Radiocarbon measured in seawater dissolved inorganic carbon (DIC) can be used to investigate ocean circulation, atmosphere/ocean carbon flux, and provide powerful constraints for the fine-tuning of general circulation models (GCMs). Time series of 14C in seawater are derived most frequently from annual bands of hermatypic corals. However, this proxy is unavailable in temperate and polar oceans. Fish otoliths, calcium carbonate auditory, and gravity receptors in the membranous labyrinths of teleost fishes, can act as proxies for 14C in most oceans and at most depths. Arcto-Norwegian cod otoliths are suited to this application due to the well-defined distribution of this species in the Barents Sea, the ability to determine ages of individual Arcto-Norwegian cod with a high level of accuracy, and the availability of archived otoliths collected for fisheries research over the past 60 years. Using measurements of 14C derived from Arcto-Norwegian cod otoliths, we present the first pre- and post-bomb time series (1919–1992) of 14C from polar seas and consider the significance of these data in relation to ocean circulation and atmosphere/ocean flux of 14C. The data provide evidence for a minor Suess effect of only 0.2‰ per year between 1919 and 1950. Bomb 14C was evident in the Barents Sea as early as 1957 and the highest 14C value was measured in an otolith core from a cod with a birth date of 1967. The otolith 14C data display key features common to records of 14C obtained from a Georges Bank mollusc and corals from the tropical and subtropical North Atlantic.

This list contains the results of measurements madeduring 1965 and 1966. Samples are counted in theform of acetylene gas, as previously, and agescomputed on the basis of the Libby half-life, 5568 ±30 yr. The error listed is always larger than theone-sigma statistical counting error commonly used,takes into account known uncertainty laboratoryfactors, but does not include external (field oratmospheric) variations.

We estimate the blank carbon mass over the course of a typical Ramped PyrOx (RPO) analysis (150–1000°C; 5°C×min–1) to be (3.7±0.6) μg C with an Fm value of 0.555±0.042 and a δ13C value of (–29.0±0.1) ‰ VPDB. Additionally, we provide equations for RPO Fm and δ13C blank corrections, including associated error propagation. By comparing RPO mass-weighted mean and independently measured bulk δ13C values for a compilation of environmental samples and standard reference materials (SRMs), we observe a small yet consistent 13C depletion within the RPO instrument (mean–bulk: μ=–0.8‰; ±1σ=0.9‰; n=66). In contrast, because they are fractionation-corrected by definition, mass-weighted mean Fm values accurately match bulk measurements (mean–bulk: μ=0.005; ±1σ=0.014; n=36). Lastly, we show there exists no significant intra-sample δ13C variability across carbonate SRM peaks, indicating minimal mass-dependent kinetic isotope fractionation during RPO analysis. These data are best explained by a difference in activation energy between 13C- and 12C-containing compounds (13–12∆E) of 0.3–1.8 J×mol–1, indicating that blank and mass-balance corrected RPO δ13C values accurately retain carbon source isotope signals to within 1–2‰.

In order to radiocarbon (14C) date a building, several components of the mortar could be used, such as the mortar binder, the lime lumps, the charcoal particles and shell fragments eventually present among the aggregates. In particular, the mortar binder requires a purification treatment in order to separate it from other sources of carbon, which could change the 14C signature of the binder invalidating the dating process. Here, we present the application of the Cryo2Sonic method to 14C dating of the ancient building structures unearthed during excavation at the Padua Cathedral complex. The dated samples were pretreated by using Cryo2Sonic method and the improved Cryo2Sonic version 2.0, recently developed by introducing additional steps such as centrifugation of the mortar suspension and gravimetric sedimentation of the binder fractions. The Cryo2Sonic version 2.0 relies heavily on the characterization of the mortar and of the purified binder fractions, allowing the isolation of a reliable 14C datable mortar fraction. Through this new method, the 14C dating of different ancient structures excavated next to the Padua Cathedral allow to identify the first religious complex of the city of Padua (3rd–4th centuries AD).

