Hostname: page-component-78c5997874-m6dg7 Total loading time: 0 Render date: 2024-11-03T00:34:13.921Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Properties of a Fully Conjugated Polydiacetylene: Poly(1,4-Bis (3-Quinolyl)-1,3-Butadiyne)

Published online by Cambridge University Press:  25 February 2011

Satya S. Talwar ,
Manjunath B. Kamath  and
K. N. Babu
Satya S. Talwar
Affiliation:
Department of Chemistry, Indian Institute of Technology, Powai, Bombay, India 400 076.
Manjunath B. Kamath
Affiliation:
Department of Chemistry, Indian Institute of Technology, Powai, Bombay, India 400 076.
K. N. Babu
Affiliation:
Department of Chemistry, Indian Institute of Technology, Powai, Bombay, India 400 076.
Get access

Abstract

Synthesis of a new fully conjugated polydiacetylene i.e. poly(l,4-bis(3-quinolyl)-l,3-butadiyne) is described. Reflectance spectra of partially polymerised samples and the polymer are reported. The spectra show long wavelength absorption band at 750 nm. with the visible absorption edge above 800 nm. DC electrical conductivity measurements on pristine and Iodine doped Poly-DQ are reported. The results are discussed in terms of side group - backbone electronic interactions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 173: Symposium Q – Advanced Organic Solid State Materials , 1989 , 583
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Matsuda, H., Nakanishi, H., Hosomi, T. and Kato, M.,Macromolecules 21,1238(1988).Google Scholar
2. Carter, G. M., Chen, Y. J., Rubner, M. F., Sandman, D. J., Thakur, M. K. and Tripathy, S. K. in Nonlinear OpticalProperties of Organic Molecules and Crystals, vol. 2, edited by Chemla, D. S. and Zyss, J. (Academic Press, New York, 1987), p. 85.CrossRefGoogle Scholar
3. Bloor, D., Phil. Trans. R. Soc. Lond. A314. 51 (1985).Google Scholar
4. Garito, A. F., Teng, C. C., Wong, K. Y. and Zammani ‘Khamiri, O., Mol. Cryst. Liq. Cryst. 106, 219 (1984).CrossRefGoogle Scholar
5. Sandman, D. J. and Chen, Y. J., Polymer 30, 1027 (1989).CrossRefGoogle Scholar
6. Clough, S. B., Kumar, S., Sun, X. F., Tripathy, S., Matsuda, H., Nakanishi, H., Okada, S. and Kato, M., Chem. Abst. No.135131 Z, 111, (1989).Google Scholar
7. Talwar, S., Kamath, M., Kalyan Das, and Sinha, U., Polymer Commun.(in press).Google Scholar
8. Wegner, G., J. Polym.Sci.,PartB 9, 133 (1971);Google Scholar
Ozcayir, Y., Asrar, J. and Blumstein, A., Mol. Cryst. Liq. Crvst. 110.1424 (1984);Google Scholar
Tsibouklis, J., Wernick, A. R., Shand, A. J. and Millbum, G. H. W., Chemtronics 3,211 (1988);Google Scholar
Millburn, G. H. W., Wemick, A. R., Tsibouklis, J., Bolton, E., Thomas, G. and Shand, A. J., Polymer 30,2115 (1989);Google Scholar
Meyerle, J. J. and Flandrora, M. A., Acta Crystallogr., Sect. B : Struct. Crystallogr. Crystl. Chem. 34,1374 (1978).Google Scholar
9. Tokura, Y., Koda, T., Itsubo, A., Miyabayashi, M., Okuhara, K. and Ueda, A., J. Chem. Phys 83,99 (1986).Google Scholar
10. Matsuda, H., Nakanishi, H., Kato, S. and Kato, M., J. Polym. Sci. Polym. Chem. 25,1663 (1987).CrossRefGoogle Scholar
11. Khandelwal, P. K. and Talwar, S. S., J. Polym. Sci. Polym. Chem. Ed. 21, 3073 (1983);Google Scholar
Kamath, M. B., Ph.D Dissertation,I.I.T., Bombay (1989).Google Scholar
12. Das, Kalyan, Sinha, U. C., Kamath, M. B. and Talwar, S. S., Acta Crystallogr., C (in press).Google Scholar
13. Reference 5 and references therein.Google Scholar
14. Batchelder, D. N. and Bloor, D. in Advances in Infrared and Raman Spectroscopy. Vol. II, edited by Clark, R. J. H. and Hester, R. E. (Wiley Heyden, New York, 1984) p. 133.Google Scholar
15. Babu, K. N. and Talwar, S. S. (unpublished work).Google Scholar
16. Se, K., Ohnuma, H. and Kotako, T., Macromolecules 17,2126(1984).Google Scholar