Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-24T07:39:50.908Z Has data issue: false hasContentIssue false
  • English
  • Français

EFFECT OF TiO2 + Nb2O5 + TiH2 CATALYSTS ON HYDROGEN STORAGE PROPERTIES OF MAGNESIUM HYDRIDE

Published online by Cambridge University Press:  21 January 2020

Ntumba Lobo ,
Alicja Klimkowicz  and
Akito Takasaki
Ntumba Lobo*
Affiliation:
Global Course of Science and Engineering, Graduate School of Engineering and Science, Shibaura Institute of Technology, Toyosu, Koto-Ku, Tokyo, 135-8548, Japan.
Alicja Klimkowicz
Affiliation:
SIT Research Laboratories, Shibaura Institute of Technology, 3-7-5 Toyosu, Koto-Ku, 135-8548 Tokyo, Japan
Akito Takasaki
Affiliation:
Department of Engineering Science and Mechanics, Shibaura Institute of Technology, 3-7-5 Toyosu, Koto-Ku, 135-8548 Tokyo, Japan
*
*(Email: [email protected])
Get access

Abstract

Magnesium hydride (MgH2) is a prospective material for the storage of hydrogen in solid materials. It can also be envisaged for thermal energy storage applications since it has the potential to reversibly absorb hydrogen in large quantities, theoretically up to 7.6% by weight. Also, MgH2 is inexpensive, abundant, and environmentally friendly, but it operates at relatively high temperatures, and the kinetics of the hydrogenation process is slow. Mechanical milling and the addition of catalyst can alter the activation energy and the kinetic properties of the MgH2 phase. It is known that the addition of titanium hydride (TiH2) lowers the enthalpy and enhances the absorption of hydrogen from MgH2, titanium oxide (TiO2) enhances the desorption of hydrogen and niobium oxide (Nb2O5) enhances the absorption of hydrogen. In this work, the influences of the catalysts, as mentioned above on the properties of MgH2, were studied. The samples were analyzed in terms of crystal and microstructure as well as hydrogen storage properties using a pressure-composition isotherm (PCT)measurement. It has been found that the simultaneous addition of the three catalysts enhances the properties of MgH2, lowers the activation energy and operating temperature, increases the rate of intake and release of hydrogen, and provides the largest gravimetric hydrogen storage capacity.

Keywords

absorptioncatalyticdifferential thermal analysis (DTA)energy storagekinetics
Type
Articles
Information
MRS Advances , Volume 5 , Issue 20: African Materials Research Society 2019 , 2020 , pp. 1059 - 1069
Copyright
Copyright © Materials Research Society 2020

