Compound words consist of two or more words which combine to form a single word or phrase that acts as one. In English, the head of compound words is usually, but not always, the right-most root (e.g., “paycheck” is a noun because the head, “check,” is a noun). The current study explores the effects of head position on language control by examining language switching performance through electroencephalography (EEG). Twenty-one pairs of Chinese (L1)–English (L2) bilinguals performed cued language switching in a simultaneous production and comprehension task. The results showed that bilinguals recognized the head position earlier both in production and comprehension. However, the language control of the head position during production occurred in the middle stage (N2), but in the late stage (LPC) during comprehension. These findings indicate that the head position in compound words exerts differential influences on language control.