The morphology of hydrotalcites determines their use in catalysis, biomedicine, or adsorption as they may work as anion exchangers or as drug deliverers. In catalysis, reagents need access to as much surface area as possible; in biomedicine, drugs have to be encapsulated. However, the parameters and the mechanisms which direct the synthesis towards a certain morphology are not well understood. Precipitating agents or crystallization conditions are expected to play a crucial role. In the present study, hydrotalcites were synthesized in the presence of two precipitating agents (NaOH or NH4OH) under three different crystallization conditions (conventional, microwave, or ultrasound irradiation) which determined the morphology of the final product, layered or vesicular. The features are explained through the template effect of the liberated gases on the co-precipitation and crystallization processes and consequently on the final structure/morphology of the synthesized solids. Indeed, the nodular particles crystallize using the effluent gases as templates. Fractal dimension and particle-size distributions, determined by small-angle X-ray scattering (SAXS) and gas adsorption are compared and correlated to the presence of ammonium. Although the materials obtained are heterogeneous, it is possible to propose a microscopic geode model.

Star formation processes in strongly self-gravitating cloud cores should be similar at all redshifts, forming single or multiple stars with a range of masses determined by local magneto-hydrodynamics and gravity. The formation processes for these cores, however, as well as their structures, temperatures, Mach numbers, etc., and the boundedness and mass distribution functions of the resulting stars, should depend on environment, as should the characteristic mass, density, and column density at which cloud self-gravity dominates other forces. Because the environments for high and low redshift star formation differ significantly, we expect the resulting gas to stellar conversion details to differ also. At high redshift, the universe is denser and more gas-rich, so the active parts of galaxies are denser and more gas rich too, leading to slightly shorter gas consumption timescales, higher cloud pressures, and denser, more massive, bound stellar clusters at the high mass end. With shorter consumption times corresponding to higher relative cosmic accretion rates, and with the resulting higher star formation rates and their higher feedback powers, the ISM has greater turbulent speeds relative to the rotation speeds, thicker gas disks, and larger cloud and star complex sizes at the characteristic Jeans length. The result is a more chaotic appearance at high redshift, bridging the morphology gap between today's quiescent spirals and today's major-mergers, with neither spiral nor major-merger processes actually in play at that time. The result is also a thick disk at early times, and after in-plane accretion from relatively large clump torques, a classical bulge. Today's disks are thinner, and torque-driven accretion is slower outside of inner barred regions. This paper reviews the basic processes involved with star formation in order to illustrate its evolution over time and environment.