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The Potential of Binary Lithium Magnesium Nitride - LiMgN for Hydrogen Storage Application

Published online by Cambridge University Press:  01 February 2011

Jun Lu ,
Zhigang Zak Fang ,
Young Joon Choi  and
Hong Yong Sohn
Jun Lu
Affiliation:
[email protected], University of Utah, Metallurgical Engineering, 135 South 1460 East Room 412, Salt Lake City UT 84112, USA, Salt Lake City, UT, 84112, United States, 001-801-581-3963, 001-801-581-4937
Zhigang Zak Fang
Affiliation:
[email protected], University of Utah, Metallurgical Engineering, 135 South 1460 East Room 412, Salt Lake City, UT, 84112, United States
Young Joon Choi
Affiliation:
[email protected], University of Utah, Metallurgical Engineering, 135 South 1460 East Room 412, Salt Lake City, UT, 84112, United States
Hong Yong Sohn
Affiliation:
[email protected], University of Utah, Metallurgical Engineering, 135 South 1460 East Room 412, Salt Lake City, UT, 84112, United States
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Abstract

Metal hydrides and amides are potential candidate materials for hydrogen storage. Lithium- and magnesium-based material systems are among the most promising materials owing to their high hydrogen contents. In the present work, we investigated hydrogenation/dehydrogenation reactions of a binary nitride, LiMgN. LiMgN can be formed by a reaction of MgH2 with LiNH2 in 1:1 ratio. The reaction also releases approximately ∼ 8.1 wt% H2 (theoretical value is 8.2 wt%) between 160 and 220 °C. The reaction product LiMgN can be rehydrogenated by reacting with H2 under 2000 psi of hydrogen pressure and 160 °C with small amount of TiCl3 doping. TGA results showed that about 8.0 wt% of hydrogen was stored in TiCl3-doped LiMgN during the hydrogenation process. The reversible hydrogenation and dehydrogenation mechanisms involving LiMgN and H2 are discussed.

Keywords

energy-storagehydrogenationnitride
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1042: Symposium S – Materials and Technology for Hydrogen Storage , 2007 , 1042-S05-03
Copyright
Copyright © Materials Research Society 2008

