The detrital zircon perspective on the pre-collisional crustal evolution of the Grenville Province remains poorly explored. In this study, we conducted in situ laser ablation U–Pb–Hf isotopic microanalysis on detrital zircon grains from three pre-orogenic (>1 Ga) supracrustal sequences that crop out in the Central Grenville Province (Lac Saint-Jean region, QC, CA). Detrital zircon grains from vestiges of these sequences record three dominant age peaks at c. 1.46 Ga, 1.62 Ga, 1.85 Ga, and a subordinate peak at 2.7 Ga. The 1.46 Ga and 1.62 Ga age peaks are recorded in detrital zircon grains from a quartzite associated with a metavolcanic sequence (i.e. Montauban Group) with a maximum depositional age of c. 1.44 Ga. In contrast, the c.1.85 Ga age peak is observed from recycled zircon grains in metasediments with maximum depositional ages between 1.2 and 1.3 Ga. The suprachondritic Hf isotope composition in detrital zircon grains of the 1.46 Ga and 1.62 Ga age populations records juvenile crustal growth during peri-Laurentian accretionary orogenesis related to the Pinwarian (1.4–1.5 Ga) and Mazatzalian–Labradorian (1.6–1.7 Ga) events. The detrital zircon grains associated with Penokean–Makkovikian (1.8–1.9 Ga) source rocks record reworking of c. 2.7 Ga continental crust derived from a near-chondritic mantle reservoir. Overall, crust-forming and basement reworking events associated with accretionary orogenesis in southeastern Laurentia are retained in the detrital zircon load of Precambrian basins even after the terminal Grenvillian collision and assembly of Rodinia.

Zircon U–Pb and Lu–Hf isotope microanalysis was conducted in (meta)-igneous units of Ammouliani island to characterize crust-forming and reworking events in the Serbo-Macedonian massif. Zircon grains from an orthogneiss of the Vertiskos unit yielded a U–Pb crystallization age for the igneous precursor at 458.8 ± 11 Ma with dominantly subchondritic ϵHf values indicating reworking of Neoproterozoic basement. A weighted mean ϵHf value of 0.7 ± 2.4 from oscillatory zoned zircon grains of the Ouranoupoli granodiorite indicates juvenile crustal input at 52.1 ± 0.6 Ma. The U–Pb–Hf zircon archive records discrete stages in the crustal evolution of the Serbo-Macedonian massif.

Whole-rock major and trace elements and Hf isotopes of magmatic zircons of tonalite–trondhjemite–granodiorite (TTG) rocks with different ages (2.9, 2.7 and 2.5 Ga) from the three blocks (the Eastern Block, Western Block and Trans-North China Orogen) of the North China Craton were compiled to investigate their respective petrogenesis, tectonic setting and implications for crustal growth and evolution. Geochemical features of the 2.5 Ga TTGs of the Eastern Block require melting of predominant rutile-bearing eclogite and subordinate garnet-amphibolite at higher pressure, while the source material of the 2.7 Ga TTGs is garnet-amphibolite or granulite at lower pressure. The 2.5 Ga TTGs have high Mg#, Cr and Ni, negative Nb–Ta anomalies and a juvenile basaltic crustal source, indicating derivation from the melting of a subducting slab. In contrast, features of the 2.7 Ga TTGs suggest generation from melting of thickened lower crust. The 2.5 and 2.7 Ga TTGs in the Trans-North China Orogen were formed at garnet-amphibolite to eclogite facies, and the source material of the 2.5 Ga TTGs in the Western Block is most likely garnet-amphibolite or eclogite. The 2.5 Ga TTGs in the Trans-North China Orogen and Western Block were generated by the melting of a subducting slab, whereas the 2.7 Ga TTGs in the Trans-North China Orogen derived from melting of thickened lower crust. The Hf isotopic data suggest both the 2.5 and 2.7 Ga TTG magmas were involved with contemporary crustal growth and reworking. The two-stage model age (TDM2) histograms show major crustal growth between 2.9 and 2.7 Ga for the whole North China Craton.

Mafic rocks in the Ryoke belt, the Cretaceous granitic province in Southwest Japan, occur in two modes: (1) as mafic dykes and pillow-shaped enclaves, and (2) as isolated kilometresized bodies of gabbroic cumulate. The dykes and pillows have fine-grained textures with thin radiating plagioclase laths, indicative of quenching. The gabbroic cumulates are predominantly coarse-grained and commonly lithologically layered.

SHRIMP zircon U-Pb ages of both types of mafic rocks are in the range 71–86 Ma, late Cretaceous. The mafic rocks become younger eastwards, matching the along-arc age trend of the associated Cretaceous granites (Nakajima et al. 1990). Both types of mafic rocks were apparently generated during the same magmatic event that produced the Ryoke/San-yo granites. The mafic dykes and pillows are aphyric basaltic-andesites to andesites (SiO2 54–60 wt.%), with microphenocrysts of biotite and hornblende. They have a composition which is similar to mafic rocks from the northern Sierra Nevada, and also to medium-K calc-alkaline rocks from present-day arc volcanics. The gabbroic cumulates are mostly pyroxene-hornblende gabbros (SiO2 43–52 wt.%). Their bulk-rock chemical compositions are mostly unlike any magma compositions.

