The lithium sodium borosilicate jadarite, LiNaSiB3O7(OH), was first identified in 2007 in the Jadar basin, Serbia, where it forms the principal ore mineral of one of Europe's largest Li deposits. We report the successful application of the dry-gel conversion technique (DGC) to synthesise a jadarite analogue, via a dry-gel precursor made using sol-gel synthesis and the inclusion of the structure directing agent tetraethylammonium hydroxide (TEAOH). Pawley refinement of powder X-ray diffraction (PXRD) data collected on the synthetic sample was carried out using a monoclinic unit cell in space group P21/c (Whitfield et al., 2007), and gave refined unit cell parameters of a = 6.824(3) Å, b = 13.882(5) Å, c = 7.735(3) Å and β = 124.37(1)° (Rwp = 9.22). Inductively-coupled plasma optical emission spectroscopy (ICP–OES) on the synthetic sample confirmed an empirical formula of Li1.07Na1.40Si0.79B3O7.32(OH), based on three B atoms per formula unit (apfu). The synthetic product was found to be deficient in Si compared to natural jadarite from analysis of PXRD and ICP–OES data. Fourier-transform infrared spectroscopy (FTIR) showed that synthetic jadarite has peaks at 1415 and 1342 cm–1 and between 1180 and 900 cm–1, which are attributed to the presence of trigonal (BO3) and tetrahedral (BO4) borate groups characteristic of the natural jadarite structure, as well as a broad peak at 3441 cm–1 due to the presence of residual TEAOH. Scanning electron microscopy showed similarities in the morphologies between synthetic and natural jadarite particles.