Indaziflam and oxadiazon are efficacious preemergence herbicides used in warm-season turfgrass because of their persistence and residual activity. It is beneficial to quantify effective concentrations for preemergence control of summer annual weeds and determine whether these concentrations are maintained throughout weed emergence periods. Therefore, greenhouse bioassays were conducted with barnyardgrass, broadleaf signalgrass, doveweed, large crabgrass, and purple nutsedge. Treatments included indaziflam at 0, 4, 8, 12, 17, 21, 25, 29, 33, and 37 g ai ha−1 or oxadiazon at 0, 420, 841, 1,260, 1,681, 2,102, 2,354, 2,942, 3,363, and 3,783 g ha−1. Although preemergence herbicides are not used to control perennial weeds, purple nutsedge was included to investigate the effect of selected herbicides on its growth. Herbicide EC50, EC80, and EC90 for seedling emergence inhibition and shoot and root mass reduction were quantified from log-logistic dose–response curves. Herbicide concentration that remains from a preemergence application during the regional species-specific periodicity of emergence was predicted using first-order kinetics equations. Indaziflam and oxadiazon controlled seedling emergence 14 d after treatment (DAT) in the evaluated annual weeds and shoot and root mass in all species 84 DAT. Indaziflam applied in mid-March at 33 g ha−1 may provide up to 90% seedling emergence inhibition in large crabgrass and signalgrass; up to 80% in barnyardgrass; and up to 50% in doveweed. Oxadiazon applied in mid-March at 3,363 g ha−1 may provide up to 80% seedling emergence inhibition in all species. Indaziflam and oxadiazon may control up to 80% shoot mass and up to 50% root mass, respectively, in purple nutsedge and 80% to 90% shoot or root mass in other species. Such information is useful in evaluating adequacy of herbicide management practices for season-long weed control, and it aids turfgrass managers in applying preemergence herbicides at optimal timing based on target weed species.

Prostrate water primrose is a troublesome weed in rice paddy fields. A study was conducted to determine the influence of environmental and agronomic factors on its emergence. The efficacy of herbicides on this species was also examined. The germination percentage of mature seeds remained above 90% within 180 d after harvest, indicating a low primary dormancy of this species. Light stimulated seed germination. Seeds buried deeper than 0.5 cm did not form seedlings. These results suggest that stale seedbed practices and deep tillage operations can mitigate the occurrence of this species in paddy fields. The optimum temperature for germination varied from 25/15 C to 35/25 C. The osmotic potential and salt concentration needed to inhibit 50% of maximum germination were −0.4 MPa and 197 mM, respectively. Seeds were tolerant to flooding and did not germinate at pH 8 to 10. The preemergence herbicides oxadiazon, oxadiargyl, and butachlor had excellent control efficacy on prostrate water primrose, with a 95.4% to 100% reduction in seedling number and a 99.2% to 100% reduction in biomass, respectively. The postemergence herbicides MCPA-Na + bentazone, bentazone, MCPA-Na, and fluroxypyr applied at the 2- to 3-leaf stage of prostrate water primrose provided a 90.6% to 100% reduction in seedling number and a 99.3% to 100% reduction in biomass. The results of this study can help in developing sustainable and effective integrated weed management strategies for controlling prostrate water primrose in paddy fields.