Both types of mafic rocks from the Ryoke belt have relatively high 87Sr/86Sr initial ratios (SrI), 0·7071–0·7097, which are similar to those of the associated granites. The granites were formed either by fractional crystallisation of the mafic magmas, or by partial melting of newly formed mafic rocks at depth. The high SrI indicates that the mafic magmas were derived from enriched mantle or mixed with enriched crustal materials. Even if the mixing occurred between primitive basaltic magma and metasedimentary rocks, then the basaltic andesite–andesite magmas must have contained more than 60% mantle-derived components. The Cretaceous magmatism in Southwest Japan represents a major episode of crustal growth by additions from the upper mantle in an arc setting.

In the Proterozoic complex of the Schirmacher region of East Antarctica, a retrograde pressure–temperature (P–T) history has been inferred through quantitative geothermobarometry and fluid inclusion studies of the mafic granulites. Microthermometric investigations of the fluid phases trapped in quartz and garnet identified three types of inclusions, namely, earliest pure CO2 inclusions (0·987–1·057 g cm−3), CO2–H2O inclusions and aqueous inclusions.

The temperature and pressure of metamorphism have been estimated through different calibrations of geothermometers and geobarometers. The mineral reactions and compositional zoning in the minerals record P–T conditions from nearly 837 ± 26°C, 7·1±0·2 kbar to 652 ± 33°C, 5·9 ± 0·3 kbar. A good correlation between the fluid and mineral data is observed. The isochores typical of highdensity CO2 fluids fall well within the P–T box estimated by mineral thermobarometry. The abundance of primary CO2 inclusions in early metamorphic minerals (notably quartz and primary garnet) and the general correspondence between fluid and mineral P–T data indicate a ‘fluid-present’ carbonic regime for the high-grade metamorpism; however, from the present data largescale CO2 advection could not be envisaged. The subsequent stages involved a decrease in CO2 density, a progressive influx of hydrous fluids and the generation of retrograde amphibolite facies metamorphism in the area.

The estimated P–T conditions of the region suggest that the rocks were metamorphosed at a depth of 19–24 km, with a geothermal gradient of c. 3°5C km−1. The estimated P–T conditions of the rocks imply a clockwise P–T–t path with a gradual decrease in temperature of around 250°C and a decrease in pressure of around 1700 bar. They have a dP/dT gradient of ≈7 ± l bar °C−1, arguing for an isobaric cooling history of the terrane under normal thickened crust after the underplating of mantle-derived material.

The Lu-Hf and Re-Os isotope systems have been applied sparsely to elucidate the origin of granites, intracrustal processes and the evolution of the continental crust. The presence or absence of garnet as a residual phase during partial melting will strongly influence Lu/Hf partitioning, making the Lu–Hf isotope system exceptionally sensitive to evaluating the role of garnet during intracrustal differentiation processes. Mid-Proterozoic (1·1–1·5Ga ) ‘anorogenic’ granites from the western U.S.A. appear to have anomalously high εHf values, relative to their εNd values, compared with Precambrian orogenic granites from several continents. The Hf-Nd isotope variations for Precambrian orogenic granites are well explained by melting processes that are ultimately tied to garnet-bearing sources in the mantle or crust. Residual, garnet-bearing lower and middle crust will evolve to anomalously high εHf values over time and may be the most likely source for later ‘anorogenic’ magmas. When crustal and mantle rocks are viewed together in terms of Hf and Nd isotope compositions, a remarkable mass balance is apparent for at least the outer silicate earth where Precambrian orogenic continental crust is the balance to the high-εHf depleted mantle, and enriched lithospheric mantle is the balance to the low-εHf depleted mantle.

Although the continental crust has been envisioned to have exceptionally high Re/Os ratios and very radiogenic Os isotope compositions, new data obtained on magnetite mineral separates suggest that some parts of the Precambrian continental crust are relatively Os-rich and non-radiogenic. It remains unclear how continental crust may obtain non-radiogenic Os isotope ratios, and these results have important implications for Re-Os isotope evolution models. In contrast, Phanerozoic batholiths and volcanic arcs that are built on young mafic lower crust may have exceptionally radiogenic Os isotope ratios. These results highlight the unique ability of Os isotopes to identify young mafic crustal components in orogenic magmas that are essentially undetectable using other isotope systems such as O, Sr, Nd and Pb.

