estonia, and areas of younger ages (Upper Devonian to Carboniferous/Permian boundary) to the north and south of this zone. The zone of older ages is interpreted as the result of illitization induced by a thermal event in front of the Caledonian orogenic belt (migration of hot metamorphic fluids?). The areas of younger ages are considered as representing deep burial illitization under a thick Silurian-Carboniferous sedimentary cover, perhaps augmented by a tectonic load. The K-Ar dates invalidate the hypothesis of a long-lasting low-temperature illitization as the mechanism of formation of the Estonian Palaeozoic illite-smectite. The ammonium content of illite-smectite from the Baltic K-bentonites reflects the proximity of organic-rich source rocks that underwent thermal alteration at the time of illite crystallization.

Diagenetic palaeotemperatures determined from aqueous fluid inclusions can be affected by re-equilibration during burial heating. Calculations based on the observed behaviour of inclusions in fluorite under external confining pressure allows prediction of the temperatures and depths of burial necessary to initiate re-equilibration of aqueous inclusions in the common size range 40 to 4 µm. Heating of 20° to 60°C over the initial trapping temperature may cause errors of 10° to 20°C in the homogenization temperature. This suggests re-equilibration may cause aqueous inclusions in carbonates to yield a poor record of their low-temperature history, but a useful record of the maximum temperature experienced by the host rock. Previous work suggests inclusions containing petroleum fluids will be less susceptible to re-equilibration.

Detailed microprobe and modal data for a sample of layered, garnetiferous, quartzose paragneiss reveal significant differences in garnet-biotite Mg-Fe distribution coefficients (Kd) — and hence paleotemperatures — determined for leucocratic (modal Grt+Bt<25 vol.%) and mesocratic (Grt+Bt> 25 vol.%) layers. In leucocratic layers, lnKd determined from both the core and rim compositions of minerals shows a range of values that varies sympathetically with the absolute amount of garnet and biotite, and, as demonstrated in other studies, inversely with the distance separating both minerals. Due to the small size (<2 mm) of garnets, which facilitated diffusional re-equilibration during cooling from peak metamorphic temperature, lnKd does not correlate to modal Bt/Grt ratios. The largest garnets, which occur in mesocratic layers, nonetheless tend to preserve the most pronounced (retrograde) zoning patterns (i.e. rimward increase in Fe/Mg), consequently mineral core composition lnKd values correlate with grain diameter except where garnets contain abundant biotite inclusions. The highest Grt-Bt temperatures (∼700°C are recorded by: (1) the composition of relatively widely-separated (>0.3 mm) grains in highly leucocratic layers; and (2) the core compositions of relatively large (>1 mm), inclusion-free grains in mesocratic layers. More closely spaced garnets and biotites in leucocratic layers, and small grains in mesocratic layers, give a range of temperatures intermediate between Tmax and diffusional blocking temperatures (∼ 560°C) recorded by the rim compositions of contiguous grains.

Assemblages of fossil coleoptera (beetles) have been obtained from eight sites in southern England that date from the early phase (Pinus — Quercetum mixtum — Corylus pollen assemblage zone) of the Eemian (Ipswichian) interglacial Stage. Altogether 294 different species have been identified from these sites. They represent a wide spectrum of habitat requirements; terrestrial, aquatic, carnivorous and phytophagous species and many more with subtle dependences of specialist biotopes. Almost all of them live today in central and southern Europe and some are restricted to regions well south of the British Isles.

By using mutual climatic range methods, the thermal climate of the early phase of the Eemian Interglacial has been estimated quantitatively, showing that mean July temperatures were about 4°C above those of southern England today. Mean winter temperatures were not much different from those nowadays. This phase was probably the thermal maximum of the Eemian Interglacial. Precipitation levels are difficult to quantify but were adequate to maintain flowing rivers in England throughout the year. These results are in agreement with the presence of other fossils, both plants and animals, in the same deposits.

Temperature profiles along east-west and north-south transects in Europe are presented for four time-slices covering the two most prominent warming phases of the last glacial-interglacial transition: Late Pleniglacial (LP), early Bøiling (BL), Younger Dryas (YD), and Preboreal (PB). These temperature profiles are based on two methods: 1) simulation experiments with an atmospheric general circulation model, 2) reconstructions based on terrestrial geological and palaeoecological data. The profiles have The Netherlands as intersection point (52°N, 5°E). During the cold phases (LP and YD), the simulated and reconstructed temperature gradients are very steep in a north-south direction, ranging in January from -25°C in northern Europe (56–60°N) to at least 5°C near the Mediterranean, and in July from 0°C to 20°C. The east-west profiles along 52°N for LP and YD show that temperatures in Eastern Europe were similar to the Atlantic coast (i.e. between ‒15°C and ‒25°C). During the warm phases (BL and PB), the temperature regimes resembled present-day thermal conditions, although steeper north-south and east-west temperature gradients were present during BL and PB. The model simulations suggest that continental Europe was a few degrees warmer during PB and BL than today in July under influence of the relatively high summer insolation. Considering the change of climate through time, the profiles show that in The Netherlands the warming during the two transitions (LP-BL, YD-PB) was relatively small compared to regions to the West and North, whereas in Eastern and Southern Europe the temperature increase is even smaller. This reflects the dominant influence of latitudinal movements of the North Atlantic polar front and associated sea-ice margin.