The Assynt Culmination of the Moine Thrust Belt, in the northwest Scottish Highlands, contains a variety of Caledonian alkaline and calc-alkaline intrusions that are mostly of Silurian age. These include a significant but little-studied suite of dykes and sills, the Northwest Highlands Minor Intrusion Suite. We describe the structural relationships of these minor intrusions and suggest a classification into seven swarms. The majority of the minor intrusions can be shown to pre-date movement in the Moine Thrust Belt, but some appear to have been intruded during the period of thrusting. A complex history of magmatism is thus recorded within this part of the Moine Thrust Belt. New geochemical data provide evidence of a subduction-related component in the mantle source of the minor intrusions.

Sedimentary basins developed along the European margin during the earliest, Permian, stage of proto-Atlantic rifting, during a phase of high heat flow. The proximity of some basins to Caledonian thrusts has implied that rifts locally utilized the basement fabric. New mineralogical and palaeomagnetic data show that thrust planes in the Moine Thrust Zone channelled a pulse of hot fluid in Permian time. The fluids precipitated kaolin in fractures in the thrust zone, and with decreasing intensity away from the zone. The high-temperature polytype dickite is largely confined to major thrust planes. Stable H and O isotope analyses indicate that the parent fluid included meteoric water involved in a hydrothermal system. Coeval hydrothermal hematite has a chemical remanence that dates the fluid pulse as Permian. This is direct evidence for post-orogenic activity in the thrust zone, in which the thrusts vented excess heat during regional crustal extension. The example from the European margin exemplifies the importance of deep-seated structures in the release of heat, and the value of kaolinite polytype mapping as a tool to record anomalous palaeo-heat flow.

A structural reinterpretation of Appin Group metasediments of the Dalradian Supergroup in part of the northwestern marginal zone of the Irish Caledonides is presented. No major F1 folds have been recorded although bedding occasionally faces upwards NW in S1. The structure is dominated by a series of NW-facing F2 recumbent folds and associated D2 tectonic slides. The slides, which have thrust the overlying rocks to the NW, are generally oblique to the fold axial planes and commonly cut out major F2 fold hinges. Rotation of the hinges towards the NW-SE (Caledonian) stretching direction in areas adjacent to the slides may have contributed to fold excision: an example of a major dislocated sheath fold is described. DM3 produces major SE-verging inclined folds. Although D4, D5 and D6 are of minor importance in the area D6 intensifies towards the SE to become the principal fabric in a major NE–SW-trending sinistrai shear zone that contains the c. 400 Ma Main Donegal granite. The early major structures of this area are compared with those in Dalradian Supergroup of adjacent parts of Scotland. It is suggested that the absence of a major F1 fold (analagous to the Islay anticline) and the occurrence of D2 recumbent folds and low angle thrusts in NW Ireland reflect the close proximity of the foreland, composed of the Lewisian complex, to the NW; such a situation is analagous to the Moine thrust zone in Scotland. The progressive development of low angle structures and thrusts to the W of the Scottish mainland is attributed to a westward shallowing of the Lewisian basement between the SW Highlands of Scotland and NW Ireland.