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High Magnetic Field Annealing of Mn-Ga IntermetallicAlloys

Published online by Cambridge University Press:  21 December 2015

Daniel R. Brown*
Affiliation:
Department of Material Science and Engineering, Florida State University, Tallahassee, FL 32304 National High Magnetic Field Laboratory, Tallahassee, FL 32310
Ke Han
Affiliation:
National High Magnetic Field Laboratory, Tallahassee, FL 32310
Theo Siegrist
Affiliation:
National High Magnetic Field Laboratory, Tallahassee, FL 32310 Department of Chemical Engineering, Florida Agricultural and Mechanical University-Florida State University, Tallahassee, FL 32304
Tiglet Besara
Affiliation:
National High Magnetic Field Laboratory, Tallahassee, FL 32310
Rongmei Niu
Affiliation:
National High Magnetic Field Laboratory, Tallahassee, FL 32310
*
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Abstract

Mn-Ga alloys have shown promising hard magnetic properties, even though thesealloys contain no rare-earth metals. However, much work is needed before Mn-Gaalloys become viable permanent magnets for applications. One of the challengesis to enhance the remanence. One technique to improve this property is applyinga magnetic field during the heat treatment process. Magnetic annealing canpromote phase transformation of the phases with high magnetic moment. Thisresults in an increased remanence. Bulk samples of Mn-Ga alloys were made bymechanically alloying in order to create a nanostructured composite, followed byheat treatments in the presence of a 31 T magnetic field. The heat treatmenttemperatures were kept low in order to keep the refined microstructure. All thealloys exhibit hard magnetic properties at room temperature with largecoercivity. This work reports findings of magnetic field annealed Mn-Ga bulkthat exhibit high coercivities up to 19.4 kOe and increased remanence of 50%over the binary system, achieving values up to 6.9 emu/g. This is the highestcoercivity reported in bulk Mn-Ga samples.

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Articles
Copyright
Copyright © Materials Research Society 2015 