This study was undertaken to investigate the integration effects of pretilachlor, oxadiazon, and dimethenamid with or without glyphosate in a stale seedbed method to control weedy rice in wet-seeded rice. The study, conducted in 2018 and 2019, comprised two seedbed treatments in main plots, with and without glyphosate (850 g ae ha−1), and four subplot treatments: pretilachlor, oxadiazon, dimethenamid, and unsprayed check. Fifteen days after glyphosate spray, each subplot was treated with preemergence herbicides at 500 g ai ha−1 under standing water conditions (2 to 3 in.), and the water level was maintained for 7 d. Pregerminated rice seeds (var. MR297) were hand-broadcasted in the moist soil at 120 kg ha−1 seeding rate. In 2019, the density and dry weight of weedy rice were 30% and 118% higher Gthan those observed in 2018, respectively. A stale seedbed with glyphosate reduced weedy rice dry weight by 12% as compared to what was observed in a stale seedbed without glyphosate. Addition of oxadiazon and pretilachlor to the stale seedbed drastically reduced weedy rice dry weight by 70% to 88% and 53% to 60% in both years. Dimethenamid contributed to a significant reduction of weedy rice dry weight of 19% in 2019 only but failed to provide a positive economic return. Integration of pretilachlor and oxadiazon in a stale seedbed with glyphosate gave profitable returns of $84.00 to 311.4 ha−1 and $175.70 to 483.8 ha−1, respectively. Without the presence of glyphosate, pretilachlor and oxadiazon contributed a positive return of $318.90 and $469.40, respectively, in 2018, but the economic returns were negative in 2019. These results suggest that integration of pretilachlor or oxadiazon in a stale seedbed with glyphosate is more crucial when weedy rice infestation is high, but glyphosate can be excluded from the management regime when the weedy rice populations are low.

Resistance to penoxsulam among barnyardgrass populations is prevalent in rice fields in China. Seeds of penoxsulam-resistant (AXXZ-2) and penoxsulam-susceptible (JLGY-3) barnyardgrass populations, as well as the seeds of two rice varieties, including Wuyungeng32 (WY) and Liangyou669 (LY), were planted in plastic pots and then treated with a rate titration of acetochlor, anilofos, butachlor, clomazone, oxadiazon, pendimethalin, pretilachlor, pyraclonil, or thiobencarb. The two barnyardgrass populations exhibited similar susceptibility to acetochlor, anilofos, butachlor, oxadiazon, pretilachlor, or pyraclonil. However, the susceptibility differed between the barnyardgrass populations in response to clomazone, pendimethalin, and thiobencarb. For AXXZ-2, herbicide rates that caused 50% reduction in shoot biomass from the nontreated control (GR50) were 179, >800, and 1,798 g ha−1 for clomazone, pendimethalin, and thiobencarb, respectively; whereas JLGY-3 GR50 values were 61, 166, and 552 g ha−1, respectively. Both rice varieties demonstrated excellent tolerance to acetochlor, butachlor, oxadiazon, pretilachlor, and thiobencarb. However, substantial rice damage was observed when anilofos and clomazone were used. Anilofos at 352 g ha−1 and clomazone at 448 g ha−1 reduced rice shoot biomass by 41% and 50% from the nontreated, respectively. Averaged across herbicide rates, clomazone use resulted in a reduction in rice shoot biomass from that of the nontreated control by 52% and 34% for WY and LY, respectively; and pendimethalin use resulted in a reduction in rice shoot biomass from the nontreated control by 25% and 9% for WY and LY, respectively.

Weeds are among the main limitations on chickpea production in Iran. The efficacy of herbicide treatments including linuron PPI, imazethapyr PPI, PRE, and POST, pendimethalin PPI and POST, bentazon POST, pyridate POST, and oxadiazon POST along with one or two hand weedings were evaluated for weed control and yield response in rain-fed chickpea in Aleshtar, Lorestan, Iran in 2015 and 2016. Wild safflower, threehorn bedstraw, wild mustard, and hoary cress were the predominant weed species in both experimental years. Total weed dry biomass in weedy check plots averaged 187 and 238 g m−2 in 2015 and 2016, respectively, and weed density and biomass were reduced in all treatments compared to the weedy check in both years. Treatments composed of pyridate followed by one hand weeding or imazethapyr POST followed by two hand weedings resulted in the lowest weed biomass. The presence of weeds reduced yield by 74% and 66% in the weedy check plots compared to the weed-free control plots in 2015 and 2016, respectively. Application of oxadiazon, bentazon, and imazethapyr PPI, PRE, and POST resulted in lower chickpea yields. All herbicides tested injured chickpea slightly, with pyridate causing the least injury.

