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Effective electrochemical n-type doping of ZnO thin films for photovoltaic window applications
Published online by Cambridge University Press: 24 September 2013
Abstract
An effective n-type doping of ZnO using Cl was demonstrated in thin films electrochemically synthetized by adding different amounts of chlorine ions in the starting electrolyte. The ratio between chlorine and zinc cations was varied between 0 and 2 while the zinc concentration in the solution was kept constant. When the concentration of chloride in the bath increases an effective n-type doping of ZnO films takes place. n-type doping is evidenced by the rise of donors concentration, obtained from Mott-Schottky measurements, as well as from the blue shift observed in the optical gap owing to the Burstein-Moss effect.
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- Copyright © Materials Research Society 2013