Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-28T11:46:40.995Z Has data issue: false hasContentIssue false
  • English
  • Français

Nanoporous Titanium Oxide Morphologies Produced by Anodizing of Titanium

Published online by Cambridge University Press:  15 February 2011

G.P. Sklar ,
H. Singh ,
V. Mahajan ,
D. Gorhe ,
S.A. Namjoshi  and
J.C. LaCombe
G.P. Sklar
Affiliation:
Metallurgical and Materials Engineering University of Nevada, Reno Reno, NV, 89557, USA.
H. Singh
Affiliation:
Metallurgical and Materials Engineering University of Nevada, Reno Reno, NV, 89557, USA.
V. Mahajan
Affiliation:
Metallurgical and Materials Engineering University of Nevada, Reno Reno, NV, 89557, USA.
D. Gorhe
Affiliation:
Metallurgical and Materials Engineering University of Nevada, Reno Reno, NV, 89557, USA.
S.A. Namjoshi
Affiliation:
Metallurgical and Materials Engineering University of Nevada, Reno Reno, NV, 89557, USA.
J.C. LaCombe
Affiliation:
Metallurgical and Materials Engineering University of Nevada, Reno Reno, NV, 89557, USA.
Get access

Abstract

A quick and dependable technique has been developed that allows us to selectively produce anodized TiO2 in the form of nanotubes. The process employs mild chemical conditions and ambient temperature. The method can consistently produce nearly 100% surface coverage of nanotubes within 10 min of anodizing. Anodizing in relatively high pH electrolytes for 1 hour permitted us to produce nanotubes of 2μm length. We attribute the repeatability of our results to a brief pre-anodizing etching step that consistently leads to excellent anodizing results. Without this etching step, we experienced very poor consistency in that only small patches of titania nanotubes were formed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 876: Symposium A – Nanoporous and Nanostructured Materials for Catalysis, Sensor and Gas Separation Applications , 2005 , R1.2
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Gong, D., Grimes, C. A., Varghese, O. K., Hu, W., Singh, R. S., Chen, Z., and Dickey, E. C., Titanium oxide nanotube arrays prepared by anodic oxidation, J. Mater. Res., Vol. 16, No. 12 (2001) 3331.Google Scholar
2 Beranek, R., Hilderbrand, H., and Schmuki, P., Self-Organized Porous Titanium Oxide Prepared in H2SO4/HF Electrolytes, Electrochemical and Solid-State Letters, Vol. 6, No. 3 (2003) B12.Google Scholar
3 Zwilling, V., Darque-Ceretti, E., Boutry-Forveille, A., David, D., Perrin, M.Y., and Aucouturier, M., Structure and Physicochemistry of Anodic Oxide Films on Titanium and TA6V Alloy, Surf. Interface Analysis, 27 (1999) 629.Google Scholar
4 Cai, Q., Paulose, M., Varghese, O.K., and Grimes, C.A., The effect of electrolyte composition on the fabrication of self-organized titanium oxide nanotube arrays by anodic oxidation, J. Mater. Res. Vol. 20 No. 1 (2005) 230.Google Scholar
5 Macák, J.M., Tsuchiya, H., and Schmuki, P., High-Aspect-Ratio TiO2 Nanotubes by Anodization of Titanium, Angew. Chem. Int. Ed., 44 (2005) 2.Google Scholar
6 Macák, J.M., Sirotnal, K., and Schmuki, P., Self-organized porous titanium oxide prepared in Na2SO4/NaF electrolytes, Electrochimica Acta, Article in Press.Google Scholar