Amicarbazone, atrazine, and metribuzin behavior was examined in a field setting in Tennessee and in a laboratory setting using soils collected from Illinois and Tennessee. Fields planted to corn were sampled from 0 to 8 cm depth, and the samples were analyzed using methanolic extraction followed by tandem mass spectrometry analysis to determine residual herbicide concentrations. Conditions were favorable for herbicide degradation, including warm temperatures and adequate rainfall. All herbicide half-lives were <10 d. Laboratory research using soils with known atrazine-use histories showed that amicarbazone did not exhibit enhanced microbial degradation due to previous atrazine use. Apparent amicarbazone and metribuzin persistence levels implied that early-season weed control would be expected, but carryover to injure sensitive rotational crops would not be anticipated under these environmental conditions. Dissipation under field conditions of amicarbazone and metribuzin was not affected by being applied to separate plots or by coapplication to the same plots.

More growers across the U.S. Midwest are considering interseeding or overseeding cover crops into corn for soil health purposes. One challenge of this practice is the potential injury from soil residual herbicides applied preemergence (PRE) for weed control in corn to the interseeded and overseeded cover crop species. Field-treated soil was collected in 2021 and 2022 at Janesville, WI, and Lancaster, WI, to investigate the impact of PRE residual herbicides on establishment of interseeded and overseeded cover crops via greenhouse bioassay. Soil samples (0 to 5 cm depth) were collected from field experiments at 0, 10, 20, 30, 40, 50, 60, and 70 days after treatment (DAT). Treatments consisted of 14 single and multiple sites of action (SOAs) PRE herbicides plus a nontreated check (NTC). Four bioindicator cover crop species were used in the greenhouse bioassay: annual ryegrass, cereal rye, radish, and red clover. Cover crop biomass was collected 28 d after bioassay seeding. Cover crop species responded differently across herbicide treatments. Annual ryegrass and cereal rye were sensitive to treatments containing herbicide Group 15, whereas Groups 2, 4, 5, 14, and 27 had minimal impact on their establishment when field soil was collected at 30 DAT (interseeding scenario) and 70 DAT (overseeding scenario) compared to the NTC. Radish and red clover were sensitive to herbicide Groups 2, 4, and 27, whereas Groups 5, 14, and 15 had minimal impact on their establishment. Annual ryegrass, radish, and red clover were more sensitive to PRE herbicides containing two and three SOAs than to herbicides with a single SOA. On the basis of these greenhouse bioassay results, cover crop species should be carefully selected depending on the soil residual herbicide when interseeded and overseeded into corn. Field studies will be conducted to validate these results and support recommendations to growers interested in this system.

Sulfentrazone was recently granted food-use tolerance approval for use on Brassica head and stem, as well as Brassica leafy vegetables. To date, one sulfentrazone registrant has listed those crops on its use label. In coastal California multiple crops per year including Brassica vegetables are grown in rapid succession; therefore, to avoid injury to rotational crops, herbicides used in those fields must be carefully selected. Given concerns about the relatively long soil persistence of sulfentrazone, studies were conducted to measure the response of direct-seeded carrot, lettuce, onion, spinach, and seeded tomato planted 3, 6, 9, and 12 mo after sulfentrazone application at 0, 112, 224, and 336 g ai ha−1. Eight plant-back studies were conducted during 2010–11 and 2012–13. Data collected were injury estimates, and stand and dry weights. Results indicate that it is safe to plant carrot and tomato 3 mo after sulfentrazone application at rates up to 336 g ai ha−1. Lettuce and green onion should not be planted within 9 mo of sulfentrazone application. Spinach should not be planted within 12 mo of sulfentrazone application.

