We consider a feed-forward network with a single-server station serving jobs with multiple levels of priority. The service discipline is preemptive in that the server always serves a job with the current highest level of priority. For this system with discontinuous dynamics, we establish the sample path large deviation principle using a weak convergence argument. In the special case where jobs have two different levels of priority, we also explicitly identify the exponential decay rate of the total population overflow probabilities by examining the geometry of the zero-level sets of the system Hamiltonians.