Goosegrass biotypes from golf courses in Richmond, VA (CCV) and New Bern, NC (RB) historically treated with oxadiazon were identified as resistant compared to susceptible standard (PBU) based on comparisons of oxadiazon applied preemergence at increasing rates (0.03 to 2.24 kg ha-1). Oxadiazon at rates ≤ 2.24 kg ha-1 rate did not prevent emergence of suspected resistant CCV and RB seedlings. PBU emergence was completely prevented at 0.14 kg ha-1. Based on percent seedling emergence relative to non-treated and percent above-ground biomass reduction relative to non-treated, the oxadiazon rate at which emergence would be reduced 50% (I50) or 90% (I90) ranged from 0.12 to 0.18 kg ha-1 or 10.83 to 85.57 kg ha-1, respectively for suspected resistant CCV and RB, compared to 0.03 to 0.4 kg ha-1 or 0.12 to 0.19 kg ha-1, respectively for susceptible standard PBU. Seedling emergence data predicted 7.9 and 3.0 times greater I90 values for CCV and RB, respectively compared to biomass data. All three biotypes were completely controlled by preemergence applied labeled rates of prodiamine and indaziflam. This is the first peer-reviewed report of evolved weed resistance to oxadiazon.

In field experiments, preemergence applications of bensulide {O,O-bis(1-methylethyl)S-[2-[(phenylsulfonyl)amino] ethyl] phosphorodithioate} or DCPA (dimethyl-2,3,5,6-tetrachloro-1,4-benzenedicarboxylate) at 11.2 kg ai/ha controlled smooth crabgrass [Digitaria ischaemum (Schreb. ex Schweig.)Schreb. ex Muhl. #3 DIGIS] selectively in turf. Granular and liquid formulations of bensulide performed similarly. Napropamide [N,N-diethyl-2-(1-naphthalenyloxy)propanamide] granules when applied alone at 1.1 to 3.4 kg ai/ha were partially effective, but when combined with 5.6 kg ai/ha bensulide, controlled smooth crabgrass for the entire season. Oxadiazon {3-[2,4-dichloro-5-(1-methylethoxy)phenyl]-5-(1,1-dimethylethyl)-1,3,4-oxadiazol-2-(3H)-one} controlled crabgrass but temporarily injured the turf. Residual control of crabgrass the year after treatment was unacceptable for all treatments.

A 3-yr study investigated highbush blackberry control in bahiagrass turf using selective herbicides. Triclopyr applied alone at ≤ 0.56 kg/ha and in combination with other herbicides provided best (75 to 95%) control for up to 52 wk after treatment with minimal damage to bahiagrass turf. Triclopyr formulations (3A vs 4EC) provided similar highbush blackberry control and bahiagrass tolerance. The addition of either 2,4-D, dicamba, hexazinone, or sulfometuron to triclopyr provided slightly better blackberry control, but increased bahiagrass turf damage. Fluroxypyr applied at 0.14 to 0.28 kg/ha provided 60 to 80% control of highbush blackberry 12 WAT. Glyphosate and glufosinate treatments provided unacceptable highbush blackberry control and/or unacceptable bahiagrass turf injury. The addition of oxadiazon for residual control of subsequent highbush blackberry emergence was ineffective.

Annual bluegrass (Poa annua L.) growing in bermudagrass completes its life cycle in May and dies leaving open spaces in the turfgrass. This occurs at a time when summer annual weeds are germinating and these weeds fill the space formerly occupied by the annual bluegrass. As the summer annual weeds die in the fall, annual bluegrass germinates and fills the space formerly occupied by the summer annual weeds. To control annual bluegrass, it is important to control the summer annual grasses and manage the bermudagrass [Cynodon dactylon (L.) Pers.] to maintain a competitive groundcover especially during the peak germination period for the weeds. Herbicide programs over a three-year period were designed to control annual grasses with treatments in April for large crabgrass [Digitaria sanguinalis (L.) Scop.], in May or June for goosegrass [Eleusine indica (L.) Gaertn.] and in late August for annual bluegrass. Oxadiazon [2-tert-butyl-4-(2,4-dichloro-5-isopropoxyphenyl)-δ2-1,3,4-ozadiazolin-5-one] applied in August gave complete control of annual bluegrass. Although oxadiazon has a long residual life in the soil, annual bluegrass was poorly controlled with treatments made in June. Fall (August or September) applications of benefin [N-butyl-N-ethyl-α,α,α-trifluoro-2,6-dinitro-p-toluidine], prosulfalin N-[[4-(dipropylamino)-3,5-dinitrophenyl] sulfonyl]-S,S-dimethylsulfilimine and butralin [4-(1,1-dimethylethyl-N-(1-methylpropyl)-2,6-dinitrobenzenamine] provided adequate control of annual bluegrass with only a few exceptions during the three-year period. Bensulide [O,O-diisopropyl phosphorodithioate S-ester with N-(2-mercaptoethyl)benzenesulfonamide] gave variable control of annual bluegrass; however, this was improved in programs with oxadiazon which provide goosegrass control during summer. In these studies, DCPA [dimethyl tetrachloroterephthalate], even with three applications a year, gave very little control of annual bluegrass. When oxadiazon was used in rotation with DCPA, adequate control was obtained.