Grape hyacinth is a perennial bulbous species in the Liliaceae. It is commonly grown as an ornamental plant, but it can spread into agricultural fields and become weedy, potentially interfering with harvest and fall-planted crops. There has been limited research on controlling grape hyacinth in cropping systems. Fall and spring applied field-research studies were conducted to determine grape hyacinth control with herbicides labeled for use in wheat or winter fallow before planting soybean. Among fall-applied herbicides, paraquat resulted in the greatest initial grape hyacinth control (90% to 100%). Grape hyacinth control, 16 months after application (MAA), was variable, but the top-performing treatments were glyphosate and metsulfuron plus paraquat, resulting in 65% and 50% control, respectively. After spring applications, grape hyacinth control in November (7 MAA) was variable, but top-performing treatments were glyphosate and metsulfuron, which resulted in at least 26% control. Spring-applied paraquat, carfentrazone, metsulfuron, and sulfosulfuron resulted in 73%, 68%, 69%, and 60% reductions in grape hyacinth bulb counts, compared with the nontreated control 7 MAA, and were the top-performing treatments. Despite product-label prohibitions on rotation to soybeans, no soybean yield reductions were observed from any treatment in either study. Single applications of certain herbicides in the fall or spring can result in good control (>80%) of grape hyacinth initially, but long-term control is poor, and additional research is required.

This study utilizes a dynamic programming decision model, considering an intertemporal nitrogen carryover function, combined with both linear stochastic and deterministic plateau response functions to evaluate optimal nitrogen fertilizer decision rules and net present values (NPVs) in Texas High Plains cotton production. Nitrogen recommendations and NPVs are influenced by response function choice and nitrogen-to-cotton price ratios. Results indicate the stochastic plateau function better describes the data; the optimum nitrogen recommendation is to apply approximately 40 lb. of nitrogen for each bale of cotton production when considering nitrogen carryover information.

Off-target movement of dicamba and 2,4-D may injure and reduce the yield of many fruit and vegetable crops, impacting specialty crop producers and herbicide applicators alike. Two field experiments were established, using plant growth regulator–resistant soybean herbicide technologies, to evaluate drift and carryover risks to horseradish production. The drift experiment was conducted in 2015 and 2016 to evaluate impact of dicamba and 2,4-D simulated drift on horseradish production with a mid-POST application in soybean. Simulated drift rates were 1/10,000X, 1/1,000X, and 1/100X, with 1/2X, 1X, and 2X of standard application rates. Injury and yield loss was greater following application of 2,4-D than with dicamba. Yield reductions were observed beginning at the 1/1,000X rate of 2,4-D, with complete crop loss occurring when rates exceed 1/2X. In comparison, dicamba only reduced yields when applied at the 1X and 2X rates. Only horseradish roots from plants treated with dicamba at the 2X rate had greater dicamba residue than the nontreated control, and the amount detected, 0.32 parts per billion (ppb), was lower than the EPA tolerance of 100 ppb in root crops. There was little to no harvestable tissue for 2,4-D residue analysis for plants treated with 2,4-D at rates above 1/2X. The carryover experiment was a 2-yr rotational evaluation conducted in 2014, 2015, and 2016 to assess dicamba carryover to horseradish following application to dicamba-resistant soybean the previous season. Observations taken at 4, 6, and 8 wk after planting indicated no significant horseradish injury, nor was height, stand, or root weight reduced. These results suggest that horseradish growers should have few concerns about injury from dicamba drift or carryover. While 2,4-D applicators may need to be cautious when making applications near horseradish fields, 2,4-D may be an effective tool for controlling volunteer horseradish in 2,4-D–resistant soybean.

The triazines are one of the most widely used herbicide classes ever developed and are critical for managing weed populations that have developed herbicide resistance. These herbicides are traditionally valued for their residual weed control in more than 50 crops. Scientific literature suggests that atrazine, and perhaps other s-triazines, may no longer remain persistent in soils due to enhanced microbial degradation. Experiments examined the rate of degradation of atrazine and two other triazine herbicides, simazine and metribuzin, in both atrazine-adapted and non-history Corn Belt soils, with similar soils being used from each state as a comparison of potential triazine degradation. In three soils with no history of atrazine use, the t1/2 of atrazine was at least four times greater than in three soils with a history of atrazine use. Simazine degradation in the same three sets of soils was 2.4 to 15 times more rapid in history soils than non-history soils. Metribuzin in history soils degraded at 0.6, 0.9, and 1.9 times the rate seen in the same three non-history soils. These results indicate enhanced degradation of the symmetrical triazine simazine, but not of the asymmetrical triazine metribuzin.

