The quartz-sillimanite-garnet rocks of the Precambrian khondalite assemblage of Orissa consist dominantly of SiO2 + Al2O3 + Fe2O3 + FeO (average c. 95%) with Fe2O3 > FeO. An average analysis (H2O and CO2 free) also shows MgO, CaO and Na2O having 1·0, 0·5 and 0·4%, respectively. Compared with average crustal abundances, enrichment is shown in SiO2, Al2O3 and Fetot and depletion shown in MgO, CaO, Na2O and P2O5 with that for CaO being more than an order of magnitude and that for Na2O being a factor of >7. On an SiO2–Al2O3–Fetot plot a clearly defined field, elongate nearly parallel to the SiO2–Al2O3 sideline, is similar to that for deeply weathered soil profiles in Brazil. This correspondence also extends to enrichment, stability or depletion, compared to crustal averages, for Ce, Co, Cu, Ga, La, Ni, Nb, Th, U, Y, Zn and Zr, but not for Ba, Cr and Rb. In addition comparison of the proportions and ratios of alkalis and alkaline earths in average khondalite and in a weathering profile over a granodiorite, considered to be typical of the weathering of continents, shows remarkable similarities.

The major and trace element data are consistent with the khondalites being granulite facies—upper amphibolite facies metamorphic equivalents of a deeply weathered soil profile. Associated quartzites and calc-silicate granulites are interpreted as having been silcretes and calcretes, respectively. This interpretation implies (1) the previous existence of a large stable cratonic mass on which the soil profile formed, (2) climatic conditions suitable for the development of such a profile, (3) topography, drainage systems and groundwater movement in Precambrian times similar to those of present day peneplane regions, (4) the presence of free oxygen in the atmosphere, (5) rapid covering (e.g. by products of volcanism) to preclude mass wasting, (6) a Precambrian stratigraphy in the crystalline rocks of the Eastern Ghats region similar to that of South India, and (7) orogenesis that involved tectonic repetition of lithological units and a mechanism for taking products of surface weathering down to granulite facies P–T conditions and subsequently elevating them.

Chemostratigraphical correlation provides valuable insights into the status of the Colonsay Group, which field and structural studies have left unresolved. Using published discriminant functions, major and trace element data support previously proposed correlations of the Colonsay Limestone with Appin Group (Lower Dalradian) limestones, and particularly with the Ballachulish Limestone Formation. They also tend to preclude correlations with other nearby Dalradian carbonate formations, with marbles of the early Precambrian Lewisian complex, and with miscellaneous unassigned limestones in a similar structural position to the Colonsay Limestone, astride the Great Glen fault.

Approximately 700 samples from five slate, three marble and five quartzite units have been analysed for 26 elements to determine the use of geochemistry in stratigraphic correlation. Statistical treatment of the data has established that for all the slates and marbles, and certain of the quartzites, geochemistry is a viable method of distinguishing units of similar lithology. The most useful elements for distinguishing the four main slate units are P, Cr. Zn, Cu and, to a lesser extent, Rb, Sr, Y, Nb, Ba, La and Ce. Sr may indicate climatic changes or variable organic activity. The three marble units were considered as three limestone and three dolostone types. Dolostones are distinguished by high insoluble residue contents and the elements that distinguish between the dolostones are heavily influenced by these. Limestones, however, have very large differences in Sr. SiO2, Al2O3, K2O, Cr, Mn, Cu, Rb, Sr, Y and Zr have been used in discrimint function analysis. These parameters are strongly controlled by the insoluble residue with Al2O3, K2O, Cr and Rb being correlated with shaley impurities and SiO2, TiO2 and Zr with sandy impurities. Sr, Pb, Y and Zn, and to a lesser extent S and Mn, appear to be associated with the carbonate fraction.

The quartzites were found to be of three major types: (1) a very variable deltaic deposit (Appin Quartzite Formation), (2) marine bodies of immature quartz sands (Glen Coe and Eilde Quartzite formations) and (3) highly mature quartz sands (Binnein Quartzite Formation and northerly outcrops of the Glen Coe Quartzite Formation). It is possible to distinguish these three types on the basis of some trace elements (Zn, Rb, Sr, Y, Ba, La, Ce) but it is not feasible to distinguish between the Glen Coe and Eilde quartzites purely on geochemistry. The Eilde Flags, an immature estuarine sandstone, has a geochemistry intermediate between that of the quartzites and the pelites, although with higher CaO, Zr and Ba than either.