Radial diffusion experiments have been carried out to assess the migration of 36Cl, as chloride, through a cementitious backfill material. Further experiments in the presence of cellulose degradation products were performed to assess the effect of organic ligands on the extent and rate of chloride diffusion. Results show that breakthrough of 36Cl is dependent on chloride concentration: as the carrier concentration increases, both breakthrough time and the quantity retained by the cement matrix decreases. Experiments in the presence of cellulose degradation products also show a decrease in time to initial breakthrough. However, uptake at various carrier concentrations in the presence of organic ligands converges at 45% of the initial concentration as equilibrium is reached. The results are consistent with organic ligands blocking sites on the cement that would otherwise be available for chloride binding, though further work is required to confirm that this is the case. Post-experimental digital autoradiographs of the cement cylinders, and elemental mapping showed evidence of increased 36Cl activity associated with black ash-like particles in the matrix, believed to correspond to partially hydrated glassy calcium-silicate-sulfate-rich clinker.

Thirty-two cosmogenic 36Cl surface exposure ages constrain the timing of two late Pleistocene glacial advances in the western Ahklun Mountains, southwestern Alaska. Boulders were sampled from one early Wisconsin (sensu lato) and six late Wisconsin moraines deposited by ice-cap outlet glaciers and local alpine glaciers. Four moraine boulders deposited during an extensive early Wisconsin ice-cap outlet glacier advance have a mean surface exposure age of 60,300±3200 yr. A moraine deposited by an ice-cap outlet glacier during the restricted late Wisconsin advance has a mean surface exposure age of 19,600±1400 yr. Five moraines deposited by late Wisconsin alpine glaciers have mean ages that range between 30,000 and 17,000 yr. The 36Cl ages are consistent with limiting 14C and thermoluminescence ages from related deposits and indicate that Ahklun Mountains glaciers reached their most extensive position of the last glaciation early during the late Pleistocene, in contrast to the deep-sea isotopic record of global ice volume.1