Glyphosate-resistant (GR) Italian ryegrass is one of the most troublesome weeds in Mississippi row crop production. Fall-applied residual herbicide applications are recommended for control of GR Italian ryegrass. However, carryover of residual herbicides applied in fields for rice production can have a negative impact on rice performance. Field studies were conducted in Stoneville, MS, to determine the effects of fall-applied residual herbicides on rice growth and yield. Herbicide treatments included suggested use rates (1×) of clomazone at 840 g ai ha–1, pyroxasulfone 170 g ai ha–1, S-metolachlor 1,420 g ai ha–1, and trifluralin 1,680 g ai ha–1, and two times (2×) the suggested use rates in the fall before rice seeding. Pooled across application rate, pyroxasulfone, S-metolachlor, and trifluralin injured rice to an extent 28% to 36% greater than clomazone 14 d after emergence (DAE). Rice seedling density and height 14 DAE and rice maturity were negatively affected by all fall-applied herbicides except clomazone. Applications at 2× rates reduced rough rice yields in plots treated with pyroxasulfone, S-metolachlor, and trifluralin compared with clomazone. Pyroxasulfone applied at the 2× rate reduced rough rice yield 22% compared with the 1× rate. Rough rice yield was 90% or greater of the nontreated control in plots treated with either rate of S-metolachlor, and these were comparable with rough rice yields from plots treated with both rates of trifluralin and the 1× rate of pyroxasulfone. Early-season injury and reductions in seedling density and height 14 DAE, would preclude even 1× applications of pyroxasulfone, S-metolachlor, and trifluralin from being viable options for residual herbicide treatments targeting GR Italian ryegrass in the fall before rice seeding. Of the herbicides evaluated, only clomazone should be utilized as a fall-applied residual herbicide treatment targeting GR Italian ryegrass before seeding rice.

Field experiments were conducted in 2014 and 2015 in Fayetteville, Arkansas, to evaluate the residual activity of acetyl-CoA carboxylase (ACCase)–inhibiting herbicides for monocot crop injury and weed control. Conventional rice, quizalofop-resistant rice, grain sorghum, and corn crops were evaluated for tolerance to soil applications of six herbicides (quizalofop at 80 and 160 g ai ha–1, clethodim at 68 and 136 g ai ha–1, fenoxaprop at 122 g ai ha–1, cyhalofop at 313 g ai ha–1, fluazifop at 210 and 420 g ai ha–1, and sethoxydim at 140 and 280 g ai ha–1). Overhead sprinkler irrigation of 1.3 cm was applied immediately after treatment to half of the plots, and the crops planted into the treated plots at 0, 7, and 14 d after herbicide treatment. In 2014, injury from herbicide treatments increased with activation for all crops evaluated, except for quizalofop-resistant rice. At 14 d after treatment (DAT) in 2014, corn and grain sorghum were injured 19% and 20%, respectively, from the higher rate of sethoxydim with irrigation activation averaged over plant-back dates. Conventional rice was injured 13% by the higher rate of fluazifop in 2014. Quizalofop-resistant rice was injured no more than 4% by any of the graminicides evaluated in either year. In 2015, a rainfall event occurred within 24 h of initiating the experiment; thus, there were no differences between activation via irrigation or by rainfall. However, as in 2014, grain sorghum and corn were injured 16% and 13%, respectively, by the higher rate of sethoxydim, averaged over plant-back dates. All herbicides provided little residual control of grass weeds, mainly broadleaf signalgrass and barnyardgrass. These findings indicate the need to continue allowing a plant-back interval to rice following a graminicide application, unless quizalofop-resistant rice is to be planted. The plant-back interval will vary by graminicide and the amount of moisture received following the application.

