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Halide Glasses

Published online by Cambridge University Press:  29 November 2013

Cornelius T. Moynihan
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The term “halide glass” refers to glasses in which the anions are from elements in Group VIIA of the periodic table, namely, F, Cl, Br and I, as opposed, for example, to “oxide glasses,” such as silicates, borates, phosphates, etc. Two known single component halide melts are glassforming, BeF2 and ZnCl2, but the majority of halide glasses are multicomponent. Practical interest in halide glasses has been generated almost entirely by their optical properties, which cannot be duplicated in a more conventional oxide glass. Barriers to the practical deployment of halide glasses have their origin in materials properties in which they can be markedly inferior to oxide glasses, e.g., mechanical strength, resistance of the melt to crystallization, chemical durability, etc.

In the past decade there has been considerable and accelerating research activity in the area of halide glass science and engineering. Halide glass research up to 1980 has been reviewed by Baldwin et al. and oxide and halide glasses for laser applications have been compared by Weber. Four international symposia on halide glass science and engineering have been held in the period 1982–1987, the proceedings of the last two of which have been or will be shortly published. The proceedings of a 1986 NATO-sponsored meeting on halide glasses have also been published in book form.

Type
Glasses
Information
MRS Bulletin , Volume 12 , Issue 5 , August 1987 , pp. 40 - 44
Copyright
Copyright © Materials Research Society 1987

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References

1.Baldwin, C.M., Almeida, R.M., and Mackenzie, J.D., J. Non-Cryst. Solids 43(1981) p. 309.CrossRefGoogle Scholar
2.Weber, M.J., Wiss. Ztschr. Friedrich-Schiller-Univ. Jena, Math.-Naturwiss. R. 32(1983) p. 239.Google Scholar
3.Halide Glasses I and II, edited by Lucas, J. and Moynihan, C.T. (Mater. Sci. Forum, Vols. 5 and 6, 1985).CrossRefGoogle Scholar
4.Halide Glasses III and IV, edited by Drexhage, M.G., Moynihan, C.T., and Robinson, M. (Mater. Sci. Forum, to be published).Google Scholar
5.Halide Glasses for Infrared Fiberoptics, edited by Almeida, R.M. (Martinus Nijhoff Publishers, Boston, 1987).CrossRefGoogle Scholar
6.Poulain, M., Poulain, M., Lucas, J., and Brun, P., Mat. Res. Bull. 10(1975) p. 243.CrossRefGoogle Scholar
7.Poulain, M., Chanthanasinh, M., and Lucas, J., Mat. Res. Bull. 12(1977) p. 151.CrossRefGoogle Scholar
8.Miyashita, T. and Manabe, T., IEEE J. Quantum Electron. 18(1982) p. 1432.CrossRefGoogle Scholar
9.Tran, D.C., Sigel, G.H. Jr., and Bendow, B., J. Lightwave Technol. 2(1984) p. 566.CrossRefGoogle Scholar
10.Drexhage, M.G., in Treatise on Materials Science and Technology 26, edited by Tomozawa, M. and Doremus, R.H. (Academic Press, New York, 1985) p. 151–243.Google Scholar
11.Infrared Optical Materials and Fibers IV, edited by Klocek, P. (SPIE Proc. 618, 1986).CrossRefGoogle Scholar
12.France, P.W., Carter, S.F., Moore, M.W., and Day, C.R., Br. Telecom. Technol. J. 5 (1987) p. 28.Google Scholar
13.Schneider, H.W., Schoberth, A., and Staudt, A., paper presented at 4th International Symposium on Optical and Optoelectronic Applied Science and Engineering, The Hague (April 3, 1987).Google Scholar
14.Klocek, P., MRS BULLETIN 11 (May/June 1986) p. 41.CrossRefGoogle Scholar
15.Lucas, J., Chanthanasinh, M., Poulain, M., Poulain, M., Brun, P., and Weber, M.J., J. Non-Cryst. Solids 27(1978) p. 273.CrossRefGoogle Scholar
16.Cline, C.F. and Weber, M.J., Wiss. Ztschr. Friedrich-Schiller-Univ. Jena, Math.-Naturwiss. R. 28(1979) p. 351.Google Scholar