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Gielen, D., Boshell, F., Saygin, D., Bazilian, M.D., Wagner, N., Gorini, R.The role of renewable energy in the global energy transformation Energy Strategy Rev., 24 (2019), 38-50.Google Scholar
Owusu, P., Asumadu, S.S.A review of renewable energy sources, sustainability issues and climate change mitigation Cogent Eng., 3 (2016) 1167990, 1-14.CrossRefGoogle Scholar
Cassia, R., Nocioni, M., Correa-Aragunde, N., Lamattina, L.Climate change and the impact of greenhouse gasses: CO2 and NO, friends and foes of plant oxidative stress Front. Plant. Sci., 9 (2018) 273-278.CrossRefGoogle ScholarPubMed
Clack, B., York, R.Carbon Metabolism: Global Capitalism, Climate Change, and the Biospheric Rift Theory and Society, 34(4) (2005), 391-428.Google Scholar
Mimura, N.Sea-level rise caused by climate change and its implications for society Proc. Jpn. Acad. Ser. B Phys. Biol. Sci., 89 (7) (2013), 281-301.CrossRefGoogle ScholarPubMed
Perera, F.Pollution from fossil-fuel combustion is the leading environmental threat to global pediatric health and equity: Solutions exist Int J Environ Res Public Health, 15 (2018).Google Scholar
Ahuja, D., Tatsutani, M.Sustainable energy for developing countries Surv. Perspect. Integr. Environ. Soc., 2 (2009), 1-5.Google Scholar
Peters, G.P., Le Quéré, C., Andrew, R.M. et al. Towards real-time verification of CO2 emissions. Nature Clim. Change 7 (2017), 848-850.CrossRefGoogle Scholar
Falcon-Lang, H. J., The Early Carboniferous (Courceyan–Arundian) monsoonal climate of the British Isles: evidence from growth rings in fossil woods Geol.Mag. 136(2) (1999),177-187.CrossRefGoogle Scholar
Zuttel, A, Remhof, A, Borgschulte, A, Friedrichs, O. Hydrogen: the future energy carrier. Phil. Trans. R. Soc. A Math. Phys. Eng. Sci. 368 (2010), 3329-3342.CrossRefGoogle ScholarPubMed
Andrews, J, Shabani, B. Where does hydrogen fit in a sustainable energy economy? Procedia Eng. 49 (2012), 15-25.CrossRefGoogle Scholar
Ogden, JM. Hydrogen: the fuel of the future? Phys. Today. 55(4) (2002), 69-73.CrossRefGoogle Scholar
Eberle, U, Felderhoff, M, Schuth, F. Chemical, and physical solutions for hydrogen storage. Angew Chem Int Ed 48 (2009), 6608.CrossRefGoogle ScholarPubMed
Myunghyun, PS, Hye, JP, Thazhe, KP, Dae-Woon, L. Hydrogen storage in metal-organic framework. Chem Rev.112(2) (2012) 782-835.Google Scholar
Staffell, I., Scamman, D., Abad, A.V., Balcombe, P., Dodds, P.E., Ekins, P.The role of hydrogen and fuel cells in the global energy system Energy Environ. Sci. 12 (2019), 463-491.Google Scholar
Paul, B., James, B., Chester, L., Line, S., Jamie, S., Adam, H., Iain, S., How to decarbonise international shipping: options for fuels, technologies and policies Energy Convers. Manage., 182 (2019), 72-88.Google Scholar
Berry, G.D., Aceves, S.M.The case for hydrogen in a carbon constrained world Journal of Energy Resources Technology, 127 (2005), 89-94.CrossRefGoogle Scholar
Lebaek, J., ed., GreenSynFuels. Economic and Technological Statement Regarding Integration and Storage of Renewable Energy in the Energy Sector by Production of Green Synthetic Fuels for Utilization in Fuel Cells, Final Project Report, EUDP Project Journal Number: 64010-0011, Danish Technological Institute, (2011).Google Scholar
Makridis, S. S.Hydrogen storage and compression. In Methane and Hydrogen for Energy Storage; Carriveau, R., Ting, D.S.K., Eds.; IET Digital Library: Stevenage, UK, (2016), 1-28Google Scholar
Manoharan, Y.; Hosseini, S.E.; Butler, B.; Alzhahrani, H.; Senior, B.T.F.; Ashuri, T.; Krohn, J.Hydrogen Fuel Cell Vehicles; Current Status and Future Prospect. Appl. Sci. 9 (2019), 2296-22300CrossRefGoogle Scholar
Andersson, J., Grönkvist, S.Large-scale storage of hydrogen Int. J Hydrogen Energy, 44 (2019), 11901-11919CrossRefGoogle Scholar
Blagojevic, V.A., Minic, D.M., Minic, D.G., Novakovic, J.G., Hydrogen economy: modern concepts, challenges and perspectives. In: Minic, D. (ed) Hydrogen energy - challenges and perspectives (2012).Google Scholar