Research was conducted to evaluate the sensitivity of cover crops to a low rate of soil-applied herbicides and investigate the likelihood of herbicide carryover to fall-seeded cover crops following an irrigated corn crop. In the sensitivity study, herbicides were applied at a 1/16×rate (to simulate four half-lives) 1 d after cover crop planting, whereas for the carryover study residual herbicides were applied at a 2×rate at the maximum label corn height or growth stage and cover crops sown immediately after corn harvest. In the sensitivity experiment, atrazine, diuron, fluridone, fomesafen, metribuzin, pyrithiobac, and sulfentrazone reduced emergence of the leguminous cover crops Austrian winterpea, crimson clover, and hairy vetch. However, reduced biomass production of leguminous cover crops in the spring was only observed for atrazine, fluridone, and pyrithiobac. For rapeseed, atrazine, flumioxazin, fluridone, pyrithiobac, pyroxasulfone, sulfentrazone, and tembotrione reduced emergence, but biomass production was reduced only by atrazine and fluridone. Conversely, wheat, cereal rye, barley, oats, and triticale were not affected by soil-applied herbicides. Barley was the only cereal cover crop that showed biomass reduction due to the application of flumioxazin, fluridone, mesotrione, S-metalochlor, and sulfentrazone. In the carryover study, with the exception of crimson clover, Austrian winterpea, cereal rye, hairy vetch, rapeseed, and wheat showed no negative affect on biomass production following a 2×rate of postemergence-applied residual herbicide in corn.

Imazapyr and imazamox are frequently applied postemergence to control grass and broadleaf weeds in imidazolinone-resistant sunflower in Argentina. Herbicide carryover to rotational crops represents a disadvantage of these herbicides, particularly in regions with low rainfall during the months prior to rotational crop sowing. Between 2009 and 2012, field and greenhouse studies were conducted on four important sunflower-cropped areas of Argentina. The objective was to quantify the effects of imazapyr alone and imazamox plus imazapyr applied in sunflower crops on the subsequent establishment, growth, and yield of barley, oat, and wheat. In all field experiments, imazapyr alone and imazamox plus imazapyr were applied at recommended rates (80 gha–1 and 66 plus 30 gha–1, respectively), and also, in some experiments, at double the recommended rates. Soil bioassays were also conducted in the greenhouse to study the effect of these herbicides on barley, oat, and wheat seedlings. The mixture of imazamox plus imazapyr was safer for rotational crops than imazapyr applied alone, because of the reduced rate of imazapyr in the mixture treatments. Barley was more sensitive to imidazolinones, particularly imazapyr, than the other winter cereals. Imazapyr at double rate (160 gha–1) reduced barley yield by 45% when seeds were sown 165 d after herbicide application and with 240 mm rainfall after herbicide application.

This study examined the response of corn to clomazone, chlorimuron, imazaquin, and imazethapyr the year following their application to soybeans. Herbicides were surface-applied from one-half to three times the labeled application rates. Soybeans were planted the year of application and crop tolerance was evaluated. Corn was planted in rotation the following season. Soybeans were tolerant of all four herbicides. The highest rates of clomazone, chlorimuron, and imazaquin injured the corn early in the season. Imazethapyr did not influence corn growth. Visual estimates of clomazone injury were as high as 39% chlorosis. Seedling dry weight reductions at the highest chlorimuron and imazaquin rates were 32% and 24%, respectively. Although corn was injured by higher rates of clomazone, imazaquin, and chlorimuron at the 3-leaf stage, none of the herbicides significantly reduced grain yield. This study suggests that these herbicides can carry over and injure corn, especially if labeled application rates are exceeded. However, low to moderate early season injury to corn may not affect grain yield.

Studies were established in 1988, 1989, and 1990 at two locations in Missouri to study the influence of fall tillage and herbicides on carryover of several residual soybean herbicides to grass and legume forage crops. Chlorimuron, clomazone, imazaquin, imazethpyr, and metribuzin plus chlorimuron were applied at their registered and 2X-registered rates in soybeans. Forage crops were planted the following fall and spring after herbicide application and evaluated for carryover effects. Fall tillage did not influence the carryover potential of these herbicides. However, herbicides injured several of the rotational crops. This injury was crop species and herbicide specific.

