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Linear Free Energy Relationships in Glass Corrosion

Published online by Cambridge University Press:  22 February 2011

Teofilo A. Abrajano JR. ,
John K. Bates  and
J. K. Bohlke
Teofilo A. Abrajano JR.
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439
John K. Bates
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439
J. K. Bohlke
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439
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Abstract

Various theoretical models that have been proposed to correlate glass durability to their composition for a wide variety of silicate, borosilicate, and aluminosilicate glasses are examined. Comparisons are made between the predictions of these models and those of an empirical formulation extracted from existing data in the present work. The empirical approach provides independent confirmation of the relative accuracy of the silica release rate predictions of the different theoretical models in static leaching systems. Extensions of the empirical approach used in this work are discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 123: Symposium L – Materials Issues in Art and Archaeology I , 1988 , 253
Copyright
Copyright © Materials Research Society 1988

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