Feldspars from the Karkonosze pluton (SW Poland) display many features compatible with magma mixing. The mixing hypothesis has been tested using a geochemical mass balance law resulting in two possible paths of magma hybridization. Based on the results of the geochemical calculation, feldspar samples have been chosen along both mixing lines for cathodoluminescence (CL) investigation which was used as the main tool for the reconstruction of their crystallization path. Changes in the conditions of nucleation and crystallization of the feldspars as well as their movement within the magma chamber have been recognized due to different luminescence characteristics. These changes in the conditions of crystallization obtained by CL allow a precise determination of the genetic affinity of the samples to more mafic or more felsic environments.

The results of the present study proved CL to be a valuable tool for the study of crystal-growth morphologies in a dynamic, turbulent environment and also as a geochemical tool for the reconstruction of various petrogenetic mechanisms (e.g. magma hybridization). Accordingly, the combination of CL with geochemical modelling provides corresponding information about magma evolution in an open system.

The elemental compositions of zoned alkali feldspar megacrysts from the Karkonosze pluton have been analysed and Pb isotope ratios determined using LA-ICP-MS, EMPA and TIMS. The results are used to interpret the magmatic environments within which they crystallized. Growth zones in the megacrysts show fluctuating trace element patterns that reflect a systematic relationship between incompatible LREE and compatible Ba. Chemical gradients between zones in the cores and rims of the megacrysts are not accompanied by significant variation in initial Pb isotope composition. The nucleation and crystallization of the megacrysts is interpreted as having occurred in an environment of magmatic hybridization caused by mixing of mantle and crustal components in which effective homogenization of the Pb isotope composition preceded the onset of megacryst growth. The concentrations of LREE in alkali feldspar zones were used to reconstruct hypothetical melt compositions. Some of the zones appear to have crystallized in an homogenous magmatic environment having clear geochemical affinities with end-member magmas in the Karkonosze pluton, whereas others crystallized in heterogeneous domains of magma hybridization. With the exception of Nd, zones crystallized in more homogeneous magma show LREE fractionation under near-equilibrium conditions. Trace element abundances of megacrysts grown in dynamic, homogeneous magmatic environments of the Karkonosze pluton occasionally deviate from the predicted patterns and show LREE impoverishment.