Existing long-term cotton experiments established in 1976 with minimum and intensive herbicide programs were subdivided in 1985 and 1986 to determine the longevity of fluometuron and trifluralin soil residues after discontinuing herbicide application. In monoculture cotton, seed cotton yield increased when herbicide use was discontinued in 1985 and 1986 after 9 and 10 yr of continuous use, respectively, on a Sharkey silty clay and a Dundee silt loam soil. Yield increases coincided with reductions of fluometuron and trifluralin soil residues. Fluometuron dissipated from the Dundee silt loam soil by 10 mo after the last application but was present in the Sharkey silty clay soil at 0.20 ppmw after 28 mo. Trifluralin did not totally dissipate from either soil, and low levels were present in the Dundee (0.05 ppmw) and Sharkey (0.13 ppmw) soils 30 mo after the last application. Visual injury to fall-seeded wheat and vetch decreased as herbicide residues dissipated. Fall tillage had no significant effect on the rate of fluometuron or trifluralin dissipation from either soil but reduced seed cotton yields.

Field studies were conducted to determine the effect of soil pH ranging from 5.1 to 7.1 on imazaquin persistence on a Grundy silty clay loam (2.8% OM). Imazaquin residues were equivalent at pH 5.5 or higher but persisted longer at pH 5.1. Corn shoot growth was not different at any soil pH. Corn grain yields in 1993 were lower in imazaquin-treated plots than in the check plots at the lowest pH (5.1), where initial imazaquin soil concentrations were between 10 and 13 μg/kg across all pH levels. Corn grain yields were not affected by herbicide carryover in 1994 where soil imazaquin residues were well below critical levels at planting. Yields were lower where soil pH was less than 5.5.

Growth chamber experiments were conducted to determine the effects of soil temperature on the response of corn to imazaquin soil residues. In a silt loam soil, 24/30 C (night/day) or 18/24 C soil temperatures caused greater inhibition of shoot growth than 12/18 C soil temperature. However, in a sandy loam soil, inhibition of corn shoot growth was maximal at 18/24 C, and there was no difference in shoot-growth inhibition between the lowest and highest temperatures. Higher soil temperatures caused greater root-growth inhibition in the sandy loam soil but not in silt loam soil. Soil temperature did not affect 14C-imazaquin uptake from either soil. Higher soil temperatures increased the translocation of imazaquin from root to shoot tissue in both soils. In the sandy loam soil, imazaquin metabolism in root tissue decreased as soil temperature increased, with twice as much parent herbicide recovered from roots of plants grown under the highest compared with the lowest temperature treatments. Soil temperature had no effect on imazaquin metabolism in shoot tissue. Longer-term experiments (22 d) were conducted with the sandy loam soil to determine the effect of changes in air temperature on corn response to imazaquin soil residues. Plants exposed to 24/30 C for 7 or 14 d of the final 14-d growing period showed greater inhibition of shoot growth compared with plants maintained at 12/18 C. Uptake and translocation of 14C-imazaquin to shoots was greater in plants maintained at 24/30 C throughout the final 14-d period than in plants maintained at 12/18 C. Plants grown for 7 d at 24/30 C during the final 14-d period either preceding or following 7 d growth at 12/18 C showed increased translocation of imazaquin to shoots but no difference in imazaquin uptake compared with plants maintained at 12/18 C. Neither air nor soil temperature treatments had any effect on imazaquin concentration in soil water.

The response of ‘C-20’ navy bean and ‘Frankenmuth’ soft white winter wheat grown in rotation to clomazone, imazethapyr, bentazon, and acifluorfen was examined. Clomazone at 560 and 430 g ai ha−1 plus 800 g ai ha−1 pendimethalin and 2000 g ai ha−1 chloramben visibly injured navy bean in 1 of 2 yr. However, navy bean seed moisture at harvest and yield was not reduced compared to the weed-free control. PPI and PRE treatments of 70 g ai ha−1 imazethapyr did not injure navy bean or reduce yield. Imazethapyr applied POST at 70 g ha−1 plus nonionic surfactant visibly injured navy bean. The addition of urea ammonium nitrate to imazethapyr enhanced visible injury and seed moisture compared to nonionic surfactant alone in 1 of 2 yr. However, seed yield was not reduced. Seed moisture at harvest was greater following treatment with 430 g ai ha−1 acifluorfen plus nonionic surfactant or urea ammonium nitrate and 140 and 280 g ha−1 acifluorfen plus 840 g ai ha−1 bentazon in 1 of 2 yr compared to the weed-free control, but yield was not reduced. Wheat yield was reduced in 2 of 2 and 1 of 2 yr by 560 g ha−1 and 430 g ha−1 clomazone, respectively, plus pendimethalin plus chloramben compared to the weed-free control. Wheat yield was not reduced by imazethapyr, bentazon, or acifluorfen.

