Field studies were conducted to evaluate linuron for POST control of Palmer amaranth in sweetpotato to minimize reliance on protoporphyrinogen oxidase (PPO)-inhibiting herbicides. Treatments were arranged in a two by four factorial in which the first factor consisted of two rates of linuron (420 and 700 g ai ha−1), and the second factor consisted of linuron applied alone or in combinations of linuron plus a nonionic surfactant (NIS; 0.5% vol/vol), linuron plus S-metolachlor (800 g ai ha−1), or linuron plus NIS plus S-metolachlor. In addition, S-metolachlor alone and nontreated weedy and weed-free checks were included for comparison. Treatments were applied to ‘Covington’ sweetpotato 8 d after transplanting (DAP). S-metolachlor alone provided poor Palmer amaranth control because emergence had occurred at applications. All treatments that included linuron resulted in at least 98% and 91% Palmer amaranth control 1 and 2 wk after treatment (WAT), respectively. Including NIS with linuron did not increase Palmer amaranth control compared to linuron alone, but it resulted in greater sweetpotato injury and subsequently decreased total sweetpotato yield by 25%. Including S-metolachlor with linuron resulted in the greatest Palmer amaranth control 4 WAT, but increased crop foliar injury to 36% 1 WAT compared to 17% foliar injury from linuron alone. Marketable and total sweetpotato yields were similar between linuron alone and linuron plus S-metolachlor or S-metolachlor plus NIS treatments, though all treatments resulted in at least 39% less total yield than the weed-free check resulting from herbicide injury and/or Palmer amaranth competition. Because of the excellent POST Palmer amaranth control from linuron 1 WAT, a system that includes linuron applied 7 DAP followed by S-metolachlor applied 14 DAP could help to extend residual Palmer amaranth control further into the critical period of weed control while minimizing sweetpotato injury.

Field and greenhouse studies were performed to examine the influence of various surfactants with glyphosate on whole plant efficacy. Relationships were examined between glyphosate phytotoxicity and surfactant properties, including ionic form, degree of ethoxylation, and hydrophobe composition. Cationic tertiary amine surfactants enhanced glyphosate performance in both field and greenhouse studies. Nonionic allinol and octoxynol surfactants were not effective in combination with glyphosate. In field studies, glyphosate efficacy increased with increasing surfactant ethylene oxide (EO) content. Soybean and velvetleaf responded similarly to glyphosate-surfactant spray applications, as both demonstrated significant linear and quadratic relationships between increasing surfactant ethoxylation and phytotoxicity, while common lambsquarters showed a significant linear relationship only. Cationic surfactants were evaluated in the greenhouse and a significant quadratic regression of glyphosate phytotoxicity to common lambsquarters on increasing surfactant ethoxylation indicated an optimum surfactant EO content of about 10 moles. Both tertiary and quaternary ethoxylated fatty amines were effective with glyphosate in decreasing common lambsquarters' fresh weight. Fatty amine hydrophobe composition did not correlate with glyphosate phytotoxicity to common lambsquarters.

Immediately following postemergence application, similar quantities of metribuzin [4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one] were retained on the foliage of downy brome (Bromus tectorum L. # BROTE) and winter wheat (Triticum aestivum L.). Three days following treatment, more metribuzin was present on the surface of the foliage of downy brome than of winter wheat and similar quantities of metribuzin had been absorbed into the interior of the foliage of both species. Fourteen days after treatment, metribuzin had disappeared from the surfaces of the foliage of both species but more metribuzin was present in the interior of the foliage of downy brome than of winter wheat. Results from petri dish studies in the field suggested that the amount of unaltered metribuzin available for absorption by leaves was influenced primarily by volatilization and secondarily by photodecomposition. In addition, small quantities of rainfall may have washed metribuzin from leaf surfaces. In 1984, yield of winter wheat was greater in metribuzin-treated plots than in nontreated check plots.

