Due to increasingly complex and automated manufacturing processes, the demands on the control parameters of these processes are also increasing. One parameter is the fill quantity of, e.g., liquids in production plants, whose precise determination is of ever-growing importance. Up to now, the exact level of determination under difficult conditions, such as high ambient temperatures, has been a particular challenge. This paper demonstrates a novel method by which an M-sequence UWB radar can determine levels of low-permittivity materials in small metal containers. For this purpose, hot melt is used as an example. Thus, the influence of large temperature differences on the long-term stability of level measurement can also be investigated. The measurements show that the level of hot melt can be measured to be long-term stable with an accuracy of better than 3 mm. Furthermore, the precise determination of the empty state is highly important for many applications. For this reason, this paper shows a method for determining the empty state without complex calibration procedures. For the empty level indication, an accuracy of up to 0.5 mm could be achieved for molten hot glue and 3% of the tank volume, independent of the shape or aggregate state of the medium.