Several commercial and experimental herbicides such as p-nitrodiphenyl ethers, oxadiazoles, and cyclic imides inhibit protoporphyrinogen IX oxidase (Protox), the enzyme that converts protoporphyrinogen IX to protoporphyrin IX (Proto). This leads to uncontrolled autooxidation of the substrate and results in accumulation of Proto. Blockage of the porphyrin pathway at this site inhibits synthesis of both chlorophylls and heme. Heme is a feedback regulator of the porphyrin pathway. Thus, inhibition of Protox also deregulates the pathway, causing increased carbon flow to the accumulating pool of Proto. Proto is a potent photosensitizer that generates high levels of singlet oxygen in the presence of molecular oxygen and light. In plants treated with these herbicides, damage is light dependent and closely correlated with the level of Proto that accumulates. Proto accumulation is apparently largely extraplastidic, resulting in rapid photodynamic damage to the plasmalemma and tonoplast. After high levels of Proto accumulate in response to these herbicides, protochlorophyllide (PChlide) levels can increase also; however, Proto appears to be the primary photodynamic pigment responsible for the herbicidal activity.

Oxadiazon [2-tert-butyl-4(2,4-dichloro-5-isopropoxyphenyl)-δ2-1,3,4-oxadiazolin-5-one] applied to dormant bermudagrass [Cynodon dactylon (L.) Pers. ‘Tifway’ ♯ CYNDA] retarded early foliar growth more than other herbicides evaluated. When bensulide [O,O-diisopropyl phosphorodithioate S-ester with N-(2-mercaptoethyl)benzenesulfonamide] treatments were delayed until after bermudagrass initiated spring growth, foliar growth and quality were generally lower than when the treatments were applied to dormant turf. Retardation of early foliar bermudagrass growth by 2,4-D [(2,4-dichlorophenoxy)acetic acid] + mecoprop {2-[(4-chloro-o-tolyl)oxy] propionic acid} + dicamba (3,6-dichloro-o-anisic acid) was generally the same whether applied to dormant or semidormant turf. This combination of herbicides reduced the quality and density of bermudagrass when applied to growing but not to dormant turf. Atrazine [2-chloro-4-(ethylamino)-6-(isopropylamino)-s-triazine] did not retard bermudagrass growth or affect density whether applied to dormant or semidormant turf, but turf quality was slightly lower when atrazine was applied to semidormant turf.

Factors affecting the germination and seedling growth of leafflower were evaluated. Germination required exposure to light. Seeds covered with a 1-cm deep layer of pine bark mulch failed to emerge. Maximum seedling development occurred in full exposure to sunlight; shading that reduced light intensity more than 26% was inhibitory. Maximum seed germination (79%) occurred between 25 and 35 C; temperatures outside this range were inhibitory. Germination was strongly influenced by osmotic potential. Osmotic potentials of 0, 304, and 507 kPa resulted in 85, 24 and 14% germination, respectively. PRE applications of either granular formulated oxadiazon at 4.5 kg ha–1, or premixed granular formulated oxyfluorfen + oryzalin at 4.6 + 2.3 kg ha–1, provided a minimum of 85% control. The following POST treatments provided a minimum of 90% control of mature plants: paraquat at 0.21 kg ha–1, glyphosate at 0.56 kg ha–1, oxyfluorfen at 1.12 kg ha–1, and acifluorfen at 2.24 kg ha–1.