Bentazon efficacy was evaluated in early, normal, and late plantings of green pea with the addition of four adjuvants: crop oil concentrate (COC), LI-700, Sylgard 309, and X-77. Weed control was improved by all adjuvants in normal and late plantings of green pea, but only by Sylgard 309, X-77, and LI-700 in the early planting. In normal and late plantings, weed control with bentazon applied at 0.56 kg/ha with any adjuvant was equal to weed control with bentazon applied alone at 1.12 kg/ha. Bentazon injury on green pea plants varied from slight to severe, with the lowest injury resulting from bentazon applied with COC and LI-700 and highest injury from bentazon applied with Sylgard 309. Bentazon injury was greater in normal and late plantings than in the early planting.

Cucumber [Cucumis sativus L. ‘Calypso′] susceptibility to the ethyl ester of quizalofop {2-[4-[(6-chloro-2-quinoxyalinyl)oxy] phenoxy] propanoic acid} was investigated under field and greenhouse conditions. Cucumber yield was significantly reduced under field conditions with a single or repeated application of quizalofop at 0.14 or 0.28 kg ai/ha. Under greenhouse conditions, quizalofop significantly suppressed cucumber plant fresh weight with or without the presence of an adjuvant. Enhancement of herbicide activity was related to the concentration of adjuvant. At a higher rate of quizalofop, addition of the lower concentration of an adjuvant increased the herbicidal effect (growth suppression and visually estimated phytotoxicity). At a lower concentration, increasing adjuvant concentration enhanced visually estimated phytotoxicity.

Glyphosate and adjuvant combinations were applied to rhizome johnsongrass at vegetative and reproductive growth stages to evaluate control and rainfastness in field studies. Using a rainfall simulator delivering 1.3 cm of water in 15 min, plots received either no rainfall or rainfall 15 or 60 min after glyphosate was applied at 2.1 kg ai/ha in combination with the nonionic surfactants Kinetic® HV at 0.25% (v/v) or Induce® at 1.0% (v/v) or the silicone surfactant Break-Thru® at 0.125% (v/v). Regardless of adjuvant, rainfall 15 or 60 min after application reduced johnsongrass control compared with no rainfall. Johnsongrass control 14 d after treatment at the reproductive stage was at least 89% with no rainfall, but no more than 53 and 65% with rainfall at 15 and 60 min, respectively. Based on initial weed control, adjuvants did not consistently improve rainfastness. Johnsongrass regrowth did not occur when glyphosate was applied with either adjuvant. In contrast, for glyphosate applied to johnsongrass in the vegetative stage, addition of Break-Thru improved control over Induce at both 15- and 60-min rainfall timings in one of two experiments. With no rainfall, addition of Kinetic HV and Break-Thru increased johnsongrass control in only one experiment. For application at the vegetative stage, johnsongrass regrowth averaged across rainfall timings was no more than 10%. In other field experiments, glyphosate at 1.4 kg/ha plus nonionic surfactants, silicone surfactant, crop oil concentrate, methylated seed oil, or a blend of silicone surfactant and methylated seed oil were equally effective in reducing johnsongrass regrowth when applied after seedhead emergence. Improved control of vegetative johnsongrass with some adjuvants was not reflected in decreased regrowth.

Hemp sesbania control by chlorimuron applied with crop oil concentrate at 1.0% v/v, BCH 815 at 1.0% v/v, methylated seed oil at 1.0% v/v, a blend of methylated seed oil and organosilicone surfactant at 0.5% v/v, organosilicone-based surfactant at 0.125% v/v, and nonionic surfactant at 0.25% v/v was evaluated in field studies in 1994 and 1995. Control by chlorimuron at 4.5 g ae/ha was greater when applied with BCH 815, organosilicone-based surfactant, and nonionic surfactant than with crop oil concentrate, methylated seed oil, and a blend of methylated seed oil and organosilicone surfactant. When chlorimuron was applied at 4.5 g/ha with BCH 815 or nonionic surfactant, hemp sesbania control was similar to that by chlorimuron at 9 g/ha applied with methylated seed oil, the blend of methylated seed oil and organosilicone surfactant, or organosilicone-based surfactant.