We present pollen diagrams and sedimentological analyses from a lake site within an extensive dune system on the Aupouri Peninsula, Northland. Five thousand years ago, a regional Agathis australis–podocarp-broadleaf forest dominated the vegetation, which manifested an increasing preponderance of conifer species. Climate was cooler and drier than at present. From ca. 3400 bp, warmth-loving species such as A. australis and drought-intolerant species, Dacrydium cupressinum and Ascarina lucida, became common, implying a warm and moist climate. The pollen record also suggests a windier climate. The most significant event in the record, however, occurred after ca. 900 bp (800 cal bp) when anthropogenic deforestation commenced. A dramatic decline in forest taxa followed, accompanied by the establishment of a Pteridium–esculentum-dominated community. Fire almost certainly caused this, evidenced by a dramatic increase of charcoal. Sedimentological evidence for this site indicates a relatively stable environment before humans arrived and an increasingly unstable environment with frequent erosional events after human contact.

Research concerning the variability of the marine radiocarbon reservoir effect (ΔR) in the southern Iberian Atlantic coast confirms the existence of different ΔR values for regions that correspond to different oceanographic conditions. Due to these oceanographic conditions, the southern Iberian Atlantic coast can be divided into 3 zones: the Barlavento (windward), where the coastal waters are influenced by an intense upwelling of the northeastern Atlantic circulation (positive ΔR values); the Sotavento (leeward), where an upwelling area of minor intensity occurs; and the Andalusian coast, where because of its configuration does not present any wind-driven coastal upwelling (negative ΔR values). For the first time, ΔR values were determined for the Sotavento coastal region and, at the same time, new ΔR values were calculated for the Barlavento and the Andalusian coast for the last 3000 yr taking into account the data already obtained but now using a new methodology for calculation. In this way, ΔR weighted mean values were determined for the 3 regions of the southern Iberian Atlantic coast: ΔR = +69 ± 17 14C yr (Barlavento), ΔR = −26 ± 14 14C yr (Sotavento), and ΔR = −108 ± 31 14C yr (Andalusian coast). These values are in accordance with the different oceanographic conditions prevailing in these coastal regions. The data also allow identification of a Bond event at 0.8 ka cal BP and a drastic change in the oceanographic conditions in the Barlavento and Andalusian coastal areas during the 5th millennium cal BP.

14C and δ13C values of C-containing species in cave drip waters are mainly controlled by the C isotope composition of karst rock and soil air, as well as by soil carbon dynamics, in particular the amount of soil CO2 in the unsaturated soil zone and the process of calcite dissolution. Here, we investigate soil carbon dynamics by analyzing the 14C activity and δ13C values of C dissolved in cave drip water. Monthly over a 2-yr period, we collected drip water from 2 drip sites, one fast and one relatively slow, within the shallow Grotta di Ernesto Cave (NE Italy). The 14C data reveal a pronounced annual cycle. In contrast, the δ13C values do not show an annual pattern and only small interannual variability compared to the δ13C values of soil waters. The annual 14C drip-water cycle is a function of drip-rate variability, soil moisture, and ultimately hydrology.

The freshwater reservoir effect is a potential problem when radiocarbon dating fish bones, shells, human bones, or food crusts on pottery from sites near rivers or lakes. The reservoir age in hardwater rivers can be up to several thousand years and may be highly variable. Accurate 14C dating of freshwater-based samples requires knowing the order of magnitude of the reservoir effect and its degree of variability. Measurements on modern riverine materials may not give a single reservoir age correction that can be applied to archaeological samples, but they show the order of magnitude and variability that can also be expected for the past. This knowledge will be applied to the dating of food crusts on pottery from the Mesolithic sites Kayhude at the Alster River and Schlamersdorf at the Trave River, both in Schleswig-Holstein, northern Germany.

Dates listed below are based on measurements made from June 1968 to May 1970 by the liquid scintillation technique using benzene. In general, the experimental procedure is as described previously (Barker, Burleigh, and Meeks, 1969a) with a few changes in detail. Data are now processed by computer using a comprehensive Algol program written by Andrew Barker, King's College, Univ. of London. There is no need to standardize on any particular sample weight and, as the benzene synthesizer can also deal with samples in the range up to the equivalent of 9 gm of carbon in a single synthesis, the amount of sample available is now less critical. However, for older material, a minimum of 1 gm of carbon is required. Another factor contributing to efficiency of operation is the “bomb” technique for sample combustion (Barker, Burleigh, and Meeks, 1969b), also mentioned in the previous date list. Finally, during 1969, an MS20 double collection mass spectrometer was acquired and all dates (but not all those in this list) are now corrected for isotopic fractionation.