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References

1) Bogdanovic, B.; Schwickardi, M. J. Alloys Compd. 1997, 253, 1.Google Scholar
2) Balema, V. P; Dennis, K. W; Pecharsky, V. K Chem. Commun. 2000, 17, 1665.Google Scholar
3) Chen, J.; Kuriyama, N.; Xu, Q.; Takeshita, H. T; Sakai, T. J. Phys. Chem. B 2001, 105, 11214.Google Scholar
4) Wang, J.; Ebner, A.D; Ritter, J.A; J. Am. Chem. Soc. 2006, 128, 5949.Google Scholar
5) Zidan, R. A.; Taraka, S.; Hee, A. G; Jensen, C. M J. Alloys Compd., 1999, 285, 119.Google Scholar
6) Jensen, C. M; Gross, K. J Appl. Phys. A 2001, 72, 213.Google Scholar
7) Sandrock, G.; Gross, K. J; Thomas, G. J. Alloys Compd. 2002, 339, 299.Google Scholar
8) Sun, D. L; Kiyobayashi, T.; Takeshite, H. T; Kuriyama, N.; Jensen, C. M J. Alloys Compd. 2002, 337, 8.Google Scholar
9) Morioka, H.; Kakizaki, K.; Chung, S. C; Yamada, A. J. Alloys Compd. 2003, 353, 310.Google Scholar
10) Fichtner, M.; Fuhr, O.; Kircher, O. J. Alloys Compd. 2003, 356, 418.Google Scholar
11) Vajo, J.J; Skeith, S.L; Mertens, F. J. Phys. Chem. B 2005, 109, 3719.Google Scholar
12) Aoki, M.; Miwa, K.; Noritake, T.; Kitahara, G.; Nakamori, Y.; Orimo, S.; Towata, S. Appl. Phys. A 2005, 80, 1409.Google Scholar
13) Miwa, K.; Ohba, N.; Towata, S. Phys. Rew. B 2004, 69, 245120.Google Scholar
14) Orimo, S.; Nakamori, Y.; Züttel, A. Mater. Sci. Eng. B 2004, 108, 51.Google Scholar
15) Chen, P.; Xiong, Z.; Luo, J.; Lin, J.; Tan, K. L Nature 2002, 420, 302.Google Scholar
16) Chen, P.; Xiong, Z.; Luo, J.; Lin, J.; Tan, K. L J. Phys. Chem. B, 2003, 107, 10967.Google Scholar
17) Lu, J.; Fang, Z.Z J. Phys. Chem. B 2005, 109, 20830.Google Scholar
18) Lu, J.; Fang, Z.Z; Sohn, H.Y J. Phys. Chem. B 2006, 110, 14236.10.1021/jp061764pGoogle Scholar
19) Lu, J.; Fang, Z.Z; Sohn, H.Y Inorg. Chem. 2006, 45, 8749.Google Scholar
20) Luo, W. J. Alloys Compd. 2004, 381, 284.Google Scholar
21) Luo, W.; Sickafoose, Q. J. Alloys Compd. 2006, 407, 274.Google Scholar
22) Xiong, Z.; Hu, J.; Wu, G.; Chen, P.; Luo, W.; Gross, K. and Wang, J. J. Alloys Compd. 2005, 398, 235.Google Scholar
23) Xiong, Z.; Wu, G.; Hu, J. and Chen, P. Adv. Mater. 2004, 16, 1522.Google Scholar
24) Leng, H. Y.; Ichikawa, T.; Hino, S.; Hanada, N.; Isobe, S.; and Fujii, H. J. Phys. Chem. B, 2004, 108, 8763.Google Scholar
25) Nakamori, Y.; Kitahara, G.; Miwa, K.; Ohba, N.; Noritake, T.; Towata, S.; Orimo, S. J. Alloys Compd. 2005, 404–406, 140.Google Scholar
26) Ichikawa, T.; Tokoyoda, K.; Leng, H.Y; Fujii, H. J. Alloys Compd. 2005, 400, 245.Google Scholar
27) Magyari-Kope, B.; Ozolins, V.; and Wolverton, C. Phys. Rev. B 2006 73, 220101.10.1103/PhysRevB.73.220101Google Scholar
28) Grochala, W.; Edwards, P. Chem. Rev., 2004, 104, 1283.10.1021/cr030691sGoogle Scholar
29) Alapati, S.V; Johnson, K.J; Sholl, D.S J. Phys. Chem. B 2006, 110, 8769.10.1021/jp060482mGoogle Scholar
30) Alapati, S.V; Johnson, K.J; Sholl, D.S Phys. Chem. Chem. Phys. 2007, 9 1438.Google Scholar
31) Hu, Y. H; Ruckenstein, E. J. Phys. Chem. A 2003, 107, 9717.Google Scholar
32) Xiong, Z.; Wu, G.; Hu, J.; Liu, Y.; Chen, P.; Luo, W.; Wang, J. Adv. Funct. Mater., 2007, 17, 1137.Google Scholar
33) Rijssenbeek, J.; Gao, Y.; Hanson, J.; Huang, Q.; Jones, C.; Toby, B. J. Alloys Compd. 2008, 454, 233.Google Scholar
34) Isobe, S.; Ichikawa, T.; Hanada, N.; Leng, H.Y; Fichtner, M.; Fuhr, O.; Fujii, H. J. Alloys Compd. 2005, 404–406, 439.Google Scholar
35) Kojima, Y.; Kawai, Y. J. Alloys Compd. 2005, 395, 236.Google Scholar
36) Linda, G.; Juza, R.; Zeitschrift fur Anorganische und Allgemeine Chemie 1974, 409, 199.Google Scholar
37) Bohger, J.P.O.; Essmann, R.R; Jacobs, H.; J. Mol. Struct. 1995, 348, 325.10.1016/0022-2860(95)08654-EGoogle Scholar