The effect of nonionic surfactant, crop oil concentrate, organosilicone surfactant, methylated seed oil, and a blend of organosilicone surfactant and methylated seed oil on absorption of 14C-clethodim was evaluated in barnyardgrass (Echinochloa crus-galli). Absorption of 14C-label was greatest during the first 40 min after application when 14C-clethodim was applied with methylated seed oil or a blend of methylated seed oil and organosilicone surfactant. These adjuvants increased the rate of absorption more than crop oil concentrate, organosilicone surfactant, or nonionic surfactant. Crop oil concentrate was more effective than organosilicone or nonionic surfactant in increasing absorption, with nonionic surfactant being more effective than organosilicone surfactant. These results generally agreed with the order of increasing efficacy of clethodim on barnyardgrass as affected by adjuvants in field experiments. Another study was conducted to determine the effect of bromoxynil on absorption and translocation of 14C-clethodim in yellow foxtail (Setaria glauca). Bromoxynil reduced absorption of 14C–clethodim 4, 8, and 24 h after application and also reduced the amount of 14C-label translocated from the treated leaf. These data suggest that antagonism of clethodim control of yellow foxtail by bromoxynil observed in previous research can be attributed partially to decreased absorption and translocation of clethodim.

Field studies were conducted from 1982 to 1984 to evaluate the effectiveness of SC-0224 (trimethylsulfonium carboxymethylaminomethylphosphonate) and glyphosate [N-(phosphonomethyl)glycine] for quackgrass [Agropyron repens (L.) Beauv. # AGRRE] control. The herbicides were compared 1) in different rates and carrier volumes, 2) on several spring and fall application dates, and 3) with varying time intervals between application and moldboard plowing. Glyphosate and SC-0224 controlled quackgrass equally well at carrier volumes of 25 to 400 L/ha. Both herbicides generally provided similar control as fall and spring applications and with time intervals of 12 to 96 h between application and plowing. Occasionally the low rate of SC-0024 gave less quackgrass control the next season than the same rate of glyphosate. Adding nonionic surfactant at 0.5% (v/v) did not influence the phytotoxicity of these herbicides at the rates and carrier volumes tested. These herbicides controlled quackgrass comparably and greater than 85% when applied under appropriate environmental conditions.

Field experiments evaluated barnyardgrass, broadleaf signalgrass, and rhizomatous johnsongrass control with clethodim applied with Agri-Dex® crop oil concentrate at 1.0% v/v, the adjuvant Dash® at 1.0% v/v, the methylated seed oil Sun-It II® at 1.0% v/v, a blend of silicone surfactant plus methylated seed oil (Dyne-Amic® at 0.5% v/v) or nonionic surfactant (Kinetic® HV at 0.125% v/v), two silicone surfactants (Sylgard® 309 and Silwet L-77® surfactant) at 0.125% v/v, two other conventional nonionic surfactants (Latron AG-98™ and Induce®) at 0.25% v/v, and the acidified soya phospholipid LI-700®. When compared with the conventional nonionic or silicone-based surfactants and LI-700, clethodim at 70 g ai/ha controlled barnyardgrass more effectively when applied with Dash or Sun-It II. Broadleaf signalgrass and rhizomatous johnsongrass were controlled more effectively when clethodim was applied with Agri-Dex, Dash, Sun-It II, or Dyne-Amic. Clethodim at 70 g/ha applied with Dash or Sun-It II controlled grasses equally or greater than clethodim at 140 g/ha.

Changing the number of ethylene oxide (EO) units on a nonylphenol surfactant changes its physicochemical and biological properties. Increasing the number of EO units makes the surfactant more hydrophilic and increases its hydrophilic-lipophilic balance (HLB). Surfactants with high HLB values, more than 16, were the most active with the hydrophilic herbicide glyphosate. More lipophilic surfactants with HLB values from 11 to 13 were more active with the lipophilic herbicide, the ethyl ester of quizalofop-P. Surfactants with intermediate HLB values were the most active with the herbicide that had intermediate water solubility, nicosulfuron. Matching the physicochemical properties of the herbicide and surfactant improved biological efficacy on giant foxtail.