14C dating with the new Vienna Environmental Research Accelerator (VERA) began with the age determination of a mummified marmot found in the Austrian Alpine region. Soft tissue and bones of the marmot were used for the investigation. For comparison, bone material from known-age samples was also processed and measured. These exercises showed that 14C dating with VERA is reliable, and since that time various samples from archaeological context have been dated.

We also studied the applicability of the 14C method in forensic sciences to determine the time of death of human individuals. 14C/12C measurements of samples from different organic human material (bone collagen, lipids from bone and bone marrow, hair) were performed and compared with the tropospheric “bomb peak” values to transform the measured ratios into “calibrated ages”. For specific substances with rapid turnover rates, this gives an estimate for the time of death of the individual. In our study, lipids and hair yield reasonable times of death, whereas the collagen fraction from bones, which has a relatively long turnover time, is not suitable for this purpose.

The following list of dates contains all measurements made during 1972, i.e., since our last list. Counting equipment, operating procedures and sample pretreatment are the same as previously described (R., 1969, v. 11, p. 263). Age calculations are based on 95% activity of the NBS oxalic acid standard computed from the Libby half-life of 5570 ± 30 yr. Background samples are synthesized from Welsh anthracite. Errors quoted refer only to the standard deviation (1σ) calculated from a statistical analysis of sample, background and standard count rates.

The third series of radiocarbon measurements made at the British Museum Research Laboratory is reported in the following list. Equipment and method used are as described previously (British Museum I) and, as in previous lists, the error terms are not based solely on counting statistics, but are widened to include contributions of ±80 years for possible isotopic fractionation effects and ±100 years for the de Vries effect. Ages are calculated on a half-life of 5568 ± 30 years. NBS oxalic acid is now used as a reference standard in place of 100-yr-old oak. The latter gave an age-corrected value almost exactly 95% of the oxalic-acid activity and thus no corrections are required to our previous date lists to bring them into line with the new standard.

Large sets of radiocarbon dates of 1019 peat, 155 speleothem, and 100 tufa samples, as well as dates of 330 fluvial samples, were investigated in order to estimate environmental variability during the last 16,000 calendar years in Poland. All 14C dating was carried out in the Gliwice Radiocarbon Laboratory, and results are stored in the RoS database. Probability density functions (PDFs) were created by summing up (on the calendar timescale) individual age probability distributions of all dates for different types of material and for different regions of Poland. We used an updated version of the Gliwice Radiocarbon Laboratory calibration program GdCALIB. The 14C dates were calibrated using the IntCal04 calibration curve (Reimer et al. 2004), and results were compared with other paleoenvironmental records. The authors conclude that analyzing PDFs of different types of sediments can be helpful in the qualitative reconstruction of the past environment. The PDF for peat samples primarily reflects paleohydrological conditions; the PDFs for speleothem and tufa samples reflect changes in temperature and humidity, while analysis of the PDF created for fluvial data is in a general agreement with the PDFs constructed for peat samples.

We have carried out a multiproxy analysis of high-resolution eutrophic peat/mud, sand dune, and loess/paleosol sequences covering the Holocene period in both southern and northern China, in order to test the hypothesis of a time-transgressive Holocene optimum in the East Asian monsoon area (An et al. 2000). Samples were radiocarbon dated to establish the chronology. Our results indicate that the Holocene optimum occurred between ∼10,000–5000 cal yr ago in both southern and northern China, consistent with a global pattern rather than simply a local expression. Our data also support the conclusion that the evolution of Holocene climate in China is consistent with changes in Northern Hemisphere solar radiation.

