Boreholes penetrating the inverted limb of a major fold in an allochthonous thrust sheet at Chillaton, West Devon, revealed highly fossiliferous strata spanning the Devonian–Carboniferous boundary in continuous succession. Details of the fauna, which includes conodonts, trilobites and ostracods, are given. Abundant siphonodellid conodonts allow the boundary to be determined according to the recommendations of the working group on the Devonian–Carboniferous boundary of the IUGS Commission on Stratigraphy. The nature of the imbricate zone beneath the Main Thrust, in which the succession is situated, is described. In addition, the fabrics associated with thrusts which cut the olistostromic succession lower in the tectonic unit are discussed.