Field studies on a sandy loam soil determined the influence of application method and rate and subsequent tillage on corn response to imazaquin and imazethapyr residues remaining in the soil. Imazaquin was applied preplant incorporated (PPI) and preemergence (PRE) at 70, 140, and 280 g ai/ha and postemergence (POST) at 70 and 140 g/ha. Imazethapyr was applied PPI and PRE at 70, 105, and 140 g ai/ha and POST at 70 and 105 g/ha. Subsequent tillage included fall moldboard plowing followed by spring field cultivation, fall chisel plowing followed by spring field cultivation, and no tillage. Herbicide dissipation was determined by analyzing soil cores taken in the spring at the time of corn planting and by measuring corn height and grain yield. Imidazolinone residues were detected in only 1 of 2 yr. Imazaquin was detected more frequently than imazethapyr. Imazaquin concentrations in the upper 10 cm of soil 11 mo after a PPI application of 280 g/ha were 5, 6, and 7 ng/g of soil in moldboard plow, chisel, and no-tillage systems, respectively. Imazaquin (5 ng/g) was also detected in the 10–18-cm soil depth in the moldboard plow system. Corn height and grain yield were not reduced from imazaquin or imazethapyr, regardless of application method or rate in any tillage system.

Herbicides can persist in the soil and injure sensitive crops planted in the years following herbicide application. The response of sugarbeet to clomazone, imazaquin, imazethapyr, and chlorimuron residues in soil was examined. Clomazone at 1.1 or 2.2 kg ai ha-1 did not reduce yield of sugarbeet planted 1 or 2 yr after application. Imazaquin at 0.07 to 0.28 kg ai ha-1, and imazethapyr at 0.09 to 0.14 kg ai ha-1, can reduce yield of sugarbeet planted 1 yr after application. Imazaquin at 0.07 to 0.14 kg ha-1 caused 28 to 47% sugarbeet injury and imazethapyr at 0.09 kg ha-1 caused 54% injury 2 yr after application in soybean. A 25% yield loss occurred from the imazethapyr treatment. Sugarbeet injury 2 yr after application was greatest when sugarbeet also was planted the year following soybean. Chlorimuron at 0.02 to 0.08 kg ai ha-1 plus linuron at 0.4 to 0.9 kg ai ha-1 reduced yield of sugarbeet planted 1 yr after application when compared with linuron alone, regardless of soil pH. Visible sugarbeet injury of 38 to 66% was still evident from chlorimuron plus linuron treatments 2 yr after application. Sugarbeet should not be planted less than 25 mo following imazaquin, imazethapyr, or chlorimuron application.

The availability and persistence of imazaquin, imazethapyr, and clomazone were studied in a Cisne silt loam (1.3% organic matter) and a Drummer silty clay loam (5.8% organic matter). Availability of all three herbicides to bioassay species was greater in the Cisne soil than in the Drummer soil. Corn root growth was more sensitive to imazaquin and imazethapyr than corn shoot growth. Shoot and root growth of wheat was inhbited by similar clomazone concentrations. In field experiments conducted in 1984, 1985, and 1986, all three herbicides were more persistent in the Drummer silty clay loam than in the Cisne silt loam. Clomazone and imazethapyr were detected by liquid or gas chromatographic analysis in the Drummer soil 3 yr following application. Crop injury occurred 5 months after application of imazaquin and clomazone to the Drummer soil. In the Cisne soil, only imazethapyr caused crop injury 5 months after application. Herbicide residues found below 7.5 cm were greater in the Drummer soil than in the Cisne soil.