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Molecular Self-Assembly of Fe3O4/Polyimide Nanocomposite Films (I)

Published online by Cambridge University Press:  10 February 2011

Yanjing Liu
Affiliation:
Fiber & Electro-Optics Research Center, Bradley Department of Electrical Engineering Virginia Polytechnic, Institute and State University, Blacksburg, VA 24061–0356, [email protected]
Anbo Wang
Affiliation:
Fiber & Electro-Optics Research Center, Bradley Department of Electrical Engineering Virginia Polytechnic, Institute and State University, Blacksburg, VA 24061–0356, [email protected]
Richard O. Claus
Affiliation:
Fiber & Electro-Optics Research Center, Bradley Department of Electrical Engineering Virginia Polytechnic, Institute and State University, Blacksburg, VA 24061–0356, [email protected]
Eric Jiang
Affiliation:
Bio-Rad, Digilab Division, 237 Putnam Avenue, Cambridge, MA 02139
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Abstract

Layer-by-layer molecular self-assembly of nanosized magnetite (Fe3O4) particles and polyimide precursor molecules into multilayer ultrathin films has been accomplished on single crystal silicon and quartz substrates. This process involves the alternate dipping of a substrate into an aqueous solution of cationic polymer which coats on nanoscale Fe3O4 particles as a stabilizer followed by dipping into an aqueous solution of anionie polyimide precursor (polyamic acid salt, PAATEA). The growth process and the structure have been characterized using UV-vis spectroscopy, FT-IR, and scanning electron microscopy. The results demonstrate that well-ordered uniform monolayer and multilayer magnetic films have been formed on silicon and silica surfaces.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1. Anton, I. et al., J. Magn. Magn. Mater. 111, 29 (1990).Google Scholar
2. Camras, M., Magnetic Recording Handbook, Van Nostrand Reinhold Company, New York, 1988;Google Scholar
Bertram, H. N., Theory of Magnetic Recording, Cambridge Univ. Press, 1994.Google Scholar
3. Pankhurst, Q. A. and Pollard, R. J., J. Phys. : Condens. Matter 5, 8487 (1993).Google Scholar
4. Kryder, M. H., in Applied Magnetism, edited by Gerber, R., Wright, C. D. and Asti, G., Kluwer Academic Publishers, 1993, vol. 253, p. 39.Google Scholar
5. Gerber, R., in Applied Magnetism, edited by Gerber, R., Wright, C. D. and Asti, G., Kluwer Academic Publishers, 1993, vol. 253, p. 165.Google Scholar
6. Falicov, L. M. et al, J. Mater. Res. 5, 1299 (1990).Google Scholar
7. Prinz, Gary A., in Sci. and Tech.of Nanostructured Magnetic Materials, edited by Hadjipanayis, G. C. and Prinz, G. A., Plenum Press, New York and London, 1991, p. 41.Google Scholar
8. Glavee, G. N., Eason, K., Klabunde, K. J., Sorensen, C. M. and Hadjipanayis, G. C, Chem. Mater. 4, 1360 (1992).Google Scholar
9. Phyne, J. J., Erwin, R. W., Borchers, J. A., Salamon, M. B., Tsui, F., Du, R., and Flynn, C. P., in Sci. and Tech.of Nanostructured Magnetic Materials, edited by Hadjipanayis, G. C and Prinz, G. A., Eds. Plenum Press, New York and London, 1991, p. 117.Google Scholar
10. Rhyne, J. J., Erwin, R. W., Borchers, J. A., Salamon, M. B., Tsui, F., Du, R. and Flynn, C. P., in Sci. and Tech.of Nanostructured Magnetic Materials, edited by Hadjipanayis, G C and Prinz, G. A., Plenum Press, New York, 1991, p. 117;Google Scholar
Engel, B. N., England, C. D., Nakada, M., Leeuwen, R. V. and Falco, C. M., in Sci. and Tech.of Nanostructured Magnetic Materials, edited by Hadjipanayis, G C and Prinz, G. A., Plenum Press, New York, 1991, p. 181.Google Scholar
11. Liu, Y. and Claus, R., in preparation.Google Scholar
12. Massart, R., IEEE Tram. Magn. 17, 1247 (1981).Google Scholar
13. Hadjipanayis, G. C, Gangopadhyay, S., Sorensen, C. M., and Klabunde, K. J., IEEE Trans. Magn. 29, 2602 (1993).Google Scholar
14. Decher, G., Hong, J. D. and Schmitt, J., Thin Solid Films 210/211, 831 (1992);Google Scholar
15. Salisbury, J. W., Walter, L. S., Vergo, N., and D'Aria, D. M., Infrared Spectra of Minerals, The Johns Hopkins Press Ltd., London, 1992, p. 144.Google Scholar