Gases will be generated in waste packages during their transport to a geological disposal facility (GDF), this generation will continue during GDF operations and after GDF closure. The range of gases produced will include flammable, radioactive and chemotoxic species. These must be managed to ensure safety during transport and operations, and the post-closure consequences need to be understood. The two primary post-closure gas issues for a GDF are the need for the system pressure to remain below a value at which irreversible damage to the engineered barrier system and host geology could occur, and the need to ensure that any flux of gas (in particular gaseous radionuclides) to the biosphere does not result in unacceptable risk. This paper provides an overview of the research of the Nuclear Decommissioning Authority, Radioactive Waste Management Directorate into gas generation and its migration from a GDF.

Carbon-14 (C-14) is a key radionuclide in the assessment of a geological disposal facility (GDF) for radioactive waste. In the UK a significant proportion of the national C-14 inventory is associated with reactor-core graphite generated by the decommissioning of the UK's Magnox and AGR reactors.

There are a number of uncertainties associated with the fate and transport of C-14 in a post-closure disposal environment that need to be considered when calculating the radiological impacts of C-14-containing wastes. Some of these uncertainties are associated with the distribution of C-14-containing gaseous species such as 14CH4 and 14CO2 between the groundwater and gaseous release pathways. As part of the C14-BIG programme, a modelling framework has been developed to investigate these uncertainties. This framework consists of a biogeochemical near-field evolution model, incorporating a graphite carbon-14 release model, which interfaces with a geosphere/biosphere model. The model highlights the potential impact of the microbial reduction of 14CO2 to 14CH4, through the oxidation of H2, on C-14 transport. The modelling results could be used to inform the possible segregation of reactor graphite from other gasgenerating wastes.

3D basin modelling is used to investigate the history of maturation and hydrocarbon generation on the main platforms in the northwestern part of the offshore area of the Netherlands. The study area covers the Cleaverbank and Elbow Spit Platforms. Recently compiled maps and data are used to build the input geological model. An updated and refined palaeo water depth curve and newly refined sediment water interface temperatures (SWIT) are used in the simulation. Basal heat flow is calculated using tectonic models. Two main source rock intervals are defined in the model, Westphalian coal seams and pre-Westphalian shales, which include Namurian and Dinantian successions. The modelling shows that the pre-Westphalian source rocks entered the hydrocarbon generation window in the Late Carboniferous. In the southern and central parts of the study area, the Namurian started producing gas in the Permian. In the north, the Dinantian source rocks appear to be immature. Lower Westphalian sediments started generating gas during the Upper Triassic. Gas generation from Westphalian coal seams increased during the Paleogene and continues in present-day. This late generation of gas from Westphalian coal seams is a likely source for gas accumulations in the area.

Westphalian coals might have produced early nitrogen prior to or during the main gas generation occurrence in the Paleogene. Namurian shales may be a source of late nitrogen after reaching maximum gas generating phase in the Triassic. Temperatures reached during the Mid Jurassic were sufficiently high to allow the release of non-organic nitrogen from Namurian shales.