Reliable spectroscopic data are needed for interpretation and modeling of observed astrophysical plasmas. For heavy element ions, which have complex spectra, experimental data are rather incomplete. To provide valuable fundamental quantities, such as precise wavelengths, level energies and semi-empirical transition probabilities, we are carrying out laboratory studies of high-resolution VUV emission spectra of moderately charged ions of transition metals and rare earth elements. Experimental and theoretical methods are summarized. Examples of studies are described.