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2 results

The stabilities of secondary tin minerals. Part 2 *: The hydrolysis of tin(II) sulphate and the stability of Sn3O(OH)2SO4
R. Edwards, R. D. Gillard, P. A. Williams
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Mineralogical Magazine / Volume 60 / Issue 400 / June 1996

Published online by Cambridge University Press:

05 July 2018, pp. 427-432
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Tritin(II)dihydroxyoxosulphate, Sn3O(OH)2SO4, is a rare corrosion product found on the surfaces of certain tin alloys. A new synthesis based on the hydrolysis of SnSO4 is described. The stability constant determination of Sn3O(OH)2SO4,s, at 298.2K and 105Pa is determined using direct measurements via electrodes, of the activities of tin(II) and sulphate ions. ΔfG0(298.2K) is equal to −1563.1 ± 0.9 KJ mol−1.

The stabilities of secondary tin minerals: abhurite and its relationships to Sn(II) and Sn(IV) oxides and oxyhydroxides
R. Edwards, R. D. Gillard, P. A. Williams
Journal:

Mineralogical Magazine / Volume 56 / Issue 383 / June 1992

Published online by Cambridge University Press:

05 July 2018, pp. 221-226
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The true formula of abhurite is Sn21Cl16(OH)14O6. A stability constant for the phase has been determined at 298.2 K. For the reaction Sn21Cl16(OH)14O6 (s) + 26H+ (aq) ⇋ 21Sn2+ (aq) + 16Cl− (aq) + 20H2O (1), log KH+ (298.2 K) is equal to -39.9 (7). This value is used to assess the relative stability of abhurite in the natural environment and to evaluate its modes of occurrence in relation to other secondary Sn(II) and Sn(IV) species.

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2 results

The stabilities of secondary tin minerals. Part 2*: The hydrolysis of tin(II) sulphate and the stability of Sn3O(OH)2SO4

The stabilities of secondary tin minerals: abhurite and its relationships to Sn(II) and Sn(IV) oxides and oxyhydroxides

The stabilities of secondary tin minerals. Part 2 *: The hydrolysis of tin(II) sulphate and the stability of Sn3O(OH)2SO4