Experiments were conducted in 1982, 1983, and 1984 to determine whether herbicides can effectively control weeds in annual statice (Limonium sinuatum Mill.) without reducing the marketability of the crop. A greenhouse evaluation of chlorpropham (1-methylethyl 3-chlorophenylcarbamate), napropamide [N,N-diethyl-2-(1-naphthalenyloxy)propanamide], EPTC (S-ethyl dipropyl carbamothioate), oxadiazon {3-[2,4-dichloro-5-(1-methylethoxy)phenyl]-5-(1,1-dimethylethyi)-1,3,4-oxadiazol-2-(3H)-one}, and trifluralin [2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzenamine] indicated that preemergence applications of the latter three herbicides resulted in the most effective weed control and least statice injury. Oxadiazon was the most effective for broadleaf and grass ed control in field-grown statice. Yield and quality were greatest in oxadiazon-treated plots and exceeded those of the handweeded controls. Annual statice was most sensitive to trifluralin.

Broadleaf weed control and tulip, daffodil, and iris response to alachlor, dithiopyr, diuron, isoxaben, napropamide, oryzalin, oxadiazon, oxyfluorfen, pendimethalin, pronamide, and thiazopyr applied preemergence were evaluated. All herbicides controlled broadleaf weeds for five months after application, but control with oxyfluorfen, pendimethalin, alachlor, pronamide, and napropamide decreased six months after application. The greatest weed control was with oxadiazon, isoxaben, thiazopyr, dithiopyr, and diuron, whereas the least weed control was with napropamide and alachlor. In general, tulip was more sensitive to herbicides than daffodil and iris. All herbicides injured tulips at early growth stages but bulb yield of tulip was reduced only by oxadiazon, oxyfluorfen at 0.28 kg ai/ha, pronamide, and dithiopyr. Tulip flower quality was reduced only by oxadiazon, oxyfluorfen at 0.28 lb/ha, and pronamide. Daffodil and iris were tolerant to thiazopyr, isoxaben, pronamide, alachlor, oryzalin, napropamide, and diuron.

Herbicides were applied annually in March or March plus August to bermudagrass [Cynodon dactylon (L.) Pers. Tifdwarf’] putting greens for 6 yr. Bensulide [O,O-diisopropyl phosphorodithioate S-ester with N-(2-mercaptoethyl)benzenesulfonamide] delayed early spring growth of bermudagrass less than the other herbicides, but did not adversely affect turf quality during the growing season. Oxadiazon [2-tert-butyl-4(2,4-dichloro-5-isopropoxyphenyl)-Δ2-1,3,4-oxadiazolin-5-one] treatments applied twice each year severely retarded turf growth and reduced the quality and stand of bermudagrass. Napropamide [2-(α-naphthoxy)-N, N-diethylpropionamide] and prosulfalin {N-[[4-dipropylamino)-3,5-dinitrophenyl] sulfonyl]-S,S-dimethylsulfilimine} treatments reduced root growth of bermudagrass.

The objective of this investigation was to determine if preemergence herbicides, applied at the standard rates and times for smooth crabgrass [Digitaria ischaemum (Schreb.) Muhl. ♯ DIGIS] control, would provide season-long control of goosegrass [Eleusine indica (L.) Gaertn. ♯ ELEIN] in the transition zone. The transition zone is a unique area of turfgrass culture between cool and warm regions where quality of turfgrasses frequently declines due to environmental stresses. Single and sequential applications of bensulide [O,O-diisopropyl phosphorodithioate S-ester with N-(2-mercaptoethyl)benzenesulfonamide] and DCPA (dimethyltetrachloroterephthalate) did not effectively control goosegrass in any of the three test years. Benefin (N-butyl-N-ethyl-α,α,α-trifluoro-2,6-dinitro-p-toluidine) usually required sequential dosages to provide good (90%) to excellent (95%) goosegrass control. Nearly all rates of oxadiazon [2-tert-butyl-4(2,4-dichloro-5-isopropoxyphenyl)-δ2-1,3,4-oxadiazolin-5-one] used provided good to excellent goosegrass control. Napropamide [2-(α-naphthoxy)-N,N-diethylpropionamide] plus bensulide provided excellent goosegrass control in 1981, but not in 1982. Pendimethalin [N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzenamine] also provided effective goosegrass control.