Vindija cave in Croatia is famous for the Neanderthal bones found in layer G of its sediment profile. Radiocarbon dating has been performed mainly on this layer due to the great interest in its fossils. In addition to Neanderthal remains, the sediment in layer G contains bones from the cave bear. Cave bear bones are found also in other layers of the sediment profile and offer the possibility of studying the bears' evolutionary mode. Therefore, we tried to determine the time span covered by the entire profile. The U/Th age determination method was applied to cave bear bones from different layers of the profile. For the younger part of the profile, the U/Th ages were compared with the results of the 14C and the amino-acid racemization method. The agreement of the different methods indicates that closed-system behavior can be assumed for the fossil bones from Vindija cave. From this finding it may be deduced that bones from the lower sediment layers are also closed systems and that the U/Th ages of these layers are reliable. This conclusion is corroborated by the stratigraphy of the cave profile.

The dating of alluvial deposits is frequently hampered by a lack of good-quality charcoal or other material for radiocarbon samples. We have dated two sites in southeastern Australia using traditional radiometric methods with minimal pretreatment. Results yielded an inconsistent chronology, affected by contamination with younger humic materials. A more consistent and older chronology was achieved using AMS dating of rigorously pretreated samples of fine-grained charcoal. The results have important implications for the radiocarbon dating of many Late Quaternary stratigraphic sequences with low charcoal abundance.

A C14-dating installation was operated in the Physics Department, Trinity College, Dublin, from early 1958 until early 1960, by I. R. McAulay. Construction and testing of the apparatus had occupied 15 months previous to this. Material for dating was selected and pretreated by W. A. Watts, who also collected and submitted the samples and carried out pollen analyses except where the contrary is stated in the text. The project was a short-term one with two main aims; to obtain a few key archaeologic dates, particularly in the Neolithic, to help orientate chronologic discussion; and to test the validity of the pollen zonation for the post-Atlantic of Mitchell (1956).

Lead white is a man-made white pigment commonly used in works of art. In this study, the possibility of radiocarbon dating lead white pigments alone and in oil paints was explored using well-dated lead white pigments and paints. Resulting 14C ages on lead white pigments produced following the traditional stack process, where carbonate groups results from the incorporation of CO2 originating from fermentation, matched the production years, while radiocarbon dating of lead white made using other industrial processes indicate that 14C depleted CO2 was used in their production. The method was applied to two case studies, where lead carbonate samples were dated in two oil paintings, one Baroque and one from the 20th century. We hereby show that the lead white pigment can be dated by 14C and used as proxy for the time of creation of an artwork. Additionally, a two-step method was developed to allow 14C analysis of both the lead white pigment and oil binder from the same sample. A single lead white paint sample can yield two distinct radiocarbon ages, one from the carbonate and one from the natural organic binder. This study thus proposes new strategies for 14C dating of artworks.

14C is one of the most important anthropogenic radionuclides released to the environment by human activities. Weapon testing raised the 14C concentration in the atmosphere and biosphere to +100% above the natural level. This excess of atmospheric C at present decreases with a half-life of ca 7 years. Recently, a new source of artificially produced 14C in nuclear reactors has become important. Since 1967, the Bratislava 14C laboratory has been measuring 14C in atmospheric 14CO2 and in a variety of biospheric samples in densely populated areas and in areas close to nuclear power plants. We have been able to identify a heavy-water reactor and the pressurized water reactors as sources of anthropogenic 14C. 14C concentrations show typical seasonal variations. These data are supported by measurements of 3H and 85Kr in the same locations. Results of calculations of future levels of anthropogenic 14C in the environment due to increasing nuclear reactor installations are presented.

The measurements reported in this list have been made in the Isotope Laboratory of the Institute of Geophysics during 1963 and are a continuation of the work reported previously (UCLA I and UCLA II). The same counting procedure—CO2 proportional counting at 1 atm pressure in a 7.5 L counter with three energy channels—continues in use. No barometric effect on the background has been observed, presumably because of the combination of fairly constant barometric pressure in this area and the location of the equipment on the ground floor of a five storey building. Dates continue to be calculated on the basis of a C14 half life of 5568 yr according to the decision of the 1962 Cambridge Conference (Godwin, 1962). The modern standard has been taken as 95% of NBS oxalic acid for all organic samples, while for carbonate material such as shells and tufa, dates have been computed on the basis of estimates of the corresponding contemporary C14 activity (Broecker and Walton, 1959) as indicated in the description accompanying the results.