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Processing and Performance of V205 Xerogel, Aerogel, and Aerogellike Materials as Lithium Intercalation Hosts

Published online by Cambridge University Press:  10 February 2011

Leland H. Manhart ,
Jun John Xu ,
Fabrice Coustier ,
Stefano Passerini ,
Boone B. Owens  and
William H. Smyrl
Leland H. Manhart
Affiliation:
Corrosion Research Center, Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
Jun John Xu
Affiliation:
Corrosion Research Center, Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
Fabrice Coustier
Affiliation:
Corrosion Research Center, Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
Stefano Passerini
Affiliation:
Corrosion Research Center, Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
Boone B. Owens
Affiliation:
Corrosion Research Center, Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
William H. Smyrl
Affiliation:
Corrosion Research Center, Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
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Abstract

Various forms of vanadium pentoxide, including xerogel, aerogel, and aerogel-like forms, were prepared by sol-gel synthesis and processed by novel procedures following synthesis. It was demonstrated that the intrinsic thermodynamics of lithium intercalation of the ARG and ARG-like materials prepared by solvent exchange processes involving methyl formate (MF/ARG and MF/ARG-xslike) are identical, while they are drastically different from those of the parent XRG, which gives rise to significantly increased specific energies for the MF/ARG or MF/ARG-like as lithium intercalation hosts. All three forms are capable of reversibly intercalating up to four moles of Li+ ions per mole of V205 electrochemically and can be cathode candidates for rechargeable lithium batteries. Various processing methods for fabricating composite electrodes with the XRG led to specific capacity in the range of 300 to 350 mAh/g at C4Li/ 20 rate, and good cyclability.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 548: Symposia EE – Solid State Ionics V , 1998 , 113
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

1. Hench, L. L. and West, J. K., Chem. Rev. 90, 33 (1990).Google Scholar
2. Phillipp, G. and Schmidt, H., J. Non-Cryst. Solids, 63, 283 (1984).Google Scholar
3. Schmidt, H., Mat. Res. Soc. Somp., 180, 961 (1990).Google Scholar
4. Feuilluade, G. and Perche, P., J. Appl. Electrochem, 5, 63 (1975).Google Scholar
5. Abraham, K. M. and Alamgir, M., J Electrochem. Soc., 137, 1657 (1990).Google Scholar
6. Dautzenberg, G., Croce, F., Passerini, S. and Scrosati, B., Chem. Mater., 6, 538 (1994).Google Scholar
7. Dunn, B., Farrington, G. C. and Katz, B., Solid State lonics, 70/71, 3 (1994).Google Scholar
8. Bach, S., Pereira-Ramos, J. P. and Baffler, N., J. Electrochem. Soc., 143, 3429 (1996).Google Scholar
9. Livage, J., Chem. Mater., 3, 578 (1991).Google Scholar
10. Passerini, S., Tipton, A. L. and Smyrl, W. H., Solar Energy Mater., 39, 167 (1995).Google Scholar
11. Park, H. K. and Smyrl, W. H., J. Electrochem. Soc., 141, L25 (1994).Google Scholar
12. Le, D. B., Passerini, S., Tipton, A. L., Owens, B. B. and Smyrl, W. H., J. Electrochem. Soc., 142, L102 (1995).Google Scholar
13. Passerini, S., Chang, D., Chu, X., Le, D. B. and Smyrl, W. H., Chem. Mater., 7, 780 (1995).Google Scholar
14. Park, H. K., Smyrl, W. H. and Ward, M. D., J. Electrochem. Soc., 142, 1068 (1995).Google Scholar
15. Le, D. B., Passerini, S., Guo, J., Ressler, J., Owens, B. B. and Smyrl, W. H., J. Electrochem. Soc., 143, 2099 (1996).Google Scholar
16. Tipton, A. L., Passerini, S., Owens, B. B., Smyrl, W. H., J. Electrochem. Soc., 143, 3473 (1996).Google Scholar
17. Coustier, F., Passerini, S. and Smyrl, W. H., J. Electrochem. Soc., 145, L73 (1998).Google Scholar
18. Coustier, F., Lee, J.-M., Passerini, S. and Smyrl, W. H., Solid State Ionics, forthcoming.Google Scholar
19. Manhart, L. H., Owens, B. B., Smyrl, W. H., and Xu, J. J., in Proceedings of the 38th Power Sources Conference, IEEE, Cherry Hill, NJ (1998).Google Scholar
20. Owens, B. B., Smyrl, W. H. and Xu, J. J., J. Power Sources, forthcoming.Google Scholar