The intense stellar SXR and EUV radiation exposure at “Hot Jupiters” causes profound responses to their upper atmosphere structures. Thermospheric temperatures can reach several thousands of Kelvins, which result in dissociation of H2 to H and ionization of H to H+. Depending on the density and orbit location of the exoplanet, as a result of these high temperatures the thermosphere expands dynamically up to the Roche lobe, so that geometric blow-off with large mass loss rates and intense interaction with the stellar wind plasma can occur. UV transit observations together with advanced numerical models can be used to gain knowledge on stellar plasma and the planet's magnetic properties, as well as the upper atmosphere.