In this paper, we discuss the H1L-boundedness of commutators of Riesz transforms associated with the Schrödinger operator L=−△+V, where H1L(Rn) is the Hardy space associated with L. We assume that V (x) is a nonzero, nonnegative potential which belongs to Bq for some q>n/2. Let T1=V (x)(−△+V )−1, T2=V1/2(−△+V )−1/2 and T3 =∇(−△+V )−1/2. We prove that, for b∈BMO (Rn) , the commutator [b,T3 ] is not bounded from H1L(Rn) to L1 (Rn) as T3 itself. As an alternative, we obtain that [b,Ti ] , ( i=1,2,3 ) are of (H1L,L1weak) -boundedness.