Field experiments were established to observe the effects of adjuvants and time of application on weed control and ‘Terra-Vig 515’ soybean tolerance with POST applications of AC 263,222. A nonionic surfactant or a crop oil concentrate increased sicklepod control with AC 263,222 applied at either V2 or V6 soybean growth stages. Sicklepod control increased as AC 263,222 was increased from 35 to 70 g ai ha–1 only when applied without an adjuvant. Late in the season, there was no difference in sicklepod control between V2 and V6 applications. Adjuvants and application timing within herbicide treatments had no effect on pitted morningglory control, and, though adjuvants increased common cocklebur control, all treatments controlled more than 85% of both species. AC 263,222 with adjuvants at all rates and timings injured and stunted soybean more 2 wk after treatment compared to AC 263,222 alone. AC 263,222 at 35 or 70 g ha–1 with crop oil concentrate reduced yields more than AC 263,222, with either a surfactant or no adjuvant when applied to V2 soybeans.

Ammonium fertilizers, petroleum oil concentrate, and nonionic surfactant were evaluated as postemergence spray additives to improve giant foxtail and volunteer corn control by 28 g ai ha−1 of the ethyl ester of quizalofop or 56 g ha−1 sethoxydim. Additions of 0.25% by vol nonionic surfactant or 2.5% petroleum oil concentrate improved grass control, but additions of 10% urea ammonium nitrate (28-0-0), 10% ammonium polyphosphate (10-34-0), or 0.1M ammonium sulfate (21-0-0-24S) did not consistently affect grass control. In laboratory studies with corn, greatest 14C absorption from leaf-applied 14C-quizalofop (8 h after treatment) was found with additions of petroleum oil concentrate (80% absorbed) or nonionic surfactant (18% absorbed), while less absorption was observed with treatments containing either no additive, urea ammonium nitrate, ammonium polyphosphate, or ammonium sulfate (8 to 13% absorbed). Surface tension and droplet size of spray solutions were affected primarily by additions of nonionic surfactant, petroleum oil concentrate, and the formulated herbicides. Solution density, solute potential, pH, and buffering capacity were primarily affected by fertilizer additions.

Certain linear alcohol ethoxylate surfactants with large hydrophobes enhanced nicosulfuron activity on giant foxtail (Setaria faberi) more effectively at low doses than surfactants with small hydrophobes and commercial standards. The most effective surfactants had a C16–18 hydrophobe and 12 to 30 moles of ethoxylation or a C24 hydrophobe with 13 moles of ethoxylation. Response curve analysis showed these linear alcohol ethoxylate surfactants were five- to 20-fold more active on a dose basis than currently used commercial surfactants.

Chlorimuron and imazethapyr applied with nonionic surfactant, crop oil concentrate, or organosilicone-based adjuvant were evaluated for purple nutsedge control in the field. Additional experiments compared chlorimuron and imazethapyr control of purple nutsedge when applied with crop oil concentrate at two growth stages. Chlorimuron controlled purple nutsedge better than did imazethapyr in most experiments. Chlorimuron performed better when applied with crop oil concentrate than with nonionic surfactant or organosilicone-based adjuvant. Imazethapyr control with the organosilicone-based adjuvant or crop oil concentrate was similar and greater than imazethapyr with nonionic surfactant. Control was greater when herbicides were applied to 2- to 6-cm tall purple nutsedge compared with plants 8 to 10 cm tall in two of three trials.

Adjuvants enhanced DPX-V9360 control of green foxtail in the greenhouse and field as follows: methylated sunflower oil > petroleum oil > nonionic surfactant WK > nonionic surfactant X-77. DPX-V9360 applied at rates that controlled weeds did not injure corn. Green foxtail control with DPX-V9360 decreased as the amount of simulated rainfall after application increased from 0 to 4 mm and control increased as a 2 mm simulated rainfall was delayed up to 24 h. The influence of simulated rainfall differed with adjuvants, but adjuvants did not overcome the lower green foxtail control with simulated rainfall. DPX-V9360 was more phytotoxic to green foxtail and redroot pigweed at 95 to 100% than 45 to 50% relative humidity and at 20 or 30 C than 10 C after treatment.