The paradox of Lachlan Fold Belt (LFB) granitoids is that although contrasted chemical types (S- and I-types) imply melting of distinct crustal sources, the simple Nd–Sr–Pb–O isotopic arrays indicate a continuum, suggesting mixing of magmatic components. The paradox is resolved by the recognition that the previously inferred, isotopically primitive end-member is itself a crust-mantle mix, so that three general source components, mantle, lower crust and middle crust, comprise the granitoids. Based on Nd isotopic evidence, mantle-derived basaltic magmas melted and mixed with Neoproterozoic-Cambrian, arc-backarc-type material to produce primitive I-type, parental granitoid magmas in the lower–middle crust. Ordovician metasediment, locally underthrust to mid-crustal levels, was remobilised under the elevated geotherms and is most clearly recognised as diatexite in the Cooma complex, but it also exists as gneissic enclaves in S-type granites. The diatexite mixed with the hybrid I-type magmas to produce the parental S-type magmas. Unique parent magma compositions of individual granite suites reflect variations within any or all of the three major source components, or between the mixing proportions. For example, chemical tie-lines between Cooma diatexite and mafic I-type Jindabyne suite magma encompass almost all mafic S-type granites of the vast Bullenbalong supersuite, consistently in the proportion Jindabyne: Cooma, 30:70. The modelling shows that LFB S-type magmas are heavily contaminated I-type magmas, produced by large-scale mixing of hot I-type material with lower temperature diatexite in the middle crust. The model implies a genetic link between migmatite and pluton-scale, crustally derived (S-type) granites.

Given the chemical and isotopic contrasts of the crustally derived source components, and their typically unequal proportions in the magmas, it is not surprising that the LFB granitoids are so distinctive and have been categorised as S- and I-type. The sublinear chemical trends of the granitoid suites are considered to be secondary effects associated with crystal fractionation of unique parental magmas that were formed by three-component mixing. The model obviates the necessity for multiple underplating events and Proterozoic continental basement, in accordance with the observed tectonostratigraphy of the Lachlan Fold Belt.

Silicic and minor intermediate and mafic pyroclastics, lavas, and dykes occupy a NW-trending zone through the Whitsunday, Cumberland and Northumberland Island groups, and locally areas on the adjacent mainland, over a distance of more than 300 km along the central Queensland coast. K-Ar and Rb-Sr data indicate an age range of 95–132 Ma, with the main activity approximately between 105–120 Ma; there is, however, evidence for easterly increasing ages. Comagmatic granites, some clearly intrusive into the volcanics, occur together with two localised areas of Triassic potassic granites (229 Ma), that form the immediate basement.

The volcanics are dominantly rhyolitic to dacitic lithic ignimbrites, with intercalated surge and bedded tuffs, accretionary lapilli tuffs, and lag deposits. Associated rock types include isolated rhyolitic and dacitic domes, and volumetrically minor andesite and rare basalt flows. The sequence is cut by abundant dykes, especially in the northern region and adjacent mainland, ranging from dolerite through andesite, dacite and rhyolite. Dyke orientations show maxima between NW-NNE. Isotope data, similarities in petrography and mineralogy, and alteration patterns all suggest dyke intrusion to be broadly contemporaneous with volcanism. The thickness of the volcanics is unconstrained, although in the Whitsunday area, minimum thicknesses of >1 km are inferred. Eruptive centres are believed to occur throughout the region, and include at least two areas of caldera-style collapse. The sequences are thus considered as predominantly intracaldera.

The phenocryst mineralogy is similar to modern “orogenic” volcanics. Phases include plagioclase, augite, hypersthene (uralitised), magnetite, ilmenite, with less common hornblende, and even rarer quartz, sanidine, and biotite. Fe-enriched compositions only develop in some high-silica rhyolites. The granites range from quartz diorite to granite s.s., and some contain spectacular concentrations of partially disaggregated dioritic inclusions.

Chemically, the suite ranges continuously from basalt to high-silica rhyolite, with calc-alkali to high-K affinities, and geochemical signatures similar to modern subduction-related magmas. Only the high-silica rhyolites and granites exhibit evidence of extensive fractional crystallisation (e.g. pronounced Eu anomalies). Variation within the suite can only satisfactorily be modelled in terms of two component mixing, with superimposed crystal fractionation. Nd and Sr isotope compositions are relatively coherent, with εNd + 2·2 to +7·3, and ISr (calculated at 110 and 115 Ma) 0·7031-0·7044. These are relatively primitive, and imply mantle and/or newly accreted crustal magma sources.

The two end-members proposed are within-plate tholeiitic melt, and ?low-silica rhyolitic melts generated by partial fusion of Permian (to ?Carboniferous) arc and arc basement. The arc-like geochemistry is thus considered to be source inherited. The tectonic setting for Cretaceous volcanism is correlated with updoming and basin rifting during the early stages of continental breakup, culminating in the opening of the Tasman Basin. Cretaceous volcanism is also recognised in the Maryborough Basin (S Queensland), the Lord Howe Rise, and New Caledonia, indicating the regional extent of volcanism associated with the complex breakup of the eastern Australasian continent margin.