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References

REFERENCES

Buschow, K. H. J., “New developments in hard magnetic materials,” Rep. Prog. Phys., vol. 54, no. 9, p. 1123, Sep. 1991.Google Scholar
Herbst, J. F., “R2Fe14B materials: Intrinsic properties and technological aspects,” Rev. Mod. Phys., vol. 63, pp. 819898, Oct. 1991.Google Scholar
Lewis, L. H. and Jiménez-Villacorta, F., “Perspectives on Permanent Magnetic Materials for Energy Conversion and Power Generation,” Metall. Mater. Trans. A, vol. 44, no. 1, pp. 220, Jul. 2012.CrossRefGoogle Scholar
Feng, J. N., Zhao, X. G., Ning, X. K., Shih, C. W., Chang, W. C., Ma, S., Liu, W., and Zhang, Z. D., “Phase evaluation, magnetic, and electric properties of Mn60+xGa40−x (x = 0–15) ribbons,” J. Appl. Phys., vol. 115, no. 17, p. 17A750, May 2014.Google Scholar
Brown, D. R., Han, K., and Siegrist, T., “Hard magnetic properties observed in bulk Mn1−xGax,” J. Appl. Phys., vol. 115, no. 17, p. 17A723, May 2014.Google Scholar
Coey, J. M. D., “New permanent magnets; manganese compounds,” J. Phys. Condens. Matter, vol. 26, no. 6, p. 064211, Feb. 2014.Google Scholar
Wei, J. Z., “Structural properties and large coercivity of bulk Mn3-xGa (0 ≤ x ≤ 1.15),” J. Appl. Phys., vol. 115, no. 17, 2014.CrossRefGoogle Scholar
El-Gendy, A. A. and Hadjipanayis, G., “Nanostructured D022-Mn3Ga with high coercivity,” J. Appl. Phys., vol. 48, no. 12, p. 125001, Apr. 2015.Google Scholar
Ener, S., Skokov, K. P., Karpenkov, D. Y., Kuz’min, M. D., and Gutfleisch, O., “Magnet properties of Mn70Ga30 prepared by cold rolling and magnetic field annealing,” J. Magn. Magn. Mater., vol. 382, pp. 265270, May 2015.Google Scholar
Ma, Q. L., Zhang, X. M., Miyazaki, T., and Mizukami, S., “Artificially engineered Heusler ferrimagnetic superlattice exhibiting perpendicular magnetic anisotropy,” Sci. Rep., vol. 5, Jan. 2015.Google Scholar
Saito, T. and Nishio-Hamane, D., “New hard magnetic phase in Mn–Ga–Al system alloys,” J. Alloys Compd., vol. 632, pp. 486489, May 2015.Google Scholar
Balke, B., Fecher, G. H., Winterlik, J., and Felser, C., “Mn3Ga, a compensated ferrimagnet with high Curie temperature and low magnetic moment for spin torque transfer applications,” Appl. Phys. Lett., vol. 90, no. 15, pp. 152504–152504–3, Apr. 2007.Google Scholar
Winterlik, J., Balke, B., Fecher, G. H., Felser, C., Alves, M. C. M., Bernardi, F., and Morais, J., “Structural, electronic, and magnetic properties of tetragonal Mn3-xGa : Experiments and first-principles calculations,” Phys. Rev. B, vol. 77, p. 054406, Feb. 2008.Google Scholar
Saito, T. and Nishimura, R., “Hard magnetic properties of Mn-Ga melt-spun ribbons,” J. Appl. Phys., vol. 112, no. 8, p. 083901, Oct. 2012.Google Scholar
Huh, Y., Kharel, P., Shah, V. R., Li, X. Z., Skomski, R., and Sellmyer, D. J., “Magnetism and electron transport of MnyGa (1 < y < 2) nanostructures,” J. Appl. Phys., vol. 114, no. 1, p. 013906, Jul. 2013.Google Scholar
Ma, Q., Sugihara, A., Suzuki, K., Zhang, X., Miyazaki, T., and Mizukami, S., “TETRAGONAL HEUSLER-LIKE Mn–Ga ALLOYS BASED PERPENDICULAR MAGNETIC TUNNEL JUNCTIONS,” SPIN, vol. 04, no. 04, p. 1440024, Sep. 2014.Google Scholar
Cullity, B.D., Introduction to Magnetic Materials, 2nd ed. Piscataway: Wiley, 2012.Google Scholar
Cui, B.z., Han, K., Garmestani, H., Schneider-Muntau, H.j., Su, J.h., and Liu, J.p., “Enhancement of material properties by magnetic field assisted phase transformation,” in Materials Processing in Magnetic Fields, 0 vols., WORLD SCIENTIFIC, 2005, pp. 1928.Google Scholar
Cui, B. Z., Han, K., Garmestani, H., Su, J. H., Schneider-Muntau, H. J., and Liu, J. P., “Enhancement of exchange coupling and hard magnetic properties in nanocomposites by magnetic annealing,” Acta Mater., vol. 53, no. 15, pp. 41554161, Sep. 2005.Google Scholar
Cui, B. Z., Yu, C. T., Han, K., Liu, J. P., Garmestani, H., Pechan, M. J., and Schneider-Muntau, H. J., “Magnetization reversal and nanostructure refinement in magnetically annealed Nd2Fe14B∕α-Fe-type nanocomposites,” J. Appl. Phys., vol. 97, no. 10, p. 10F308, May 2005.Google Scholar
Cui, B. Z., Han, K., Zhang, Y., Liu, J. P., Garmestani, H., Liu, S., and Schneider-Muntau, H. J., “Crystallization, morphology and magnetic properties of melt-spun (Nd,Pr,Dy)2(Fe,Co,Mo)14B/ alpha;-Fe nanocomposites,” IEEE Trans. Magn., vol. 40, no. 4, pp. 28672870, Jul. 2004.Google Scholar
Cui, B. Z., Han, K., Li, D. S., Garmestani, H., Liu, J. P., Dempsey, N. M., and Schneider-Muntau, H. J., “Magnetic-field-induced crystallographic texture enhancement in cold-deformed FePt nanostructured magnets,” J. Appl. Phys., vol. 100, no. 1, p. 013902, Jul. 2006.Google Scholar
Cui, B. Z., Han, K., Garmestani, H., and Schneider-Muntau, H. J., “Structure and magnetic properties of FePt and FePt–Ag nanostructured magnets by cyclic cold rolling,” J. Appl. Phys., vol. 99, no. 8, p. 08E910, Apr. 2006.Google Scholar
Han, K., “Materials Processing Under the Influence of External Fields: High Magnetic Field Influences on Fabrication of Materials with Magnetic Phases.”Google Scholar
Chikazumi, S., Physics of Ferromagnetism, 2 edition. Oxford : New York: Clarendon Press, 1997.Google Scholar
Wang, X., Qi, M., and Yi, S., “Crystallization behavior of bulk amorphous alloy Zr62Al8Ni13Cu17 under high magnetic field,” Scr. Mater., vol. 51, no. 11, pp. 10471050, Nov. 2004.Google Scholar