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Transformation matrices provide a quick, easy, and reliable method for balancing and manipulating chemical reactions in an arbitrary fashion. This chapter shows how the matrices can be applied to balance reactions, calculate equilibrium constants and free-energy changes of reaction, compute equilibrium temperatures, and determine the form of equilibrium equations.
The chemical composition of a multicomponent system is described in terms of a basis set of thermodynamic components, where the components may be, among many possibilities, elements, aqueous species, salts, and gas species. This chapter shows how the choice of entries in the basis set may be modified quickly and easily using transformation matrix operations.
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