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1 results

  • Metavivianite and kerchenite: a review

  • K. A. Rodgers
  • Journal:
    Mineralogical Magazine / Volume 50 / Issue 358 / December 1986
    Published online by Cambridge University Press:
    05 July 2018, pp. 687-691

  • Metavivianite has been shown to be not dimorphous with vivianite. Assuming the homogeneity and uniformity of the original type samples, it is a triclinic hydrated ferri-ferrous hydroxy phosphate whose formula may be given as Fe2+3-xFe3+x(po4)2(OH)x(8-x)H2O where x > 1.4. The precise oxidation limits between which the triclinic lattice is stable are not known but the structure persists close to total oxidation of all iron. The structure of metavivianite was established using a fragment of kerchenite whose formula as originally given is covered by the general metavivianite formula. Assuming the homogeneity of the original (1907) samples, kerchenite and metavivianite appear to be identical.