Green kyllinga is a relatively new weed species in well-irrigated turfs in the southwest US. To understand the germination requirements of green kyllinga, the effects of planting depth, temperature, pH, and osmotic potential were determined. Green kyllinga emergence was sensitive to planting depth. At 21 days after planting (DAP), emergence of green kyllinga was 60% when planted at the soil surface but only 20% at 0.5 cm and less than 5% at 1 cm. Germination occurred at temperatures between 17 and 30 C but was notably better between 20 and 24 C. Germination was uniform from pH 5.5 to 9.5. Germination decreased between the water potentials −0.1 to −0.6 MPa, although germination was high at water potentials found in irrigated turf. The environmental conditions found in nonstressed turf areas in Arizona will likely support the establishment of green kyllinga. The efficacy of herbicides for the control of green kyllinga was also determined. Control of kyllinga (95% or greater) was obtained with preemergence applications of oxadiazon, dithiopyr, and metolachlor, and with postemergence applications of DSMA, halosulfuron-methyl, and imazaquin.

Control of goosegrass and large crabgrass with different preemergence herbicides for the initial and sequential application was studied at four locations in Indiana. Pendimethalin at 1.1 kg ai ha-1 was used as the initial application in all treatments. Sequential treatments applied 6 wk after the initial treatment consisted of: 2.2 kg ha-1 benefin; 1.4/0.7 kg ha-1 benefin/trifluralin; 8.4 kg ha-1 bensulide; 11.8 kg ha-1 DCPA; 0.6 kg ha-1 dithiopyr; 2.2 kg ha-1 oxadiazon; 1.1 kg ha-1 pendimethalin; or 0.6 kg ha-1 prodiamine. Dithiopyr at 0.6 kg ha-1 with no initial application was also included. Highest large crabgrass control ratings were obtained through September with pendimethalin + pendimethalin, pendimethalin + dithiopyr, and dithiopyr alone postemergence. All other sequential applications tested improved control over a single application of 1.1 kg ha-1 pendimethalin, but rarely gave adequate season long control.

Several herbicides were sprayed on emerged London rocket (Sisymbrium irio L.), common sunflower (Helianthus annuus L.), ragweed parthenium (Parthenium hysterophorus L.), annual sowthistle (Sonchus oleraceus L.), and onion (Allium cepa L. ‘yellow granex PRR’), to determine selectivity. Onion yields were reduced with common sunflower and London rocket interference within 7 weeks after emergence. Oxadiazon [2-tert-butyl-4-(2,4-dichloro-5-isopropoxyphenyl)-δ2-1,3,4-oxadiazolin-5-one] at 2.2 kg/ha controlled all but common sunflower under most field conditions and reduced the yield of onion in one experiment out of six. Methazole [2-(3,4-dichlorophenyl)-4-methyl-1,2,4-oxadiazolidine-3,5-dione] and bromoxynil (3,5-dibromo-4-hydroxybenzonitrile) reduced the yields of onion in two of four experiments and three of six experiments, respectively. Both herbicides controlled most weed species, but only bromoxynil controlled annual sunflower adequately. Onion was injured when low temperature, low light intensity, and high relative humidity occurred within 3 days of the application of herbicides. Bioassays showed that oxadiazon persisted 5 months in soil in three of five experiments. Seeded London rocket populations reduced the growth of onion 20% within the first 4 weeks and 65% within 12 weeks after planting.

The influence of PRE herbicides on rooting characteristics of bermudagrass turfgrass was studied using sod plugs removed from the field. Greenhouse root fresh weight was reduced the greatest with dithiopyr or prodiamine. Pendimethalin caused fewer fresh weight reductions compared to dithiopyr or prodiamine and these reductions were usually for a short period. Root weight loss was due to lower root density and root malformation. Significant numbers of malformed roots were also observed for greater periods of time where dithiopyr or prodiamine had been applied.