Rosen, M.A., Koohi-Fayegh, S.The prospects for hydrogen as an energy carrier: an overview of hydrogen energy and hydrogen energy systems Energy, Ecol Environ, 1 (2016), 10-29.Google Scholar
Dornheim, M. Thermodynamics of metal hydrides: tailoring reaction enthalpies of hydrogen storage materials. In: Moreno-Pirajan, JC, editor. Thermodynamics—interaction studies–solids, liquids and gases. Rijeka: InTech; (2011), 891-918.Google Scholar
Aymard, L., Oumellal, Y., Bonnet, J.-P.Metal hydrides: an innovative and challenging conversion reaction anode for lithium-ion batteries. Beilstein J. Nanotechnol. 6, (2015), 1821-1839.CrossRefGoogle ScholarPubMed
Uesugi, H., Sugiyama, T., Nii, H., Ito, T., Nakatsugawa, I.Industrial production of MgH2 and its application J Alloys Compd, 509 (2011), 650-653.CrossRefGoogle Scholar
Li, B., Li, J.D., Shao, H.Y., He, L.Q.Mg-based hydrogen absorbing materials for thermal energy storage-A review Appl Sci Basel, 8 (2018), 1375-1382.CrossRefGoogle Scholar
Zhang, J., Li, Z., Wu, Y., Guo, X., Ye, J., Yuan, B.Recent advances on the thermal destabilization of Mg-based hydrogen storage materials. RSC Adv. 9(2019), 408-428.CrossRefGoogle Scholar
Jain, A., Agarwal, S., Kumar, S., Yamaguchi, S., Miyaoka, H., Kojima, Y., Ichikawa How does TiF4 affect the decomposition of MgH2 and its complex variants? – an XPS investigation J. Mater. Chem., 5 (30) (2017), 15543-15551.CrossRefGoogle Scholar
Wang, Y. Recent advances in additive-enhanced magnesium hydride for hydrogen storage Prog Nat Sci Mater Int, 27 (2017), 41-49.CrossRefGoogle Scholar
Huang, Y., Xia, G., Chen, J., Zhang, B., Li, Q., Yu, X.One-step uniform growth of magnesium hydride nanoparticles on graphene Prog Nat Sci, 27 (1) (2017), 81-87.CrossRefGoogle Scholar
Yartys, V.A., Lototskyy, M.V., Akiba, E., Albert, R., Antonov, V.E., Ares, J.R.Magnesium based materials for hydrogen based energy storage: past, present and future Int J Hydrogen Energy, 44 (2019), 7809-7859.CrossRefGoogle Scholar
Westerwaal, R.J., Haije, W.G.Evaluation solid-state hydrogen storage systems, current status ECN-E-08-043 (2008), 74.Google Scholar
Aguey-Zinsou, K.-F., Ares-Fernandez, J.-R.Hydrogen in magnesium: New perspectives toward functional stores. Energy Environ. Sci. 3 (2010), 526-543.CrossRefGoogle Scholar
Huot, J., Ravnsbæk, D., Zhang, J., Cuevas, F., Latroche, M., Jensen, T.Mechanochemical synthesis of hydrogen storage materials Prog Mater Sci, 58 (1) (2013), 30-75.CrossRefGoogle Scholar
Nobuko, H., Takayuki, I., Hironobu, F.Catalytic effect of nanoparticle 3d-transition metals on hydrogen storage properties in magnesium hydride MgH2 prepared by mechanical milling J Phys Chem B, 109 (2005), 7188-7194.Google Scholar
Huot, J., Ravnsbæk, D.B., Zhang, J., Cuevas, F., Latroche, M., Jensen, T.R.Mechanochemical synthesis of hydrogen storage materials Prog Mater Sci, 58 (1) (2013), 30-75.CrossRefGoogle Scholar
Billur, S., Lamari-Darkrim, F., Hirscher, M.Metal hydride materials for solid hydrogen storage: a review Int J Hydrog Energy, 32 (2007), 1121-1140.Google Scholar
Yadav, T.K., Yadav, R.M., Singh, D.P.Mechanical milling: a top down approach for the synthesis of nanomaterials and nanocomposites Nanosci Nanotechnol, 2 (3) (2012), 22-48.CrossRefGoogle Scholar
Lobo, N., Takasaki, A., Mineo, K., Klimkowicz, A., Goc, K.Stability investigation of the γ-MgH2 phase synthesized by high-energy ball milling Int. J. Hydrog. Energy 44(55) (2019), 29179-29188CrossRefGoogle Scholar
Pavel, R.-A., Fermín, C., Michel, L.Optimization of TiH2 content for fast and efficient hydrogen cycling of MgH2-TiH2 nanocomposites Int. J. Hydrog. Energy 43(34) (2018), 16774-16781.Google Scholar
Radojka, V. Theoretical and experimental study of TiO2 influence of on hydrogen sorption in MgH2/Mg system, faculty of physical chemistry, University of Belgrade Ph.D. theses 2017Google Scholar
Webb, C.J., A review of catalyst-enhanced magnesium hydride as a hydrogen storage material. J. Phys. Chem. Solids 84 (2015), 96-106.CrossRefGoogle Scholar
Hilman, M.A.R., Alief, M.S., Klimkowicz, A., Uematsu, S., Takasaki, A.Effects of KNbO3 catalyst on hydrogen sorption kinetics of MgH2 J. Hydrog. Energy 44 (2019) 29196-29202.Google Scholar