Determining free lime content in steelmaking slag is crucial for its safe reuse in road construction. A simple method has been recently developed to rapidly derive this value via cathodoluminescence (CL) imaging of steelmaking slag, previously quenched from 1,000°C to room temperature, according to the illuminated areas corresponding to free lime (luminescence peak at 600 nm). This quenching is required to obtain intense CL from free lime, but the mechanism of such signal enhancement is still unknown. Therefore, the present study investigated the mechanism by comparing the microstructures, CL images, and CL spectra of free lime in quenched and unquenched steelmaking slag. Large amounts of defects, including dislocations, were observed in the free lime emitting intense luminescence at 600 nm, whereas the samples without clear CL exhibited only a few defects. These results and previous studies suggest that the luminescence at 600 nm from free lime is enhanced by the CL originating from oxygen vacancies (380 nm); therefore, the enhancement of the intensity of the free lime CL peak could be attributed to the increase in the oxygen vacancies via quenching from 1,000°C to room temperature.

The finite difference method of the low-alloy wear-resistant steel quenching process wasstudied. The temperature field and cooling rate variation of thickness of 45-mmwear-resistant steel (NM450) were calculated for different quenching practices. Themicrostructure and hardness of quenched plates were examined. The results indicate thatwhen quenching started, the cooling rate was highest on the subsurface and decreasedgradually until the center of the plate. However, as the quenching progressed, the coolingrate distribution along the plate thickness was reversed. The cooling rate increasedlinearly when the heat transfer coefficient (HTC) increased from 0–10 000W/m2 K, and then the speed gradually slowed down until achieving the maximumcooling rate. Close to the plate mid-thickness, the maximum cooling rate was easilyreached. Compared with high-pressure (HP) quenching and low-pressure (LP) quenching, underthe HP + LP continuous quenching mode, it is possible to obtain a high critical coolingrate in the temperature range of 900 °C–400 °C and small temperature difference betweenthe surface and center below 400 °C. The microstructure and hardness distribution on theplate surface for the HP + LP quenching mode indicated 100% martensite on the surface andmartensite with a little granular bainite in the plate center, while the hardnessdifference in the entire steel plate was less than 7%. This study provided guidance forthe formulation and optimization of wear-resistant steel.