Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-28T01:08:38.274Z Has data issue: false hasContentIssue false
  • English
  • Français

Chlorsulfuron Adsorption and Degradation in Soil

Published online by Cambridge University Press:  12 June 2017

Kausalya Thirunarayanan ,
Robert L. Zimdahl  and
Darryl E. Smika
Kausalya Thirunarayanan
Affiliation:
Weed Res. Lab., Dep. Plant Pathol. and Weed Sci., Colorado State Univ., Ft. Collins, CO 80523
Robert L. Zimdahl
Affiliation:
Weed Res. Lab., Dep. Plant Pathol. and Weed Sci., Colorado State Univ., Ft. Collins, CO 80523
Darryl E. Smika
Affiliation:
Cent. Great Plains Res. Stn., Akron, CO 80720
Get access Rights & Permissions [Opens in a new window]

Abstract

Adsorption of chlorsulfuron {2-chloro-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl) amino] carbonyl] benzenesulfonamide} on four soils having different pH values (6.2 to 8.1) was low. Log/log Freundlich isotherms for all soils at 8 and 30 C were linear, the extent of adsorption being greater at 8 than at 30 C. There was an inverse relationship between pH and degradation rate with a half-life of 88.5 days at pH 6.2 and 144 days at pH 8.1 at 20 C. Rapid disappearance was noted during the first 15 days after application. With decreasing moisture and temperature, chlorsulfuron degraded more slowly. The half-life ranged from 229 days at 10 C and moisture content of 75% field capacity to 62.5 days at 40 C and 75% field capacity at pH 7.7.

Keywords

Soil moisturesoil temperaturesoil pH
Type
Soil, Air, and Water
Information
Weed Science , Volume 33 , Issue 4 , July 1985 , pp. 558 - 563
Copyright
Copyright © 1985 by the Weed Science Society of America 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Literature Cited