Field experiments were conducted in 1988 and 1989 to (i) evaluate annual weed control with nicosulfuron applied at rates of 17 to 70 g ai/ha with several additives and (ii) evaluate annual weed control with nicosulfuron applied at rates of 17 to 105 g/ha at three corn growth stages. In 1988, in the adjuvant study, giant foxtail control increased linearly with no additive or with urea ammonium nitrate as the rate of nicosulfuron increased. Petroleum oil concentrate, nonionic surfactant, and a combination of either petroleum oil concentrate or nonionic surfactant with urea ammonium nitrate applied with nicosulfuron increased giant foxtail control to 90% or greater regardless of rate both years. Nicosulfuron at all rates with no additive and in combination with all additives controlled 93% or more of redroot pigweed and Pennsylvania smartweed both years. Corn grain yield was related to the level of giant foxtail control. In the rate by corn growth stage study, giant foxtail, redroot pigweed, and Pennsylvania smartweed control was 90% or greater regardless of nicosulfuron rate or application stage both years. Corn grain yield was related more to the duration of weed competition than the level of weed control with grain yield 8 to 12% lower with nicosulfuron applied at the V7 growth stage compared with the V3 or V5 growth stage.

Foliar and root absorption and translocation of metribuzin (4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one) by downy brome (Bromus tectorum L. # BROTE) and winter wheat (Triticum aestivum L.) was determined. After a 48-h absorption period, roots of three-week-old downy brome plants had absorbed two times more metribuzin on a total plant fresh weight basis than had roots of winter wheat. Root-absorbed metribuzin was translocated similarly regardless of species with 80% of absorbed 14C accumulating in leaf blades, 10% in the leaf sheaths, and 10% in the roots. After 24 h, leaves of downy brome and winter wheat had absorbed, respectively, 26 and 36% of foliar-applied metribuzin, and absorption increased threefold with the addition of a nonionic surfactant. Translocation of foliar-absorbed metribuzin was primarily towards the apex of the treated leaf. No translocation from the treated leaf to other plant parts occurred with either species. The greater tolerance of winter wheat to metribuzin is due in part to less root absorption of metribuzin by winter wheat than by downy brome.

Greenhouse and field experiments were conducted to evaluate the effectiveness of nicosulfuron and primisulfuron with different adjuvants on wirestem muhly control. The adjuvants evaluated with the two herbicides included a nonionic surfactant, crop-oil concentrate, crop-oil concentrate plus urea-ammonium nitrate, methylated vegetable-oil concentrate, and organosilicone methylated vegetable-oil concentrate. In the greenhouse, nicosulfuron and primisulfuron performance was similar, although small differences occurred between adjuvants and herbicides. In the field, changing adjuvant affected nicosulfuron performance more than primisulfuron and in general, greater control was achieved with nicosulfuron than with primisulfuron. Among adjuvants, methylated vegetable-oil concentrate provided greater wirestem muhly control with nicosulfuron and sometimes primisulfuron compared to the others, while the nonionic surfactant was the least effective with both herbicides. Regardless of adjuvant, none of the field-applied treatments controlled wirestem muhly much beyond the 12 wk-evaluation period.

Diammonium sulfate often is used as an adjuvant with glyphosate. Experiments were conducted in the greenhouse to determine the effectiveness of diammonium sulfate in overcoming calcium antagonism of glyphosate toxicity to wheat, sunflower, kochia, and soybean. Each species was a separate experiment and treatments varied with the experiment. Diammonium sulfate at 0.5% (w/v) in a spray carrier containing calcium chloride (500 ppm calcium) overcame calcium antagonism of glyphosate toxicity to wheat, overcame antagonism and enhanced toxicity to sunflower, but only partly overcame calcium antagonism of toxicity to kochia and soybean. With glyphosate at 100 g ae ha–1, diammonium sulfate at 2% (w/v) in a distilled water spray carrier enhanced toxicity to sunflower from a 11% to a 55% fresh weight reduction but was antagonistic to glyphosate toxicity to kochia and soybean.