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Investigations of Bonding in Skutterudites by Electron Energy-Loss Spectroscopy
Published online by Cambridge University Press: 01 February 2011
Abstract
The local electronic structure of phosphorus in the binary skutterudites CoP3 and NiP3, and in the filled skutterudite LaFe4P12 are studied using a combination of electron energy-loss spectroscopy and ab initio calculations. Relative to CoP3 we observe a filling of phosphorus s and d states in NiP3, while for LaFe4P12 increased EELS intensity indicates more empty s and d states close to the Fermi-level.
- Type
- Research Article
- Information
- MRS Online Proceedings Library (OPL) , Volume 1044: Symposium U – Thermoelectric Power Generation , 2007 , 1044-U06-22
- Copyright
- Copyright © Materials Research Society 2008