1. Cheng, H. H. 1971. Picloram in soil: extraction and mechanism of adsorption. Bull. Environ. Contam. Toxicol. 6:28–33.CrossRefGoogle ScholarPubMed
2. Corbin, F. T. and Upchurch, R. P. 1967. Influence of pH on detoxication of herbicides in soil. Weeds 15:370–377.Google Scholar
3. Corbin, F. T., Upchurch, R. P., and Selman, F. L. 1971. Influence of pH on the phytotoxicity of herbicides in soil. Weed Sci. 19: 233–239.Google Scholar
4. Farmer, W. J. and Aochi, Y. 1974. Picloram sorption by soils. Soil Sci. Soc. Am. Proc. 38:418–423.Google Scholar
5. Grover, R. 1968. Influence of soil properties on phytotoxicity of 4-amino-3,5,6-trichloropicolinic acid (picloram). Weed Res. 8:227–232.Google Scholar
6. Grover, R. 1971. Adsorption of picloram by soil colloids and various other adsorbents. Weed Sci. 19:417–418.CrossRefGoogle Scholar
7. Hamaker, J. W. 1972. Decomposition: quantitative aspects. Pages 255–340 in Goring, C.A.I. and Hamaker, J. W., eds. Organic Chemicals in the Soil Environment. Marcel Dekker, Inc., New York.Google Scholar
8. Hamaker, J. W. and Goring, C.A.I. 1976. Turnover of pesticide residues in soil. Pages 219–243 in Kaufman, D. D., Still, G. G., Paulson, G. D., and Bandal, S. K., eds. Bound and Conjugated Pesticide Residues. ACS Am. Chem. Soc., Symp. Ser. 29. Washington, DC.Google Scholar
9. Hamaker, J. W., Goring, C.A.I., and Youngson, C. R. 1966. Sorption and leaching of 4-amino-3,5,6-trichloropicolinic acid in soils. Pages 23–27 in Gould, R. F., ed. Organic Pesticides in the Environment. Advances in Chemistry Series No. 60. Am. Chem. Soc., Washington, DC.Google Scholar
10. Hance, R. J. 1965. The adsorption of urea and some of its derivatives by a variety of soils. Weed Res. 5:108–114.CrossRefGoogle Scholar
11. Harvey, R. G. 1974. Soil adsorption and volatility of dinitroaniline herbicides. Weed Sci. 22:120–124.Google Scholar
12. Hayes, M.H.B., Stacey, M., and Thompson, J. M. 1968. Adsorption of s-triazine herbicides by soil organic matter preparations. Pages 75–90 in Isotopes and Radiation in Soil Organic Matter Studies. International Atomic Energy Agency, Vienna.Google Scholar
13. Henson, M. A. and Zimdahl, R. L. 1983. Residual effect of chlorsulfuron on Canada thistle [Cirsium arvense (L.) Scop.] and five crops. Weed Sci. Soc. Am. Abstr. Pages 87–88.Google Scholar
14. Hurle, K. and Walker, A. 1980. Persistence and its prediction. Pages 83–120 in Hance, R. J., ed. Interactions Between Herbicides and the Soil. Academic Press, New York.Google Scholar
15. Hyzak, D. L. and Zimdahl, R. L. 1974. Rate of degradation of metribuzin and two analogs in soil. Weed Sci. 22:75–79.Google Scholar
16. Jenkinson, D. S. and Powlson, D. S. 1976. The effects of biocidal treatments on metabolism in soil – V. A. method for measuring soil biomass. Soil Biol. Biochem. 8:209–213.Google Scholar
17. Joshi, M. M., Brown, H. M., and Romesser, J. A. 1984. Degradation of chlorsulfuron by soil microbes. Proc. West. Soc. Weed Sci. 37:63.Google Scholar
18. Kleinbaum, D. G. and Kupper, L. L. 1982. Applied Regression Analysis and Other Multivariate Methods. Duxbury Press, Massachusetts. 101 pp.Google Scholar
19. Levitt, G., Ploeg, H. L., Weigel, R. C. Jr., and Fitzgerald, D. J. 1981. 2-chloro-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl) aminocarbonyl)-benzenesulfonamide, a new herbicide. J. Agr. Food Chem. 29:416–418.Google Scholar
20. Lode, O. and Skuterud, R. 1983. EPTC persistence and phytotoxicity influenced by pH and manure. Weed Res. 23:19–25.Google Scholar
21. Palm, H. L., Riggleman, J. D., and Allison, D. A. 1980. Worldwide review of the new cereal herbicide – DPX 4189. Proc. Br. Crop. Prot. Conf. – Weeds. Pages 1–14.Google Scholar
22. Poku, J. A. and Zimdahl, R. L. 1980. Soil persistence of dinitramine. Weed Sci. 28:650–654.Google Scholar
23. Sethi, R. K. and Chopra, S. L. 1975. Adsorption, degradation and leaching of alachlor in some soils. J. Ind. Soc. Soil Sci. 23: 184–194.Google Scholar
24. Shea, P. J. 1982. Soil adsorption characteristics of chlorsulfuron. Proc. North Cent. Weed Control Conf. 37:54.Google Scholar
25. Smith, A. E. and Fitzpatrick, A. 1970. The loss of five thiocarbamate herbicides in nonsterile soils and their stability in acidic and basic solutions. J. Agr. Food Chem. 18:720–722.CrossRefGoogle Scholar
26. Snedecor, G. W. and Cochran, W. G. 1978. Statistical Methods. Iowa State University Press, Ames, IA. 324 pp.Google Scholar
27. Stevenson, I. L. 1956. Some observations on the microbial activity in remoistened air-dried soils. Plant Soil 8:170–182.Google Scholar
28. Talbert, R. E. and Fletchall, O. H. 1965. The adsorption of some s-triazines in soils. Weeds 13:46–52.Google Scholar
29. Walker, A. 1978. Simulation of the persistence of eight soil applied herbicides. Weed Res. 18:305–313.CrossRefGoogle Scholar
30. Walker, A. and Brown, P. A. 1983. Measurement and prediction of chlorsulfuron persistence in soil. Bull. Environ. Contam. Toxicol. 30:365–372.CrossRefGoogle ScholarPubMed
31. Zahnow, E. W. 1982. Analysis of the herbicide chlorsulfuron in soil by liquid chromatography. J. Agr. Food Chem. 30:854–857.Google Scholar
32. Zimdahl, R. L. and Fithian, W. A. 1984. Chlorsulfuron soil persistence. West Soc. of Weed Sci. Res. Prog. Rpt.: 278–281.Google Scholar
33. Zimdahl, R. L., Freed, V. H., Montgomery, M. L., and Furtik, W. R. 1970. The degradation of triazine and uracil herbicides in soil. Weed Res. 10:18–26.Google Scholar
34. Zimdahl, R. L. and Gwynn, S. M. 1977. Soil degradation of three dinitroanilines. Weed Sci. 25:247–251.CrossRefGoogle Scholar